Lithium ion batteries (including lithium ion polymer batteries)

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Detailinfo IMDG-Code, Amdt. 42-24 (DGG-Info)

UN 3480 Lithium ion batteries (including lithium ion polymer batteries) IMDG-Code, Amdt. 42-24 (Detailinfo)

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Substance information(collapsed)

The BAM name is based on the "name and description" from the regulations and the IUPAC rules, but may be supplemented with further information so that significant differences between two dangerous goods data sets are apparent.

Language BAM name
German Lithium-Ionen-Batterien (einschließlich Lithium-Ionen-Polymer-Batterien)
English Lithium ion batteries (including lithium ion polymer batteries)
French Piles au lithium ionique (y compris les piles au lithium ionique à membrane polymère)

The aggregate state is given under normal conditions, i.e. at room temperature of 20 °C and normal pressure of 101.3 kPa.

Aggre­gate state
under normal con­di­tions articles
during trans­port articles

The formula describes the chemical composition of a substance.

Formula

The BAM number is used to uniquely identify a substance or object in the BAM dangerous goods data pool.

BAM no. 11008
CAS no.
EC no.
Index no.
ZVG nos.

Physico-chemical substance information(collapsed)
Properties and remarks
Appearance electrical batteries containing lithium ion
Colour not specified
Odour not specified
Misci­bility/solu­bility not specified
Impact on human orga­nism not specified
Addi­tio­nal pro­per­ties/remarks Electrical batteries containing lithium ion may react (e.g. flame, heat, emission of toxic, corrosive or flammable gases or vapours) or disassemble due to damage, defects or short circuit.
Reaction with ...
Water not specified
Acids not specified
Alkalis not specified
Metals not specified
Oxidizing substances not specified

Classification(collapsed)
General
UN no. 3480
Class
Sub­si­diary risks
Packing group
Compati­bility group
Spe­cial pro­vi­sions
,
,
,
,
,
,
,
Maritime transport
Marine pollutant
Environ­mentally ha­zar­dous
Emergency Schedules (EmS)
,
MFAG no.

Remark (german): Laut Sondervorschrift 188 unterliegt diese UN-Nr. unter bestimmten Bedingungen nicht den Vorschriften des IMDG-Codes.


Names(collapsed)
Transport document names 2
German LITHIUM-IONEN-BATTERIEN
English LITHIUM ION BATTERIES
Instruction names 2
English LITHIUM ION BATTERIES (including lithium ion polymer batteries)
German LITHIUM-IONEN-BATTERIEN (einschließlich Lithium-Ionen-Polymer-Batterien)
Synonyms 0
Synonyms for transport documents 0
INCI synonyms 0
Synonyms (not recommended) 0

Transport exlusions(collapsed)
Transport status of this substance/article allowed

Labelling(collapsed)
Packagings
Label / Mark
IBC
Label / Mark
Notice not stated - the carriage in intermediate bulk containers (IBCs) is forbidden.
Large packagings (LP)
Label / Mark
Tanks
Placard / Mark
Orange-coloured plate
Tanks Notice not stated - carriage in tanks is forbidden
Vehicles
Placard / Mark
Orange-coloured plate
Containers
Placard / Mark
Orange-coloured plate
Bulk
Placard / Mark
Orange-coloured plate
Notice not stated - carriage in bulk containers is forbidden

Limited and excepted quantities(collapsed)

Values in "ml" and "L" refer to substances that are liquid under normal conditions (temperature 20 °C, density 1013 mbar). Values in "g" and "kg" refer to substances that generally have a melting point greater than 20 °C. Solid substances that can liquefy during transport may only be transported in packagings that are suitable for liquids (paper bags, for example, are not permitted).

Limited quantities(collapsed)

No exemption according to the provisions of Chapter 3.4 possible

Excepted quantities(collapsed)

E0, No exemption according to the provisions of Chapter 3.5 possible


Containments(collapsed)
Single packagings(collapsed)
Permission Transport in packagings is generally permitted.
Instructions P903, P908, P909, P910, P911
Special provisions
Requirements Show requirements

Unless otherwise stated, the quantities indicated for the packagings in the table below refer to the maximum capacity (in litres, "l") or the maximum net mass (in kilograms, "kg"). For some quantities, an additional note with the requirements is displayed.

Number UN-Code Quantity (l/kg), opt. note
See requirements
Combination packagings(collapsed)
Combination packagings
Code
Packing methods(collapsed)
Packing method
Notice For this substance or article no packing procedure applies.
Intermediate bulk containers (IBC)(collapsed)
Intermediate bulk containers (IBC)
Permission Transport in intermediate bulk containers (IBCs) is not permitted.
Number UN-Code Permission Requirements
0
Large packagings(collapsed)
Permission Transport in large packagings is generally permitted.
Instructions
LP903,
LP904,
LP905,
LP906
Inner packaging Intermediate packaging Outer packaging
Not necessary
Not necessary
Steel (50A),
Aluminium (50B),
Metal other than steel or aluminium (50N),
Rigid plastics (50H),
Natural wood (50D),
Plywood (50D),
Reconstituted wood (50F),
Fibreboard (50G)

This instruction applies to large cells with a gross mass of more than 500 g, large batteries with a gross mass of more than 12 kg, and equipment containing large cells or large batteries of UN Nos. 3090, 3091, 3480, 3481, 3551 and 3552. The following large packagings are authorized for cells, batteries and equipment containing cells or batteries, provided that the general provisions of 4.1.1 and 4.1.3 are met: The rigid large packagings shall met the packing group II performance level. Cells, batteries or equipment shall be placed in inner packagings or separated by other suitable means, such as placement in trays or by dividers, to ensure protection against damage that may be caused under normal conditions of transport by: (a) its movement or placement within the large packaging; (b) contact with other cells, batteries or equipment within the large packaging; and (c) any loads arising from the superimposed weight of cells, batteries, equipment and packaging components above the cell, battery or equipment within the large packaging. When multiple cells, batteries or items of equipment, are packed in the large packaging, bags (e.g. plastics) alone shall not be used to satisfy these requirements. Additional requirement: Batteries shall be protected against short circuit.

Inner packaging Intermediate packaging Outer packaging
Not necessary
Not necessary
Steel (50A),
Aluminium (50B),
Metal other than steel or aluminium (50N),
Rigid plastics (50H),
Plywood (50D)

This instruction applies to single damaged or defective batteries and to single items of equipment containing damaged or defective cells or batteries of UN Nos. 3090, 3091, 3480 , 3481, 3551 and 3552. The general provisions of 4.1.1 and 4.1.3 shall be met. The rigid large packagings shall met the packing group II performance level. Large packagings shall also meet the following requirements: (a) The damaged or defective battery or equipment containing such cells or batteries shall be individually packed in an inner packaging and placed inside of an outer packaging. The inner packaging or outer packaging shall be leakproof to prevent the potential release of electrolyte. (b) The inner packaging shall be surrounded by sufficient non-combustible and electrically non-conductive thermal insulation material to protect against a dangerous evolution of heat. (c) Sealed packagings shall be fitted with a venting device when appropriate. (d) Appropriate measures shall be taken to minimize the effects of vibrations and shocks, prevent movement of the battery or the equipment within the package that may lead to further damage and a dangerous condition during transport. Cushioning material that is non-combustible and electrically non-conductive may also be used to meet this requirement. (e) The non-combustibility of the thermal insulation material and the cushioning material shall be assessed according to a standard recognized in the country where the packaging is designed or manufactured. For leaking batteries and cells, sufficient inert absorbent material shall be added to the inner or outer packaging to absorb any release of electrolyte. Additional requirement: Batteries and cells shall be protected against short circuit.

Inner packaging Intermediate packaging Outer packaging
Not necessary
Not necessary
Steel (50A),
Aluminium (50B),
Metal other than steel or aluminium (50N),
Rigid plastics (50H),
Natural wood (50D),
Plywood (50D),
Reconstituted wood (50F),
Fibreboard (50G)

The general provisions of 4.1.1 and 4.1.3 shall be met. This instruction applies to UN Nos. 3090, 3091, 3480, 3481, 3551 and 3552 production runs consisting of not more than 100 cellsor batteries and to pre-production prototypes of cells or batteries when these prototypes are transported for testing. The large packagings are authorized for a single battery and for a single item of equipment containing cells or batteries, provided that the general provisions of 4.1.1 and 4.1.3 are met: (1) For a single battery: The rigid large packagings shall met the packing group II performance level. Large packagings shall also meet the following requirements: (a) A battery of different size, shape or mass may be packed in an outer packaging of a tested design type listed above provided the total gross mass of the package does not exceed the gross mass for which the design type has been tested; (b) The battery shall be packed in an inner packaging and placed inside the outer packaging; (c) The inner packaging shall be completely surrounded by sufficient non-combustible and electrically non-conductive thermal insulation material to protect against a dangerous evolution of heat; (d) Appropriate measures shall be taken to minimize the effects of vibration and shocks and prevent movement of the battery within the package that may lead to damage and a dangerous condition during transport. When cushioning material is used to meet this requirement it shall be non-combustible and electrically non-conductive; and (e) The non-combustibility of the thermal insulation material and the cushioning material shall be assessed according to a standard recognized in the country where the large packaging is designed or manufactured. (2) For a single item of equipment containing cells or batteries: The rigid large packagings shall met the packing group II performance level. Large packagings shall also meet the following requirements: (a) A single item of equipment of different size, shape or mass may be packed in an outer packaging of a tested design type listed above provided the total gross mass of the package does not exceed the gross mass for which the design type has been tested; (b) The equipment shall be constructed or packed in such a manner as to prevent accidental operation during transport; (c) Appropriate measures shall be taken to minimize the effects of vibration and shocks and prevent movement of the equipment within the package that may lead to damage and a dangerous condition during transport. When cushioning material is used to meet this requirement, it shall be non-combustible and electrically non-conductive; and (d) The non-combustibility of the cushioning material shall be assessed according to a standard recognized in the country where the large packaging is designed or manufactured. Additional requirement: Cells and batteries shall be protected against short circuit.

Inner packaging Intermediate packaging Outer packaging
Not necessary
Not necessary
Steel (50A),
Aluminium (50B),
Metal other than steel or aluminium (50N),
Rigid plastics (50H),
Natural wood (50D),
Plywood (50D),
Fibreboard (50G)

This instruction applies to damaged or defective batteries of UN Nos. 3090, 3091, 3480, 3481, 3551 und 3552 liable to rapidly disassemble, dangerously react, produce a flame or a dangerous evolution of heat or a dangerous emission of toxic, corrosive or flammable gases or vapours under normal conditions of transport. The general provisions of 4.1.1 and 4.1.3 shall be met. For batteries and items of equipment containing batteries, the rigid large packagings shall conform to the packing group I performance level. (1) The large packaging shall be capable of meeting the following additional performance requirements in case of rapid disassembly, dangerous reaction, production of a flame or a dangerous evolution of heat or a dangerous emission of toxic, corrosive or flammable gases or vapours of the battery: (a) The outside surface temperature of the completed package shall not have a temperature of more than 100°C. A momentary spike in temperature up to 200°C is acceptable; (b) No flame shall occur outside the package; (c) No projectiles shall exit the package; (d) The structural integrity of the package shall be maintained; and (e) The large packagings shall have a gas management system (e.g. filter system, air circulation, containment for gas, gas tight packaging etc.), as appropriate. (2) The additional large packaging performance requirements shall be verified by a test as specified by the competent authority.* A verification report shall be made available on request. As a minimum requirement, the name of the batteries, their type as defined in Section 38.3.2.3 of the Manual of Tests and Criteria, the maximum number of batteries, the total mass of batteries, the total energy content of the batteries, the large packaging identification and the test data according to the verification method as specified by the competent authority shall be listed in the verification report. A set of specific instructions describing the way to use the package shall also be part of the verification report. (3) When dry ice or liquid nitrogen is used as a coolant, the requirements of section 5.5.3 shall apply. The inner packaging and outer packaging shall maintain their integrity at the temperature of the refrigerant used as well as the temperatures and the pressures which could result if refrigeration were lost. (4) The specific instructions for use of the package shall be made available by the packaging manufacturers and subsequent distributors to the consignor. They shall include at least the identification of the batteries and items of equipment that may be contained inside the packaging, the maximum number of batteries contained in the package and the maximum total of the batteries energy content, as well as the configuration inside the package, including the separations and protections used during the performance verification test. * The following criteria, as relevant, may be considered to assess the performance of the large packaging: (a) The assessment shall be done under a quality management system (as described e.g. in section 2.9.4.5) allowing for the traceability of tests results, reference data and characterization models used; (b) The list of hazards expected in case of thermal runaway for the battery type, in the condition it is transported (e.g. usage of an inner packaging, state of charge (SOC), use of sufficient non-combustible, electrically non-conductive and absorbent cushioning material etc.), shall be clearly identified and quantified; the reference list of possible hazards for batteries (e.g. rapidly disassemble, dangerously react, produce a flame or a dangerous evolution of heat or a dangerous emission of toxic, corrosive or flammable gases or vapours) can be used for this purpose. The quantification of these hazards shall rely on available scientific literature; (c) The mitigating effects of the large packaging shall be identified and characterized, based on the nature of the protections provided and the construction material properties. A list of technical characteristics and drawings shall be used to support this assessment (density [kg/m³], specific heat capacity [J/(kg·K)], heating value [kJ/kg], thermal conductivity [W/(m·K)], melting temperature and flammability temperature [K], heat transfer coefficient of the outer packaging [W/(m²·K)], …); (d) The test and any supporting calculations shall assess the result of a thermal run-away of the battery inside the large packaging in the normal conditions of transport; (e) In case the SOC of the battery is not known, the assessment used shall be done with the highest possible SOC corresponding to the battery use conditions; (f) The surrounding conditions in which the large packaging may be used and transported shall be described (including for possible consequences of gas or smoke emissions on the environment, such as ventilation or other methods) according to the gas management system of the large packaging; (g) The tests or the model calculation shall consider the worst case scenario for the thermal runaway triggering and propagation inside the battery: this scenario includes the worst possible failure in the normal transport condition, the maximum heat and flame emissions for the possible propagation of the reaction; (h) These scenarios shall be assessed over a period long enough to allow all the possible consequences to occur (e.g. 24 hours). (i) In the case of multiple batteries and multiple items of equipment containing batteries, additional requirements such as the maximum number of batteries and items of equipment, the total maximum energy content of the batteries, and the configuration inside the package, including separations and protections of the parts, shall be considered.

Bulk(collapsed)
Bulk
The transport of that substance in bulk (IMSBC Code) on sea-vessels is: forbidden
Remark(s)
Bulk container(collapsed)
Bulk container
The transport in bulk conainers is according to subsection 4.3.1.1: forbidden
Special requirements according to 4.3
Tanks(collapsed)
Tanks
UN Tanks
Permissibility Transport in portable tanks (UN tanks) is not permitted.
Tank instruction Carriage in tanks is not authorized.
Additional information
Substance-related remark Carriage in tanks is not authorized.

Exceptions(collapsed)

The following is a list of exceptions from the regulations on the transport of dangerous goods (Gefahrgut-Ausnahmeverordnung - GGAV 2002, PDF (German)), which may be relevant for the current substance for transport within Germany.
The scope of the GGAV refers to the GGVSEB (Gefahrgutverordnung Straße, Eisenbahn und Binnenschifffahrt) and GGVSee (Gefahrgutverordnung See).

Exception Title Validity
8 B unlimited
18 S 30.06.2027
20 S E B 30.06.2027
31 S 30.06.2027
32 S E unlimited
33 M unlimited
34 M unlimited

The Memorandum of Understanding for the transport of packaged dangerous goods by Ro/Ro ships in the Baltic Sea is a further exception in accordance with section 7 paragraph 2 of the GGVSee in conjunction with section 7.9.1 of the IMDG Code.


Special transport provisions(collapsed)
Security provisions
This substance/article is NOT a high consequence dangerous good.
Chapter 1.4 Security provisions

Mixed packing(collapsed)

The mixed packing of two or more dangerous goods is only permitted if the goods are compatible with each other. According to 7.2.2.1, two substances or articles are considered incompatible if, as a result of their being packed or stowed together, unacceptable hazards may arise in the event of leakage or escape of the contents or in the event of any other accident.

Note:
For guidance, refer to the general stowage and segregation instructions and to the segregation table in the section on mixed loading/stowage/segregation.

Note on mixed packing of limited quantities (3.4.4.1):
Different dangerous goods in limited quantities may be packed together in an outer packaging provided that the segregation provisions of Chapter 7.2 are taken into account and the goods do not react dangerously with each other in the event of leakage.


Mixed Loading, Stowage, Segregation(collapsed)
Segregation
 This substance or article is classified as dangerous good.
The table below provides information about which general segregation provisions shall be applied to the individual classes.
Since the properties of the substances or objects in the individual classes can be very different, you should always check the dangerous goods list to see whether special segregagtion provisions need to be applied. In the event of conflicting regulations, these take precedence over the general regulations.
A single secondary hazard must also be taken into account for the segregation.
Class 1.1
Class 1.2
Class 1.3
Class 1.4
Class 1.5
Class 1.6
Class 2.1
Class 2.2
Class 2.3
Class 3
Class 4.1
Class 4.2
Class 4.3
Class 5.1
Class 5.2
Class 6.1
Class 6.2
Class 7
Class 8
Class 9
General segregation provisions
No additional segregation provisions in column 16b of the dangerous goods list
Precautions with respect to foodstuffs and animal feeds: no
Stowage
Stowage category
Stowage category
General stowage provisions
Special stowage provisions
Special stowage provisions
Handling
Handling: No handlings provisions in column 16a of the dangerous goods list
Regulations for stowage and segregation for bulk cargoes (IMSBC-Code)
not stated - carriage in bulk is forbidden

Links to external databases(collapsed)