Detailinfo RID 2025
The BAM name is based on the "name and description" from the regulations and the IUPAC rules, but may be supplemented with further information so that significant differences between two dangerous goods data sets are apparent.
| Language | BAM name |
|---|---|
| German | Aluminiumalkylbromide, flüssig, pyrophor |
| English | Aluminium alkyl bromides, liquid, pyrophoric |
| French | Bromures d'alkylaluminium, liquides pyrophoriques |
The aggregate state is given under normal conditions, i.e. at room temperature of 20 °C and normal pressure of 101.3 kPa.
| Aggregate state | |
|---|---|
| under normal conditions | liquid |
| during transport | liquid |
The formula describes the chemical composition of a substance.
| Formula |
|---|
The BAM number is used to uniquely identify a substance or object in the BAM dangerous goods data pool.
| BAM no. | 5102 |
|---|---|
| CAS no. | |
| EC no. | |
| Index no. | |
| ZVG nos. | |
| NHM codes |
293100
|
| General | |
|---|---|
| UN no. | 3394 |
| Class |
|
| Labels |
4.2 +
4.3
|
| Packing group |
|
| Compatibility group | |
| Special provisions |
|
| Land transport | |
|---|---|
| Classification code |
|
| Transport category | 0 |
| Hazard identification number |
|
| Transport status | |
|---|---|
| allowed |
Remark (german): Die UN-Nr. 3052 wurde zum 01.01.2007 gestrichen, daher muss dieser Stoff unter der Sammeleintragung UN-Nr. 3394 befördert werden.
| German | PYROPHORER METALLORGANISCHER FLÜSSIGER STOFF, MIT WASSER REAGIEREND (-technischer Name-) |
|---|---|
| English | ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (-technical name-) |
| English | ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE |
|---|---|
| German | PYROPHORER METALLORGANISCHER FLÜSSIGER STOFF, MIT WASSER REAGIEREND |
| Transport status of this substance/article | allowed | ||
|---|---|---|---|
| Label / Mark |
|
|---|---|
| Label / Mark | |
|---|---|
| Notice | not stated - the carriage in intermediate bulk containers (IBCs) is forbidden. |
| Label / Mark | |
|---|---|
| Notice | not stated - carriage in large packagings is forbidden |
| Placard / Mark |
|
|---|---|
| Orange plate |
|
| Warnings | DO NOT OPEN DURING CARRIAGE. LIABLE TO SPONTANEOUS COMBUSTION. |
| Placard / Mark |
|
|---|---|
| Orange plate |
|
| Placard / Mark |
|
|---|---|
| Orange plate |
|
| Placard / Mark | |
|---|---|
| Orange plate | |
| Notice | not stated - carriage in bulk is forbidden |
| Placard / Mark | |
|---|---|
| Orange plate | |
| Notice | not stated - carriage in RID MEGC/battery-wagons and UN MEGC is not authorized |
Values in "ml" and "L" refer to substances that are liquid under normal conditions (temperature 20 °C, density 1013 mbar). Values in "g" and "kg" refer to substances that generally have a melting point greater than 20 °C. Solid substances that can liquefy during transport may only be transported in packagings that are suitable for liquids (paper bags, for example, are not permitted).
No exemption according to the provisions of Chapter 3.4 possible
E0, No exemption according to the provisions of Chapter 3.5 possible
| Permission | Transport in packagings is generally permitted. |
|---|---|
| Instructions | P400 |
| Special provisions | |
| Requirements | Show requirements |
Unless otherwise stated, the quantities indicated for the packagings in the table below refer to the maximum capacity (in litres, "l") or the maximum net mass (in kilograms, "kg"). For some quantities, an additional note with the requirements is displayed.
| Number | UN-Code | Quantity (l/kg), opt. note |
|---|---|---|
| See requirements | ||
| Code | |
|---|---|
| Special Provisiona/Remarks |
| Notice | For this substance or article no packing procedure applies. |
|---|
| Permission | Transport in intermediate bulk containers (IBCs) is not permitted. |
|---|
| Number | UN-Code | Permission | Requirements |
|---|---|---|---|
| 0 |
| Permission | Transport in large packagings is not permitted. |
|---|---|
| Notice | not stated - carriage in large packagings is forbidden |
| The transport in bulk is according to subsection 7.3.1.1b): | forbidden |
|---|---|
| Special requirements according to 7.3.3 |
| The transport in bulk conainers is according to subsection 7.3.1.1a): | forbidden |
|---|---|
| Special requirements according to 7.3.2 |
| Permissibility | Transport in tanks is generally permitted. |
|---|---|
| RID Tanks | |
| Permissibility | Transport in ADR/RID tanks is generally permitted. |
| Tank code | |
| Special provisions |
,
,
,
,
,
,
,
,
|
| UN Tanks | |
|---|---|
| Permissibility | Transport in portable tanks (UN tanks) is permitted. |
| Tank instruction | |
| Special provisions |
,
,
,
|
| Additional information | |
|---|---|
| Substance-related remark | |
The following is a list of exceptions from the regulations on the transport of dangerous goods (Gefahrgut-Ausnahmeverordnung - GGAV 2002, PDF (German)), which may be relevant for the current substance for transport within Germany.
The scope of the GGAV refers to the GGVSEB (Gefahrgutverordnung Straße, Eisenbahn und Binnenschifffahrt) and GGVSee (Gefahrgutverordnung See).
| Exception | Title | Validity |
|---|---|---|
| 8 B | unlimited | |
| 18 S | 30.06.2027 | |
| 31 S | 30.06.2027 | |
| 32 S E | unlimited | |
| 34 M | unlimited |
The Memorandum of Understanding for the transport of packaged dangerous goods by Ro/Ro ships in the Baltic Sea is a further exception in accordance with section 7 paragraph 2 of the GGVSee in conjunction with section 7.9.1 of the IMDG Code.
The following agreements may be important for transport in Germany.
| Agreement | Instruction type | Title, Publication status, Signatory states | Validity |
|---|---|---|---|
| none valid in Germany | |||
| Provision |
|
|---|---|
Unless otherwise provided, packages may be loaded:
|
|
| Provision | Forwarding as Colis Express (express parcels) is not permitted according to Chapter 3.2 Table A and Chapter 7.6. |
|---|
| High consequence dangerous good according to table 1.10.3.1.2 "Indicative List of High Consequence Dangerous Goods"! | |
| Chapter 1.10 Security Provisions | |
|---|---|
| Amounts: Exceeding the amounts mentioned below leads to a classification as a high consequence dangerous good: | |
| Packages [kg] | The provisions of 1.10.3 do not apply, whatever the quantity is. |
| Bulk [kg] | not relevant |
| Tank [litres] | High consequence dangerous good where the quantity of the substance carried exceeds 3000 l. |
According to Table A, Chapter 3.2 of ADR/RID, the following encodings apply:
| Encodings |
|
|---|
Section 4.1.10 applies:
4.1.10 Special provisions for mixed packing
4.1.10.1 When mixed packing is permitted in accordance with the provisions of this section, different dangerous goods or dangerous goods and other goods may be packed together in combination packagings conforming to 6.1.4.21, provided that they do not react dangerously with one another and that all other relevant provisions of this Chapter are complied with.
NOTE 1: See also 4.1.1.5 and 4.1.1.6.
NOTE 2: For radioactive material, see 4.1.9.
4.1.10.2 Except for packages containing Class 1 goods only or Class 7 goods only, if wooden or fibreboard boxes are used as outer packagings, a package containing different goods packed together shall not weigh more than 100 kg.
4.1.10.3 Unless otherwise prescribed by a special provision applicable according to 4.1.10.4, dangerous goods of the same class and the same classification code may be packed together.
See also subsections 4.1.1.5 and 4.1.1.6, section 5.1.4 and subsection 6.1.4.21:
4.1.1.5 Inner packagings shall be packed in an outer packaging in such a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents into the outer packaging. Inner packagings containing liquids shall be packed with their closures upward and placed within outer packagings consistent with the orientation marks prescribed in 5.2.1.10. Inner packagings that are liable to break or be punctured easily, such as those made of glass, porcelain or stoneware or of certain plastics materials, etc., shall be secured in outer packagings with suitable cushioning material. Any leakage of the contents shall not substantially impair the protective properties of the cushioning material or of the outer packaging.
4.1.1.5.1 Where an outer packaging of a combination packaging or a large packaging has been successfully tested with different types of inner packagings, a variety of such different inner packagings may also be assembled in this outer packaging or large packaging. In addition, provided an equivalent level of performance is maintained, the following variations in inner packagings are allowed without further testing of the package:
- Inner packagings of equivalent or smaller size may be used provided:
- the inner packagings are of similar design to the tested inner packagings (e.g. shape – round, rectangular, etc.);
- the material of construction of the inner packagings (glass, plastics, metal, etc.) offers resistance to impact and stacking forces equal to or greater than that of the originally tested inner packaging;
- the inner packagings have the same or smaller openings and the closure is of similar design (e.g. screw cap, friction lid, etc.);
- sufficient additional cushioning material is used to take up void spaces and to prevent significant movement of the inner packagings; and
- inner packagings are oriented within the outer packaging in the same manner as in the tested package.
- A lesser number of the tested inner packagings, or of the alternative types of inner packagings identified in (a) above, may be used provided sufficient cushioning is added to fill the void space(s) and to prevent significant movement of the inner packagings.
4.1.1.6 Dangerous goods shall not be packed together in the same outer packaging or in large packagings, with dangerous or other goods if they react dangerously with each other and cause:
- combustion or evolution of considerable heat;
- evolution of flammable, asphyxiant, oxidizing or toxic gases;
- the formation of corrosive substances; or
- the formation of unstable substances.
[...]
5.1.4 Mixed packing
When two or more dangerous goods are packed within the same outer packaging, the package shall be labelled and marked as required for each substance or article. If the same label is required for different goods, it only needs to be applied once.
6.1.4.21 Combination packagings
The relevant requirements of section 6.1.4 for the outer packagings to be used, are applicable.
NOTE: For the inner and outer packagings to be used, see the relevant packing instructions in Chapter 4.1.
| Class 1 | |
|---|---|
| Class 1.4 | |
| Class 1.5 | |
| Class 1.6 | |
| Class 2.1 | |
| Class 2.2 | |
| Class 2.3 | |
| Class 3 | |
| Class 4.1 | |
| Class 4.1 + 1 | |
| Class 4.2 | |
| Class 4.3 | |
| Class 5.1 | |
| Class 5.2 | |
| Class 5.2 + 1 | |
| Class 6.1 | |
| Class 6.2 | |
| Class 7 | |
| Class 8 | |
| Class 9 | |
| Class 9A |
| Precautions with respect to foodstuffs, other articles of consumption and animal feeds: | no |
|---|
| Additional regulations for special classes or goods: | No special provisions are indicated for this substance/article |
|---|