Hydrazine monohydrobromide, solid

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Detailinfo IMDG-Code, Amdt. 42-24

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Substance information(collapsed)

The BAM name is based on the "name and description" from the regulations and the IUPAC rules, but may be supplemented with further information so that significant differences between two dangerous goods data sets are apparent.

Language BAM name
German Hydrazinmonohydrobromid, fest
English Hydrazine monohydrobromide, solid
French Monohydrobromure d'hydrazine, solide

The aggregate state is given under normal conditions, i.e. at room temperature of 20 °C and normal pressure of 101.3 kPa.

Aggre­gate state
under normal con­di­tions solid
during trans­port solid

The formula describes the chemical composition of a substance.

Formula
H5BrN2

The BAM number is used to uniquely identify a substance or object in the BAM dangerous goods data pool.

BAM no. 1268
CAS no. 13775-80-9
EC no. 237-412-7
Index no. 007-014-00-6
ZVG nos.
3080

Physico-chemical substance information(collapsed)
Properties and remarks
Appearance toxic solid
Colour not specified
Odour not specified
Misci­bility/solu­bility not specified
Impact on human orga­nism Toxic if swallowed, by skin contact or by inhalation.
Addi­tio­nal pro­per­ties/remarks not specified
Reaction with ...
Water not specified
Acids not specified
Alkalis not specified
Metals not specified
Oxidizing substances not specified

Classification(collapsed)
General
UN no. 3288
Class
Sub­si­diary risks
Packing group
Compati­bility group
Spe­cial pro­vi­sions
,
Maritime transport
Marine pollutant
Environ­mentally ha­zar­dous
Emergency Schedules (EmS)
,
MFAG no.
Transport status
allowed

Names(collapsed)
Transport document names 6
German 1 GIFTIGER ANORGANISCHER FESTER STOFF, N.A.G. (Hydrazinmonohydrobromid)
German 2 GIFTIGER ANORGANISCHER FESTER STOFF, N.A.G. (Hydrazinhydrobromid)
German 3 GIFTIGER ANORGANISCHER FESTER STOFF, N.A.G. (Hydraziniumbromid)
German 4 GIFTIGER ANORGANISCHER FESTER STOFF, N.A.G. (Hydrazinmonobromid)
English 1 TOXIC SOLID, INORGANIC, N.O.S. (Hydrazine monohydrobromide)
English 2 TOXIC SOLID, INORGANIC, N.O.S. (Hydrazine monobromide)
Instruction names 2
English TOXIC SOLID, INORGANIC, N.O.S.
German GIFTIGER ANORGANISCHER FESTER STOFF, N.A.G.
Synonyms 0
Synonyms for transport documents 5
English Hydrazine monobromide
German Hydrazinhydrobromid
German Hydraziniumbromid
German Hydrazinmonobromid
French Hydrobromure d'hydrazine
INCI synonyms 0
Synonyms (not recommended) 0

Transport exlusions(collapsed)
Transport status of this substance/article allowed

Labelling(collapsed)
Packagings
Label / Mark
IBC
Label / Mark
Large packagings (LP)
Label / Mark
Tanks
Placard / Mark
Orange plate
Proper shipping name GIFTIGER ANORGANISCHER FESTER STOFF, N.A.G. (Hydrazinhydrobromid)
Vehicles
Placard / Mark
Orange plate
Containers
Placard / Mark
Orange plate
Bulk
Placard / Mark
Orange plate
Notice not stated - carriage in bulk containers is forbidden

Limited and excepted quantities(collapsed)

Values in "ml" and "L" refer to substances that are liquid under normal conditions (temperature 20 °C, density 1013 mbar). Values in "g" and "kg" refer to substances that generally have a melting point greater than 20 °C. Solid substances that can liquefy during transport may only be transported in packagings that are suitable for liquids (paper bags, for example, are not permitted).

Limited quantities(collapsed)

For substances in inner packaging or objects transported in trays with stretch or shrink film instead of outer packaging, other quantities may apply, which can be found in the table below in the column "trays".

Packagings Trays
Max. net quantity per inner packaging 5 kg 5 kg
Maximum brutto mass 30 kg 20 kg
Mark
Please also note the General information on sea transport from Chapter 3.4 "Dangerous goods packed in limited quantities".
Excepted quantities(collapsed)
Code E1
Max. net quantity per inner packaging 30 g
Max. net quantity per outer packaging 1000 g
Mark
Please also note the General information on sea transport from Chapter 3.5 "Dangerous goods packed in excepted quantities".

Containments(collapsed)
Single packagings(collapsed)
Permission Transport in packagings is generally permitted.
Instructions P002
Special provisions
Requirements Show requirements

Unless otherwise stated, the quantities indicated for the packagings in the table below refer to the maximum capacity (in litres, "l") or the maximum net mass (in kilograms, "kg"). For some quantities, an additional note with the requirements is displayed.

Number UN-Code Quantity (l/kg), opt. note
1 0A1 forbidden
2 0A2 forbidden
3 1A1 400 kg
4 1A2 400 kg
5 1B1 400 kg
6 1B2 400 kg
7 1N1 400 kg
8 1N2 400 kg
9 1D 400 kg
10 1G 400 kg
11 1H1 400 kg
12 1H2 400 kg
13 2C1 forbidden
14 2C2 forbidden
15 3A1 120 kg
16 3A2 120 kg
17 3B1 120 kg
18 3B2 120 kg
19 3N1 forbidden
20 3H1 120 kg
21 3H2 120 kg
22 4A 400 kg
23 4B 400 kg
24 4N 400 kg
25 4C1 400 kg
26 4C2 400 kg
27 4D 400 kg
28 4F 400 kg
29 4G 400 kg
30 4H1 forbidden
31 4H2 400 kg
32 5H1 forbidden
33 5H2 forbidden
34 5H3 50 kg
35 5H4 50 kg
36 5L1 forbidden
37 5L2 forbidden
38 5L3 50 kg
39 5M1 forbidden
40 5M2 50 kg
41 6HA1 400 kg
42 6HA2 75 kg
43 6HB1 400 kg
44 6HB2 75 kg
45 6HC 75 kg
46 6HD1 400 kg
47 6HD2 75 kg
48 6HG1 400 kg
49 6HG2 75 kg
50 6HH1 400 kg
51 6HH2 75 kg
52 6PA1 75 kg
53 6PA2 75 kg Note
54 6PB1 75 kg
55 6PB2 75 kg Note
56 6PC 75 kg
57 6PD1 75 kg
58 6PD2 75 kg
59 6PG1 75 kg
60 6PG2 75 kg
61 6PH1 75 kg
62 6PH2 75 kg
Combination packagings(collapsed)
Combination packagings
Code
Packing methods(collapsed)
Packing method
Notice For this substance or article no packing procedure applies.
Intermediate bulk containers (IBC)(collapsed)
Intermediate bulk containers (IBC)
Permission Transport in intermediate bulk containers (IBCs) is generally permitted.
Instructions IBC08
Special provisions
Number UN-Code Permission Requirements
0
1 +
2 +
3 +
4 +
5 +
6 +
7 +
8 +
9 +
10 +
11 +
12 +
13 +
14 +
15 +
16 +
17 +
18 +
19 +
50 +
51 +
52 +
53 +
54 +
55 +
56 +
57 +
58 +
59 +
60 +
61 +
62 +
63 +
64 +
65 +
66 +
67 +
68 +
69 +
70 +
71 +
72 +
73 +
74 +
75 +
76 +
77 +
78 +
79 +
80 +
81 +
82 +
83 +
84 +
85 +
86 +
87 +
88 +
89 +
90 +
91 +
92 +
93 +
94 +
95 +
96 +
97 +
98 +
99 +
100 +
101 +
102 +
103 +
104 +
105 +
106 +
107 +
108 +
109 +
110 +
Large packagings(collapsed)
Permission Transport in large packagings is generally permitted.
Instructions
LP02
Inner packaging Intermediate packaging Outer packaging
Glass (10 kg) ,
Plastics (50 kg) ,
Metal (50 kg) ,
Paper (50 kg) ,
Fibre (50 kg)
Not necessary
Steel (50A),
Aluminium (50B),
Metal other than steel or aluminium (50N),
Rigid plastics (50H),
Natural wood (50D),
Plywood (50D),
Reconstituted wood (50F),
Fibreboard (50G),
Flexible plastics (51H)

The general provisions of 4.1.1 and 4.1.3 shall be met. Inner packagings of plastics, paper or fibre shall be sift-proof. Outer packagings of flexible plastics (51H) shall only be used with flexible inner packagings. The volume of the large packaging may not exceed 3 m³.

Bulk(collapsed)
Bulk
The transport of that substance in bulk (IMSBC Code) on sea-vessels is: forbidden
Remark(s)
Bulk container(collapsed)
Bulk container
The transport in bulk conainers is according to subsection 4.3.1.1: forbidden
Special requirements according to 4.3
Tanks(collapsed)
Tanks
UN Tanks
Permissibility Transport in portable tanks (UN tanks) is permitted.
Tank instruction
Special provisions
Additional information
Substance-related remark

Exceptions(collapsed)

The following is a list of exceptions from the regulations on the transport of dangerous goods (Gefahrgut-Ausnahmeverordnung - GGAV 2002, PDF (German)), which may be relevant for the current substance for transport within Germany.
The scope of the GGAV refers to the GGVSEB (Gefahrgutverordnung Straße, Eisenbahn und Binnenschifffahrt) and GGVSee (Gefahrgutverordnung See).

Exception Title Validity
8 B unlimited
9 S E B unlimited
18 S 30.06.2027
20 S E B 30.06.2027
22 S E unlimited
31 S 30.06.2027
32 S E unlimited
33 M unlimited
34 M unlimited

The Memorandum of Understanding for the transport of packaged dangerous goods by Ro/Ro ships in the Baltic Sea is a further exception in accordance with section 7 paragraph 2 of the GGVSee in conjunction with section 7.9.1 of the IMDG Code.


Further provisions(collapsed)
Security provisions
This substance/article is NOT a high consequence dangerous good.
Chapter 1.4 Security provisions

Mixed packing(collapsed)

The mixed packing of two or more dangerous goods is only permitted if the goods are compatible with each other. According to 7.2.2.1, two substances or articles are considered incompatible if, as a result of their being packed or stowed together, unacceptable hazards may arise in the event of leakage or escape of the contents or in the event of any other accident.

Note:
For guidance, refer to the general stowage and segregation instructions and to the segregation table in the section on mixed loading/stowage/segregation.

Note on mixed packing of limited quantities (3.4.4.1):
Different dangerous goods in limited quantities may be packed together in an outer packaging provided that the segregation provisions of Chapter 7.2 are taken into account and the goods do not react dangerously with each other in the event of leakage.


Mixed Loading, Stowage, Segregation(collapsed)
Segregation
 This substance or article is classified as dangerous good.
The table below provides information about which general segregation provisions shall be applied to the individual classes.
Since the properties of the substances or objects in the individual classes can be very different, you should always check the dangerous goods list to see whether special segregagtion provisions need to be applied. In the event of conflicting regulations, these take precedence over the general regulations.
A single secondary hazard must also be taken into account for the segregation.
Class 1.1
Class 1.2
Class 1.3
Class 1.4
Class 1.5
Class 1.6
Class 2.1
Class 2.2
Class 2.3
Class 3
Class 4.1
Class 4.2
Class 4.3
Class 5.1
Class 5.2
Class 6.1
Class 6.2
Class 7
Class 8
Class 9
General segregation provisions
No additional segregation provisions in column 16b of the dangerous goods list
Precautions with respect to foodstuffs and animal feeds:
Stowage
Stowage category
Stowage category
General stowage provisions
No additional stowage provisions in column 16a of the dangerous goods list
Handling
Handling: No handlings provisions in column 16a of the dangerous goods list
Regulations for stowage and segregation for bulk cargoes (IMSBC-Code)
not stated - carriage in bulk is forbidden

Links to external databases(collapsed)