Phosphorus oxybromide, solid

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Detailinfo ADR 2025

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Substance information(collapsed)

The BAM name is based on the "name and description" from the regulations and the IUPAC rules, but may be supplemented with further information so that significant differences between two dangerous goods data sets are apparent.

Language BAM name
German Phosphoroxybromid, fest
English Phosphorus oxybromide, solid
French Oxybromure de phosphore, solide

The aggregate state is given under normal conditions, i.e. at room temperature of 20 °C and normal pressure of 101.3 kPa.

Aggre­gate state
under normal con­di­tions solid
during trans­port solid

The formula describes the chemical composition of a substance.

Formula
POBr3

The BAM number is used to uniquely identify a substance or object in the BAM dangerous goods data pool.

BAM no. 715
CAS no. 7789-59-5
EC no. 232-177-7
Index no.
ZVG nos.
510666

Classification(collapsed)
General
UN no. 1939
Class
Labels 8
Packing group
Compati­bility group
Spe­cial pro­vi­sions none
Land transport
Classification code
Transport category 2
Hazard identification number
Transport status
allowed

Names(collapsed)
Transport document names 3
German PHOSPHOROXYBROMID
English PHOSPHORUS OXYBROMIDE
French OXYBROMURE DE PHOSPHORE
Instruction names 3
German PHOSPHOROXYBROMID
English PHOSPHORUS OXYBROMIDE
French OXYBROMURE DE PHOSPHORE
Synonyms 0
Synonyms for transport documents 7
French Bromure de phosphoryle
German Phosphoroxidtribromid
English Phosphorus oxide tribromide
English Phosphoryl bromide
German Phosphorylbromid
German Phosphoryltribromid
French Tribromure de phosphoryle
INCI synonyms 0
Synonyms (not recommended) 0

Transport exlusions(collapsed)
Transport status of this substance/article allowed
Verlagerung und Fahrweg im Straßenverkehr nach §35 / §35a der GGVSEB
Restrictions for road tunnels
Tunnel restriction code

Labelling(collapsed)
Packagings
Label / Mark
IBC
Label / Mark
Large packagings (LP)
Label / Mark
Notice not stated - carriage in large packagings is forbidden
Tanks
Placard / Mark
Orange plate
Warnings No additional warnings are required on the tank.
Vehicles
Placard / Mark
Orange plate
Notice not stated - no placards/markings required
Quantity according to 1.1.3.6
Containers
Placard / Mark
Orange plate
Quantity according to 1.1.3.6
Bulk
Placard / Mark
Orange plate
Notice not stated - carriage in bulk is forbidden
UN multiple-element gas containers (MEGCs)
Placard / Mark
Orange plate
Notice not stated - carriage in ADR MEGC/battery-vehicles and UN MEGC is not authorized

Limited and excepted quantities(collapsed)

Values in "ml" and "L" refer to substances that are liquid under normal conditions (temperature 20 °C, density 1013 mbar). Values in "g" and "kg" refer to substances that generally have a melting point greater than 20 °C. Solid substances that can liquefy during transport may only be transported in packagings that are suitable for liquids (paper bags, for example, are not permitted).

Limited quantities(collapsed)

For substances in inner packaging or objects transported in trays with stretch or shrink film instead of outer packaging, other quantities may apply, which can be found in the table below in the column "trays".

Packagings Trays
Max. net quantity per inner packaging 1 kg 1 kg
Maximum brutto mass 30 kg 20 kg
Mark
Please also note the General information on inland transport from Chapter 3.4 "Dangerous goods packed in limited quantities".
Excepted quantities(collapsed)

E0, No exemption according to the provisions of Chapter 3.5 possible

Exemption according to subsection 1.1.3.6(collapsed)

If several dangerous goods with different transport categories or maximum permissible quantities in packages are transported in one transport unit, the total calculated in accordance with subsection 1.1.3.6 shall not exceed 1,000.

Limited quantity according to 1.1.3.6 333 kg
Trans­port cate­gory 2
Please also note the Extracts from ADR, subsection 1.1.3.6.

Containments(collapsed)
Single packagings(collapsed)
Permission Transport in packagings is generally permitted.
Instructions P002
Special provisions
Requirements Show requirements

Unless otherwise stated, the quantities indicated for the packagings in the table below refer to the maximum capacity (in litres, "l") or the maximum net mass (in kilograms, "kg"). For some quantities, an additional note with the requirements is displayed.

Number UN-Code Quantity (l/kg), opt. note
1 0A1 forbidden
2 0A2 forbidden
3 1A1 400 kg
4 1A2 400 kg
5 1B1 400 kg
6 1B2 400 kg
7 1N1 400 kg
8 1N2 400 kg
9 1D 400 kg
10 1G 400 kg
11 1H1 400 kg
12 1H2 400 kg
13 2C1 forbidden
14 2C2 forbidden
15 3A1 120 kg
16 3A2 120 kg
17 3B1 120 kg
18 3B2 120 kg
19 3N1 forbidden
20 3H1 120 kg
21 3H2 120 kg
22 4A 400 kg
23 4B 400 kg
24 4N 400 kg
25 4C1 400 kg
26 4C2 400 kg
27 4D 400 kg
28 4F 400 kg
29 4G 400 kg
30 4H1 forbidden
31 4H2 400 kg
32 5H1 forbidden
33 5H2 forbidden
34 5H3 50 kg
35 5H4 50 kg
36 5L1 forbidden
37 5L2 forbidden
38 5L3 50 kg
39 5M1 forbidden
40 5M2 50 kg
41 6HA1 400 kg
42 6HA2 75 kg
43 6HB1 400 kg
44 6HB2 75 kg
45 6HC 75 kg
46 6HD1 400 kg
47 6HD2 75 kg
48 6HG1 400 kg
49 6HG2 75 kg
50 6HH1 400 kg
51 6HH2 75 kg
52 6PA1 75 kg
53 6PA2 75 kg
54 6PB1 75 kg
55 6PB2 75 kg
56 6PC 75 kg
57 6PD1 75 kg
58 6PD2 75 kg
59 6PG1 75 kg
60 6PG2 75 kg
61 6PH1 75 kg
62 6PH2 75 kg
Combination packagings(collapsed)
Combination packagings
Code
Packing methods(collapsed)
Packing method
Notice For this substance or article no packing procedure applies.
Intermediate bulk containers (IBC)(collapsed)
Intermediate bulk containers (IBC)
Permission Transport in intermediate bulk containers (IBCs) is generally permitted.
Instructions IBC08
Special provisions
Number UN-Code Permission Requirements
0
1 +
2 +
3 +
4 +
5 +
6 +
7 +
8 +
9 +
10 +
11 +
12 +
13 +
14 +
15 +
16 +
17 +
18 +
19 +
50 +
51 +
52 +
53 +
54 +
55 +
56 +
57 +
58 +
59 +
60 +
61 +
62 +
63 +
64 +
65 +
66 +
67 +
68 +
69 +
70 +
71 +
72 +
73 +
74 +
75 +
76 +
77 +
78 +
79 +
80 +
81 +
82 +
83 +
84 +
85 +
86 +
87 +
88 +
89 +
90 +
91 +
92 +
93 +
94 +
95 +
96 +
97 +
98 +
99 +
100 +
101 +
102 +
103 +
104 +
105 +
106 +
107 +
108 +
109 +
110 +
Large packagings(collapsed)
Permission Transport in large packagings is not permitted.
Notice not stated - carriage in large packagings is forbidden
Bulk(collapsed)
Bulk
The transport in bulk is according to subsection 7.3.1.1b): forbidden
Special requirements according to 7.3.3
Bulk container(collapsed)
Bulk container
The transport in bulk conainers is according to subsection 7.3.1.1a): forbidden
Special requirements according to 7.3.2
Tanks(collapsed)
Tanks
Permissibility Transport in tanks is generally permitted.
ADR Tanks
Permissibility Transport in ADR/RID tanks is generally permitted.
Tank code
Special provisions
Vehicle for tank carriage
UN Tanks
Permissibility Transport in portable tanks (UN tanks) is permitted.
Tank instruction
Special provisions
Additional information
Substance-related remark

Exceptions(collapsed)

The following is a list of exceptions from the regulations on the transport of dangerous goods (Gefahrgut-Ausnahmeverordnung - GGAV 2002, PDF (German)), which may be relevant for the current substance for transport within Germany.
The scope of the GGAV refers to the GGVSEB (Gefahrgutverordnung Straße, Eisenbahn und Binnenschifffahrt) and GGVSee (Gefahrgutverordnung See).

Exception Title Validity
8 B unlimited
9 S E B unlimited
18 S 30.06.2027
20 S E B 30.06.2027
22 S E unlimited
31 S 30.06.2027
32 S E unlimited
33 M unlimited
34 M unlimited

The Memorandum of Understanding for the transport of packaged dangerous goods by Ro/Ro ships in the Baltic Sea is a further exception in accordance with section 7 paragraph 2 of the GGVSee in conjunction with section 7.9.1 of the IMDG Code.


Agreements(collapsed)

The following agreements may be important for transport in Germany.

Agree­ment Instruc­tion type Title, Publication status, Signatory states Validity
none valid in Germany

Further provisions(collapsed)
Package provisions
Provision
Unless otherwise provided, packages may be loaded:
  1. in closed vehicles or in closed containers; or
  2. in sheeted vehicles or in sheeted containers; or
  3. in open vehicles or in open containers.
Requirements for equipment and operation
According to chapter 8.1 ADR the following requirements concerning transport units and equipment on board apply
Additional requirements No special provisions are indicated for this substance/article
Security provisions
This substance/article is NOT a high consequence dangerous good.
Chapter 1.10 Security Provisions

Mixed packing(collapsed)

According to Table A, Chapter 3.2 of ADR/RID, the following encodings apply:

Encodings

Section 4.1.10 applies:

4.1.10 Special provisions for mixed packing

4.1.10.1 When mixed packing is permitted in accordance with the provisions of this section, different dangerous goods or dangerous goods and other goods may be packed together in combination packagings conforming to 6.1.4.21, provided that they do not react dangerously with one another and that all other relevant provisions of this Chapter are complied with.

NOTE 1: See also 4.1.1.5 and 4.1.1.6.
NOTE 2: For radioactive material, see 4.1.9.

4.1.10.2 Except for packages containing Class 1 goods only or Class 7 goods only, if wooden or fibreboard boxes are used as outer packagings, a package containing different goods packed together shall not weigh more than 100 kg.

4.1.10.3 Unless otherwise prescribed by a special provision applicable according to 4.1.10.4, dangerous goods of the same class and the same classification code may be packed together.

See also subsections 4.1.1.5 and 4.1.1.6, section 5.1.4 and subsection 6.1.4.21:

4.1.1.5 Inner packagings shall be packed in an outer packaging in such a way that, under normal conditions of carriage, they cannot break, be punctured or leak their contents into the outer packaging. Inner packagings containing liquids shall be packed with their closures upward and placed within outer packagings consistent with the orientation marks prescribed in 5.2.1.10. Inner packagings that are liable to break or be punctured easily, such as those made of glass, porcelain or stoneware or of certain plastics materials, etc., shall be secured in outer packagings with suitable cushioning material. Any leakage of the contents shall not substantially impair the protective properties of the cushioning material or of the outer packaging.

4.1.1.5.1 Where an outer packaging of a combination packaging or a large packaging has been successfully tested with different types of inner packagings, a variety of such different inner packagings may also be assembled in this outer packaging or large packaging. In addition, provided an equivalent level of performance is maintained, the following variations in inner packagings are allowed without further testing of the package:

  1. Inner packagings of equivalent or smaller size may be used provided:
    1. the inner packagings are of similar design to the tested inner packagings (e.g. shape – round, rectangular, etc.);
    2. the material of construction of the inner packagings (glass, plastics, metal, etc.) offers resistance to impact and stacking forces equal to or greater than that of the originally tested inner packaging;
    3. the inner packagings have the same or smaller openings and the closure is of similar design (e.g. screw cap, friction lid, etc.);
    4. sufficient additional cushioning material is used to take up void spaces and to prevent significant movement of the inner packagings; and
    5. inner packagings are oriented within the outer packaging in the same manner as in the tested package.
  2. A lesser number of the tested inner packagings, or of the alternative types of inner packagings identified in (a) above, may be used provided sufficient cushioning is added to fill the void space(s) and to prevent significant movement of the inner packagings.

4.1.1.6 Dangerous goods shall not be packed together in the same outer packaging or in large packagings, with dangerous or other goods if they react dangerously with each other and cause:

  1. combustion or evolution of considerable heat;
  2. evolution of flammable, asphyxiant, oxidizing or toxic gases;
  3. the formation of corrosive substances; or
  4. the formation of unstable substances.

[...]

5.1.4 Mixed packing

When two or more dangerous goods are packed within the same outer packaging, the package shall be labelled and marked as required for each substance or article. If the same label is required for different goods, it only needs to be applied once.

6.1.4.21 Combination packagings

The relevant requirements of section 6.1.4 for the outer packagings to be used, are applicable.

NOTE: For the inner and outer packagings to be used, see the relevant packing instructions in Chapter 4.1.


Mixed Loading, Stowage, Segregation(collapsed)
Mixed loading (with other dangerous goods)
 This substance or article is classified as dangerous good.
Packages bearing different danger labels shall not be loaded together in the same vehicle or container unless mixed loading is permitted according to the following Table based on the danger labels they bear.
Class 1
Class 1.4
Class 1.5
Class 1.6
Class 2.1
Class 2.2
Class 2.3
Class 3
Class 4.1
Class 4.1 + 1
Class 4.2
Class 4.3
Class 5.1
Class 5.2
Class 5.2 + 1
Class 6.1
Class 6.2
Class 7
Class 8
Class 9
Class 9A
Segregation (from other goods)
Precautions with respect to foodstuffs, other articles of consumption and animal feeds: no
Handling
Additional regulations for special classes or goods: No special provisions are indicated for this substance/article

Links to external databases(collapsed)