UN 3077 tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) + C12-14-tert-alkylammonium((1-(4(or 5)-nitro-2-oxidophenylazo)-2-naphtholato)(1-(3-nitro-2-oxido-5-pentylphenylazo)-2-naphtholato))chromat(1-), mixture RID 2025 (Shortinfo)

BAM name (German)	tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalinolato(2-)]-chromat(1-) + tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphthalinolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalinolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalinolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalinolato(2-)]]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalinolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalinolato(2-)]]-chromat(1-) + C12-14-tert-Alkylammonium((1-(4(oder 5)-nitro-2-oxidophenylazo)-2-naphtholato)(1-(3-nitro-2-oxido-5-pentylphenylazo)-2-naphtholato))chromat(1-), Gemisch
BAM name (English)	tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) + C12-14-tert-alkylammonium((1-(4(or 5)-nitro-2-oxidophenylazo)-2-naphtholato)(1-(3-nitro-2-oxido-5-pentylphenylazo)-2-naphtholato))chromat(1-), mixture
BAM name (French)	Bis[1-[(2-hydroxy-5-nitrophényl)azo]-2-naphtalènolato(2-)]-chromate(1-) de tert-alkyl(C12-C14)ammonium + bis[1-[(2-hydroxy-4-nitrophényl)azo]-2-naphtalènolato(2-)]-chromate(1-) de tert-alkyl(C12-C14)ammonium + bis[1-[[5-(1,1-diméthylpropyl)-2-hydroxy-3-nitrophényl]azo]-2-naphtalènolato(2-)]-chromate(1-) de tert-alkyl(C12-C14)ammonium + [[1-[(2-hydroxy-5-nitrophényl)azo]-2-naphtalènolato(2-)]-[1-[(2-hydroxy-5-nitrophényl)azo]-2-naphtalènolato(2-)]]-chromate(1-) de tert-alkyl(C12-C14)ammonium + [[1-[[5-(1,1-diméthylpropyl)-2-hydroxy-3-nitrophényl]azo]-2-naphtalènolato(2-)]-[1-[(2-hydroxy-5-nitrophényl)azo]-2-naphtalènolato(2-)]]-chromate(1-) de tert-alkyl(C12-C14)ammonium + ((1-(4(ou 5)-nitro-2-oxydophénylazo)-2-naphtolato)(1-(3-nitro-2-oxydo-5-pentylphénylazo)-2-naphtolato))chromate(1-) de C12-14-tert-alkylammonium, en mélange
Aggregate state (under normal conditions)	solid
BAM No.	10085
CAS No.	117527-94-3
Detailinfo

German	UMWELTGEFÄHRDENDER STOFF, FEST, N.A.G. (tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalinolato(2-)]-chromat(1-), tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphthalinolato(2-)]-chromat(1-), tert-alkyl(C12-C14)ammonium-bis[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalinolato(2-)]-chromat(1-), tert-alkyl(C12-C14)ammonium-[[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalinolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalinolato(2-)]]-chromat(1-), tert-alkyl(C12-C14)ammonium-[[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalinolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalinolato(2-)]]-chromat(1-) und C12-14-tert-Alkylammonium((1-(4(oder 5)-nitro-2-oxidophenylazo)-2-naphtholato)(1-(3-nitro-2-oxido-5-pentylphenylazo)-2-naphtholato))chromat(1-), Gemisch)
English	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-), tert-alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-), tert-alkyl(C12-C14)ammonium-bis[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-chromat(1-), tert-alkyl(C12-C14)ammonium-[[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-), tert-alkyl(C12-C14)ammonium-[[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) and C12-14-tert-alkylammonium((1-(4(or 5)-nitro-2-oxidophenylazo)-2-naphtholato)(1-(3-nitro-2-oxido-5-pentylphenylazo)-2-naphtholato))chromat(1-), mixture)
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Transport status	allowed
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UN No.	3077
Class
Classification code
Packing group
Special provisions	, Special provision 274 The provisions of 3.1.2.8 apply: 3.1.2.8 Generic or "not otherwise specified" (n.o.s.) names 3.1.2.8.1 Generic and "not otherwise specified" proper shipping names that are assigned to special provision 274 or 318 in Column (6) of Table A in Chapter 3.2 shall be supplemented with the technical name of the goods unless a national law or international convention prohibits its disclosure if it is a controlled substance. For explosives of Class 1, the dangerous goods description may be supplemented by additional descriptive text to indicate commercial or military names. Technical names shall be entered in brackets immediately following the proper shipping name. An appropriate modifier, such as "contains" or "containing" or other qualifying words such as "mixture", "solution", etc. and the percentage of the technical constituent may also be used. For example: "UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS XYLENE AND BENZENE), 3, II". 3.1.2.8.1.1 The technical name shall be a recognized chemical name or biological name, or other name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose. In the case of pesticides, only ISO common name(s), other name(s) in the World Health Organization (WHO) Recommended Classification of Pesticides by Hazard and Guidelines to Classification, or the name(s) of the active substance(s) may be used. 3.1.2.8.1.2 When a mixture of dangerous goods is described by one of the "n.o.s." or "generic" entries to which special provision 274 has been allocated in Column (6) of Table A in Chapter 3.2, not more than the two constituents which most predominantly contribute to the hazard or hazards of a mixture need to be shown, excluding controlled substances when their disclosure is prohibited by national law or international convention. If a package containing a mixture is labelled with any subsidiary risk label, one of the two technical names shown in parentheses shall be the name of the constituent which compels the use of the subsidiary risk label. NOTE: See 5.4.1.2.2. 3.1.2.8.1.3 Examples illustrating the selection of the proper shipping name supplemented with the technical name of goods for such n.o.s. entries are: UN 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. (drazoxolon) UN 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (trimethylgallium) UN 3540 ARTICLES CONTAINING FLAMMABLE LIQUID, N.O.S. (pyrrolidine). 3.1.2.8.1.4 For UN Nos. 3077 and 3082 only, the technical name may be a name shown in capital letters in column 2 of Table A of Chapter 3.2, provided that this name does not include "N.O.S." and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.: UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT) UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS). , Special provision 335 Mixtures of solids which are not subject to the requirements of RID and environmentally hazardous liquids or solids shall be classified as UN 3077 and may be carried under this entry provided there is no free liquid visible at the time the substance is loaded or at the time the packaging or cargo transport unit is closed. Each cargo transport unit shall be leakproof when used for carriage in bulk. If free liquid is visible at the time the mixture is loaded or at the time the packaging or cargo transport unit is closed, the mixture shall be classified as UN 3082. Sealed packets and articles containing less than 10 ml of an environmentally hazardous liquid, absorbed into a solid material but with no free liquid in the packet or article, or containing less than 10 g of an environmentally hazardous solid, are not subject to the requirements of RID. , Special provision 375 These substances when carried in single or combination packagings containing a net quantity per single or inner packaging of 5 l or less for liquids or having a net mass per single or inner packaging of 5 kg or less for solids, are not subject to any other provisions of RID provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8. Special provision 601 Pharmaceutical products (medicines) ready for use, which are substances manufactured and packaged for retail sale or distribution for personal or household consumption are not subject to the requirements of RID.
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Labels

Marks

Orange-coloured plate for tanks

Orange-coloured plate: Hazard identification number 90, UN number 3077

Hazard identification number	90	environmentally hazardous substance; miscellaneous dangerous substances
UN number	3077	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Limited quantities	5 kg
Excepted quantities	E1
Transport category	3
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Packages
Loading, unloading and handling	, Loading, unloading and handling: CW13 If any substances have leaked and been spilled in a wagon or container, it may not be re-used until after it has been thoroughly cleaned and, if necessary, disinfected or decontaminated. Any other goods and articles carried in the same wagon or container shall be examined for possible contamination. Loading, unloading and handling: CW31 Wagons or large containers in which substances of this Class have been carried as full loads, or small containers in which these substances have been carried, shall be checked, after unloading, for any residues of the load.
Express parcel
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Instructions	P002, R001
Special provisions	Special provision: PP12 For UN Nos. 1361, 2213 and UN No. 3077, 5H1, 5L1 and 5M1 bags are allowed when carried in closed wagons or closed containers.
Mixed packing	Mixed packing: MP10 May - in quantities not exceeding 5 kg per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21: - with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or - with goods which are not subject to the requirements of RID, provided they do not react dangerously with one another.

Instructions	IBC08
Special provisions

Instructions	LP02
Special provisions	none

Portable tanks (UN tanks)

Tank instruction

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RID tanks

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none

Special provisions	,

Admissibility	acceptable
Instructions	, , Instruction BK3 Carriage in flexible bulk containers is permitted. The bulk container used shall conform to the requirements of Chapter 6.11.

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