UN 3077 tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) + C12-14-tert-alkylammonium((1-(4(or 5)-nitro-2-oxidophenylazo)-2-naphtholato)(1-(3-nitro-2-oxido-5-pentylphenylazo)-2-naphtholato))chromat(1-), mixture IMDG-Code, Amdt. 42-24 (Shortinfo)

Transport exlusions (collapsed)

Transport status	allowed
Detailinfo

Classification (collapsed)

UN No.	3077
Class	9 Class 9 Miscellaneous dangerous substances and articles Normal Courier Close
Subsidiary risks
Packing group	III Packing group III Substance presenting low danger Normal Courier Close
Spe­cial pro­vi­sions	274, Special provision 274 For the purposes of documentation and package marking, the proper shipping name shall be supplemented with the technical name (see 3.1.2.8.1). For UN 3077 and UN 3082 only, the technical name may be a name shown in capital letters in column 2 of the Dangerous Goods List, provided that this name does not include "N.O.S." and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT) UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS). Normal Courier Close 335, Special provision 335 Mixtures of solids which are not subject to the provisions of this Code and environmentally hazardous liquids assigned to UN 3082 may be classified and transported as UN 3077, provided there is no free liquid visible at the time the substance is loaded or at the time the packaging or cargo transport unit is closed. If free liquid is visible at the time the mixture is loaded or at the time the packaging or cargo transport unit is closed, the mixture shall be classified as UN 3082. Each cargo transport unit shall be leakproof when used as a bulk container. Sealed packets and articles containing less than 10 mL of an environmentally hazardous liquid assigned to UN 3082, absorbed into a solid material but with no free liquid in the packet or article, or containing less than 10 g of an environmentally hazardous solid assigned to UN 3077, are not subject to the provisions of this Code. Normal Courier Close 375, Special provision 375 These substances, when carried in single or combination packagings containing a net quantity per single or inner packaging of 5 L or less for liquids or having a net mass per single or inner packaging of 5 kg or less for solids, are not subject to any other provisions of the present Code, provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8. Normal Courier Close 966, Special provision 966 Sheeted bulk containers (BK1) are only permitted in accordance with 4.3.3. Normal Courier Close 967, Special provision 967 Flexible bulk containers (BK3) are only permitted in accordance with 4.3.4. Normal Courier Close 969 Special provision 969 Substances classified in accordance to 2.9.3 are subject to the provisions for marine pollutants. Substances which are transported under UN 3077 and 3082 but which do not meet the criteria of 2.9.3 (see 2.9.2.2) are not subject to the provisions for marine pollutants. However for substances that are identified as marine pollutants in this Code (see Index) but which no longer meet the criteria of 2.9.3, the provisions of 2.10.2.6 apply. Normal Courier Close
Marine pollutant
Environmentally hazardous	yes (acc. CLP-VO) Environmentally hazardous - yes (acc. CLP-VO) The substance shall be marked with the environmentally hazardous substance mark. Normal Courier Close
EmS	F-A, EmS F-A Fire Schedule A (Alfa) General fire schedule Normal Courier Close S-F EmS S-F Spillage Schedule F (Foxtrott) for: Water-soluble marine pollutants Normal Courier Close
Detailinfo

Marking and Labelling (collapsed)

Labels	Label 9 Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances Label model No. 9 Symbol and symbol colour: 7 vertical stripes in upper half, black Background: white Figure in bottom corner (and figure colour): 9 underlined (black) Close
Marks	Mark Marine pollutant Marine pollutant mark The mark shall be in the form of a square set at an angle of 45° (diamond-shaped). The symbol (fish and tree) shall be black on white or suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. If the size of the package so requires, the dimensions/line thickness may be reduced, provided the mark remains clearly visible. Where dimensions are not specified, all features shall be in approximate proportion to those shown. Close
Orange-coloured plate for tanks	Orange-coloured plate for tanks UN number 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. Close
Detailinfo

Limited and excepted quantities (collapsed)

Limited quantities	5 kg
Excepted quantities	E1
Detailinfo

Stowage, segregation, handling (collapsed)

Stowage category	A Stowage category A Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 m of overall length, whichever is the greater number -> ON DECK OR UNDER DECK Other passenger ships in which the limiting number of passengers transported is exceeded -> ON DECK OR UNDER DECK Normal Courier Close
Stowage provisions	SW23 Stowage provision SW23 When transported in BK3 bulk container, see 7.6.2.12 and 7.7.3.9. Normal Courier Close
Segregation groups	none
Segregation provisions	none
Handling	none
Detailinfo

Containments (collapsed)

Pack­ag­ings (collapsed)

In­struc­tions	P002
Spe­cial pro­vi­sions	PP12 Special provision: PP12 For UN 2213 and UN 3077, 5H1, 5L1 and 5M1 bags are allowed when transported in closed cargo transport units. Normal Courier Close

In­ter­me­dia­te bulk con­tai­ners (IBC) (collapsed)

In­struc­tions	IBC08
Spe­cial pro­vi­sions	B3 Special provision: B3 Flexible IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. Normal Courier Close

Large pack­ag­ings (collapsed)

In­struc­tions	LP02
Spe­cial pro­vi­sions	none

Tanks (collapsed)

Por­table tanks (UN tanks)
Tank in­struc­tion	T1 Tank instruction T1 The portable tank instructions T1 to T22 apply to liquid and solid substances of class 1 and classes 3 to 9. The general provisions of section 4.2.1 and the requirements of section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes or divisions 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the provisions of chapter 6.10 apply to the portable tanks with FRP shells. T1 Minimum test pressure (bar): 1,5 Minimum shell thickness (in mm - reference steel) (see 6.7.2.4): see 6.7.2.4.2 Pressure-relief provisions *) (see 6.7.2.8): Normal Bottom opening provisions (see 6.7.2.6): see 6.7.2.6.2 *) When the word "Normal" is indicated, all the requirements of 6.7.2.8 apply except for 6.7.2.8.3. Normal Courier Close
Spe­cial pro­vi­sions	TP33 Special provision TP33 The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point and which are cooled and transported as a solid mass. For solids which are transported above their melting point, see 4.2.1.19. Normal Courier Close

Bulk con­tai­ners (collapsed)

Admissibility

acceptable

In­struc­tions

BK1, Instruction BK1 Carriage in sheeted bulk container is permitted. The bulk container used shall conform to the provisions of chapter 6.9. 4.3.3 Additional provisions for the use of sheeted bulk containers (BK1) 4.3.3.1 Sheeted bulk containers (BK1) shall not be used for sea transport, except for UN 3077 not meeting the criteria of 2.9.3 transported on short international voyages. Normal Courier Close BK2, Instruction BK2 Carriage in closed bulk container is permitted. The bulk container used shall conform to the provisions of chapter 6.9. Normal Courier Close BK3, Instruction BK3 Carriage in flexible bulk container is permitted. The bulk container used shall conform to the provisions of chapter 6.9. 4.3.4 Additional provisions for the use of flexible bulk containers (BK3) 4.3.4.1 Flexible bulk containers are only allowed in the holds of general cargo ships. They are not allowed to be transported in cargo transport units. Normal Courier Close 966, Instruction 966 Special requirement of Special Provision 966 Sheeted bulk containers (BK1) are only permitted in accordance with 4.3.3. Normal Courier Close 967 Instruction 967 Special requirement of Special Provision 967 Flexible bulk containers (BK3) are only permitted in accordance with 4.3.4. Normal Courier Close

Bulk carriage (IMSBC)(collapsed)

Admissibility	forbidden

Detailinfo ... Packagings Intermediate bulk containers (IBC) Large packagings Tanks Bulk Bulk containers