MATIÈRE DANGEREUSE DU POINT DE VUE DE L'ENVIRONNEMENT, LIQUIDE, N.S.A. (Bis[[2,2',2''-nitrilotris-[éthanolate]]-1-N,O]-bis[2-(2-méthoxyéthoxy)éthoxy]-titane)
Environmentally hazardous substances: pollutant to the aquatic environment, liquid
Packing group
Packing group III
Substance presenting low danger
Special provisions
,
Special provision 274
The provisions of 3.1.2.8 apply:
3.1.2.8 Generic or "not otherwise specified" (N.O.S.) Names
3.1.2.8.1 Generic and "not otherwise specified" proper shipping names that are assigned to special provision 274 or 318 in Column (6) of Table A in Chapter 3.2 shall be supplemented with the technical name of the goods unless a national law or international convention prohibits its disclosure if it is a controlled substance. For explosives of Class 1, the dangerous goods description may be supplemented by additional descriptive text to indicate commercial or military names. Technical names shall be entered in brackets immediately following the proper shipping name. An appropriate modifier, such as "contains" or "containing" or other qualifying words such as "mixture", "solution", etc. and the percentage of the technical constituent may also be used. For example: "UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS XYLENE AND BENZENE), 3, II".
3.1.2.8.1.1 The technical name shall be a recognized chemical name or biological name, or other name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose. In the case of pesticides, only ISO common name(s), other name(s) in the World Health Organization (WHO) Recommended Classification of Pesticides by Hazard and Guidelines to Classification, or the name(s) of the active substance(s) may be used.
3.1.2.8.1.2 When a mixture of dangerous goods is described by one of the "N.O.S." or "generic" entries to which special provision 274 has been allocated in Column (6) of Table A in Chapter 3.2, not more than the two constituents which most predominantly contribute to the hazard or hazards of a mixture need to be shown, excluding controlled substances when their disclosure is prohibited by national law or international convention. If a package containing a mixture is labelled with any subsidiary risk label, one of the two technical names shown in parentheses shall be the name of the constituent which compels the use of the subsidiary risk label.
NOTE: See 5.4.1.2.2.
3.1.2.8.1.3 Examples illustrating the selection of the proper shipping name supplemented with the technical name of goods for such N.O.S. entries are:
UN 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. (drazoxolon)
UN 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (trimethylgallium)
UN 3540 ARTICLES CONTAINING FLAMMABLE LIQUID, N.O.S. (pyrrolidine).
3.1.2.8.1.4 For UN Nos. 3077 and 3082 only, the technical name may be a name shown in capital letters in column 2 of Table A of Chapter 3.2, provided that this name does not include "N.O.S." and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.:
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT)
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS).
,
Special provision 335
Mixtures of solids which are not subject to the requirements of ADR and environmentally hazardous liquids or solids shall be classified as UN 3077 and may be carried under this entry provided there is no free liquid visible at the time the substance is loaded or at the time the packaging or cargo transport unit is closed. Each cargo transport unit shall be leakproof when used for carriage in bulk. If free liquid is visible at the time the mixture is loaded or at the time the packaging or cargo transport unit is closed, the mixture shall be classified as UN 3082. Sealed packets and articles containing less than 10 ml of an environmentally hazardous liquid, absorbed into a solid material but with no free liquid in the packet or article, or containing less than 10 g of an environmentally hazardous solid, are not subject to the requirements of ADR.
,
Special provision 375
These substances when carried in single or combination packagings containing a net quantity per single or inner packaging of 5 l or less for liquids or having a net mass per single or inner packaging of 5 kg or less for solids, are not subject to any other provisions of ADR provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8.
,
Special provision 601
Pharmaceutical products (medicines) ready for use, which are substances manufactured and packaged for retail sale or distribution for personal or household consumption are not subject to the requirements of ADR.
Special provision 650
Waste consisting of packaging residues, solidified residues and liquid residues of paint may be carried under the conditions of UN No. 1263, packing group II, or UN No. 3082, as appropriate. In addition to the provisions for UN No. 1263, packing group II, and UN No. 3082, the waste may also be packed and carried as follows:
(a) The waste may be packed in accordance with packing instruction P002 of 4.1.4.1 or to packing instruction IBC06 of 4.1.4.2. Mixed packing of waste classified as UN 1263 and waste water-based paints classified as UN 3082 is permitted;
(b) The waste may be packed in flexible IBCs of types 13H3, 13H4 and 13H5 in overpacks with complete walls;
(c) Testing of packagings and IBCs indicated under (a) or (b) may be carried out in accordance with the requirements of Chapters 6.1 or 6.5, as appropriate, in relation to solids, at the packing group II performance level. The tests shall be carried out on packagings and IBCs, filled with a representative sample of the waste, as prepared for carriage;
(d) Carriage in bulk in sheeted vehicles, closed containers or sheeted large containers, all with complete walls is allowed. Waste classified as UN 1263 may be mixed and loaded with waste water-based paints classified as UN 3082 in the same vehicle or container. In the case of such mixed loading the entire contents shall be assigned to UN 1263. The body of vehicles or containers shall be leakproof or rendered leakproof, for example by means of a suitable and sufficiently stout inner lining;
(e) If the waste is carried under the conditions of this special provision, the goods shall be declared in accordance with 5.4.1.1.3.1 with the appropriate UN number(s) in the transport document, as follows:
"UN 1263 WASTE PAINT, 3, II, (D/E)";
"UN 1263 WASTE PAINT, 3, PG II, (D/E)";
"UN 3082 WASTE ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT), 9, III, (-)"; or
"UN 3082 WASTE ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT), 9, PG III, (-)".
Class 9 hazard: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Label model No. 9
Symbol and symbol colour: 7 vertical stripes in upper half, black
Background: white
Figure in bottom corner (and figure colour): 9 underlined (black)
Marks
Mark EHS
Environmentally hazardous substance mark:
The mark shall be in the form of a square set at an angle of 45° (diamond-shaped). The symbol (fish and tree) shall be black on white or suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. If the size of the package so requires, the dimensions/line thickness may be reduced, provided the mark remains clearly visible. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
IBCs of type 31HZ2 (31HA2, 31HB2, 31HN2, 31HD2 and 31HH2) shall be carried in closed vehicles or containers.
Bulk
forbidden
Loading, unloading and handling
Loading, unloading and handling: CV13
If any substances have leaked and been spilled in a vehicle or container, it may not be re-used until after it has been thoroughly cleaned and, if necessary, disinfected or decontaminated. Any other goods and articles carried in the same vehicle or container shall be examined for possible contamination.
For UN Nos. 1133, 1210, 1263 and 1866 and for adhesives, printing inks, printing ink related materials, paints, paint related materials and resin solutions which are assigned to UN 3082, metal or plastics packagings for substances of packing groups II and III in quantities of 5 litres or less per packaging are not required to meet the performance tests in Chapter 6.1 when carried:
(a) in palletized loads, a pallet box or unit load device, e.g. individual packagings placed or stacked and secured by strapping, shrink or stretch-wrapping or other suitable means to a pallet; or
(b) as inner packagings of combination packagings with a maximum net mass of 40 kg.
Mixed packing
Mixed packing: MP19
May - in quantities not exceeding 5 litres per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21:
- with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or
- with goods which are not subject to the requirements of ADR, provided they do
not react dangerously with one another.
Instructions
IBC03
Special provisions
none
Instructions
LP01
Special provisions
Tank instruction
Tank instruction T4
The portable tank instructions T1 to T22 apply to liquid and solid substances of Class 1 and Classes 3 to 9. The general provisions of Section 4.2.1 and the requirements of Section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the requirements of Chapter 6.9 apply.
T4
Minimum test pressure (bar): 2.65
Minimum shell thickness (in mm-reference steel for shells made of metallic materials) (see 6.7.2.4): See 6.7.2.4.2
Pressure-relief requirements (see 6.7.2.8): Normal *)
Bottom opening requirements (see 6.7.2.6): See 6.7.2.6.3
*) When the word "Normal" is indicated, all the requirements of 6.7.2.8 apply except for 6.7.2.8.3.
Special provisions
,
Special provision TP1
The degree of filling prescribed in 4.2.1.9.2 shall not be exceeded:
Degree of filling = 97 / (1 + alpha x (tr - tf))
where
alpha = mean coefficient of cubical expansion of the liquid between tf and tr;
tr = maximum mean bulk temperature during carriage [°C];
tf = mean temperature of the liquid during filling [°C].
Special provision TP29
A portable tank having a minimum test pressure of 1.5 bar may be used if it is shown that a test pressure of 1.5 bar or less is acceptable according to the test pressure definition in 6.7.2.1.
Tank code
Tank code LGBV
Code LGBV:
L = Type of tank:
Tank for substances in the liquid state (liquids or solids handed over for carriage in the molten state).
-------------------------
G = Calculation pressure:
Minimum calculation pressure according to the general requirements of 6.8.2.1.14.
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B = Openings (see 6.8.2.2.2):
Tank with bottom-filling or bottom-discharge openings with 3 closures.
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V = Safety valves/devices:
Tank with a breather device, according to 6.8.2.2.6, but no device protecting against the propagation of a flame; or non-explosion pressure shock resistant tank.
(a) A vehicle, other than EX/III or FL vehicle or than a MEMU, intended for the carriage of dangerous goods in fixed tanks or demountable tanks with a capacity exceeding 1 m³ or in tank-containers, portable tanks or MEGCs with an individual capacity exceeding 3 m³; or
(b) A battery-vehicle with a total capacity exceeding 1 m³ other than a FL vehicle.
Tunnel restriction code
Tunnel restriction code: -
Passage allowed through all tunnels (For UN Nos. 2919 and 3331, see also 8.6.3.1).
