UN 1724 Allyltrichlorosilane, stabilized ADR 2025 (Shortinfo)

When substances are stabilized by temperature control, the provisions of 2.2.41.1.21, 7.1.7, special provision V8 of Chapter 7.2, special provision S4 of Chapter 8.5 and the requirements of Chapter 9.6 apply. When chemical stabilization is employed, the person offering the packaging, IBC or tank for carriage shall ensure that the level of stabilization is sufficient to prevent the substance in the packaging, IBC or tank from dangerous polymerization at a bulk mean temperature of 50 °C, or, in the case of a portable tank, 45 °C. Where chemical stabilization becomes ineffective at lower temperatures within the anticipated duration of carriage, temperature control is required. In making this determination factors to be taken into consideration include, but are not limited to, the capacity and geometry of the packaging, IBC or tank and the effect of any insulation present, the temperature of the substance when offered for carriage, the duration of the journey and the ambient temperature conditions typically encountered in the journey (considering also the season of year), the effectiveness and other properties of the stabilizer employed, applicable operational controls imposed by regulation (e.g. requirements to protect from sources of heat, including other cargo carried at a temperature above ambient) and any other relevant factors.

For the carriage of packages containing polymerizing substances the provisions of special provision 386, in conjunction with 7.1.7.3, 7.1.7.4, 5.4.1.1.15 and 5.4.1.2.3.1, need not be applied, when carried for disposal or recycling provided the following conditions are met: (a) Before loading an examination has shown that there is no significant deviation between the outside temperature of the package and the ambient temperature; (b) The carriage is effected within a period of not more than 24 hours from that examination; (c) The packages are protected from direct sunlight and from the impact of other sources of heat (e.g. additional loads that are being carried above ambient temperature) during carriage; (d) The ambient temperatures during the carriage are below 45 °C; (e) Vehicles and containers are adequately ventilated; (f) The substances are packed in packages with a maximum capacity of 1000 litres. In assessing the substances for carriage under the conditions of this special provision, additional measures to prevent dangerous polymerization may be considered, for example the addition of inhibitors.

See 7.1.7. NOTE: This special provision V8 does not apply to substances referred to in 3.1.2.6 when substances are stabilized by the addition of chemical inhibitors such that the SADT is greater than 50 °C. In this case, temperature control may be required under conditions of carriage where the temperature may exceed 55 °C.

Additional requirements concerning the carriage of flammable liquids or gases (1) Portable lighting apparatus The load compartment of closed vehicles carrying liquids having a flash-point of not more than 60 °C or flammable substances or article of Class 2, shall not be entered by persons carrying portable lighting apparatus other than those so designed and constructed that they cannot ignite any flammable vapours or gases which may have penetrated into the interior of the vehicle. (2) Operation of combustion heaters during loading or unloading The operation of combustion heaters of vehicles of type FL (see Part 9) is forbidden during loading and unloading and at loading sites. (3) Precautions against electrostatic charges In the case of vehicles of type FL (see Part 9), a good electrical connection from the vehicle chassis to earth shall be established before tanks are filled or emptied. In addition, the rate of filling shall be limited.

See 7.1.7. NOTE: This special provision S4 does not apply to substances referred to in 3.1.2.6 when substances are stabilized by the addition of chemical inhibitors such that the SADT is greater than 50 °C. In this case, temperature control may be required under conditions of carriage where the temperature may exceed 55 °C.