Flammable liquids, without subsidiary hazard, having a flash-point of or below 60 °C
Packing group
Packing group II
Flash-point < 23 °C, initial boiling point > 35 °C
Special provisions
,
Special provision 274
The provisions of 3.1.2.8 apply:
3.1.2.8 Generic or "not otherwise specified" (N.O.S.) Names
3.1.2.8.1 Generic and "not otherwise specified" proper shipping names that are assigned to special provision 274 or 318 in Column (6) of Table A in Chapter 3.2 shall be supplemented with the technical name of the goods unless a national law or international convention prohibits its disclosure if it is a controlled substance. For explosives of Class 1, the dangerous goods description may be supplemented by additional descriptive text to indicate commercial or military names. Technical names shall be entered in brackets immediately following the proper shipping name. An appropriate modifier, such as "contains" or "containing" or other qualifying words such as "mixture", "solution", etc. and the percentage of the technical constituent may also be used. For example: "UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS XYLENE AND BENZENE), 3, II".
3.1.2.8.1.1 The technical name shall be a recognized chemical name or biological name, or other name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose. In the case of pesticides, only ISO common name(s), other name(s) in the World Health Organization (WHO) Recommended Classification of Pesticides by Hazard and Guidelines to Classification, or the name(s) of the active substance(s) may be used.
3.1.2.8.1.2 When a mixture of dangerous goods is described by one of the "N.O.S." or "generic" entries to which special provision 274 has been allocated in Column (6) of Table A in Chapter 3.2, not more than the two constituents which most predominantly contribute to the hazard or hazards of a mixture need to be shown, excluding controlled substances when their disclosure is prohibited by national law or international convention. If a package containing a mixture is labelled with any subsidiary risk label, one of the two technical names shown in parentheses shall be the name of the constituent which compels the use of the subsidiary risk label.
NOTE: See 5.4.1.2.2.
3.1.2.8.1.3 Examples illustrating the selection of the proper shipping name supplemented with the technical name of goods for such N.O.S. entries are:
UN 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. (drazoxolon)
UN 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE (trimethylgallium)
UN 3540 ARTICLES CONTAINING FLAMMABLE LIQUID, N.O.S. (pyrrolidine).
3.1.2.8.1.4 For UN Nos. 3077 and 3082 only, the technical name may be a name shown in capital letters in column 2 of Table A of Chapter 3.2, provided that this name does not include "N.O.S." and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.:
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT)
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS).
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Special provision 386
When substances are stabilized by temperature control, the provisions of 2.2.41.1.21, 7.1.7, special provision V8 of Chapter 7.2, special provision S4 of Chapter 8.5 and the requirements of Chapter 9.6 apply. When chemical stabilization is employed, the person offering the packaging, IBC or tank for carriage shall ensure that the level of stabilization is sufficient to prevent the substance in the packaging, IBC or tank from dangerous polymerization at a bulk mean temperature of 50 °C, or, in the case of a portable tank, 45 °C. Where chemical stabilization becomes ineffective at lower temperatures within the anticipated duration of carriage, temperature control is required. In making this determination factors to be taken into consideration include, but are not limited to, the capacity and geometry of the packaging, IBC or tank and the effect of any insulation present, the temperature of the substance when offered for carriage, the duration of the journey and the ambient temperature conditions typically encountered in the journey (considering also the season of year), the effectiveness and other properties of the stabilizer employed, applicable operational controls imposed by regulation (e.g. requirements to protect from sources of heat, including other cargo carried at a temperature above ambient) and any other relevant factors.
,
Special provision 601
Pharmaceutical products (medicines) ready for use, which are substances manufactured and packaged for retail sale or distribution for personal or household consumption are not subject to the requirements of ADR.
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Special provision 640D
The physical and technical characteristics mentioned in column (2) of Table A of Chapter 3.2 determine different tank codes for the carriage of substances of the same packing group in ADR tanks.
In order to identify these physical and technical characteristics of the product carried in the tank, the following shall be added, to the particulars required in the transport document, only in case of carriage in ADR tanks:
"Special provision 640D"
These particulars may, however, be dispensed with in the case of carriage in the type of tank which, for substances of a specific packing group of a specific UN number, meets at least the most stringent requirements.
Special provision 676
For the carriage of packages containing polymerizing substances the provisions of special provision 386, in conjunction with 7.1.7.3, 7.1.7.4, 5.4.1.1.15 and 5.4.1.2.3.1, need not be applied, when carried for disposal or recycling provided the following conditions are met:
(a) Before loading an examination has shown that there is no significant deviation between the outside temperature of the package and the ambient temperature;
(b) The carriage is effected within a period of not more than 24 hours from that examination;
(c) The packages are protected from direct sunlight and from the impact of other sources of heat (e.g. additional loads that are being carried above ambient temperature) during carriage;
(d) The ambient temperatures during the carriage are below 45 °C;
(e) Vehicles and containers are adequately ventilated;
(f) The substances are packed in packages with a maximum capacity of 1000 litres.
In assessing the substances for carriage under the conditions of this special provision, additional measures to prevent dangerous polymerization may be considered, for example the addition of inhibitors.
Class 3 hazard: Flammable liquids (and liquid desensitized explosives)
Label model No. 3
Symbol and symbol colour: Flame, black or white
Background: red
Figure in bottom corner (and figure colour): 3 (black or white)
Marks
Orange plate for tanks
Orange plate for tanks
Hazard identification number
33
highly flammable liquid (flash-point below 23 °C)
UN number
1993
FLAMMABLE LIQUID, N.O.S. (vapour pressure at 50 °C not more than 110 kPa)
See 7.1.7.
NOTE: This special provision V8 does not apply to substances referred to in 3.1.2.6 when substances are stabilized by the addition of chemical inhibitors such that the SADT is greater than 50 °C. In this case, temperature control may be required under conditions of carriage where the temperature may exceed 55 °C.
Loading, unloading and handling
none
Operation
,
Operation: S2
Additional requirements concerning the carriage of flammable liquids or gases
(1) Portable lighting apparatus
The load compartment of closed vehicles carrying liquids having a flash-point of not more than 60 °C or flammable substances or article of Class 2, shall not be entered by persons carrying portable lighting
apparatus other than those so designed and constructed that they cannot ignite any flammable vapours or gases which may have penetrated into the interior of the vehicle.
(2) Operation of combustion heaters during loading or unloading
The operation of combustion heaters of vehicles of type FL (see Part 9) is forbidden during loading and unloading and at loading sites.
(3) Precautions against electrostatic charges
In the case of vehicles of type FL (see Part 9), a good electrical connection from the vehicle chassis to earth shall be established before tanks are filled or emptied. In addition, the rate of filling shall be limited.
,
Operation: S4
See 7.1.7.
NOTE: This special provision S4 does not apply to substances referred to in 3.1.2.6 when substances are stabilized by the addition of chemical inhibitors such that the SADT is greater than 50 °C. In this case, temperature control may be required under conditions of carriage where the temperature may exceed 55 °C.
Operation: S20
The provisions of Chapter 8.4 concerning the supervision of vehicles shall apply when the total mass or volume of these substances in the vehicle exceeds 10 000 kg as packaged goods or more than 3 000 litres in tanks.
May - in quantities not exceeding 5 litres per inner packaging - be packed together in a combination packaging conforming to 6.1.4.21:
- with goods of the same class covered by other classification codes or with goods of other classes, when mixed packing is also permitted for these; or
- with goods which are not subject to the requirements of ADR, provided they do
not react dangerously with one another.
Instructions
IBC02
Special provisions
none
Transport in large packagings is not permitted.
Portable tanks (UN tanks)
Tank instruction
Tank instruction T7
The portable tank instructions T1 to T22 apply to liquid and solid substances of Class 1 and Classes 3 to 9. The general provisions of Section 4.2.1 and the requirements of Section 6.7.2 shall be met. The instructions for portable tanks with FRP shells apply to substances of classes 1, 3, 5.1, 6.1, 6.2, 8 and 9. Additionally, the requirements of Chapter 6.9 apply.
T7
Minimum test pressure (bar): 4
Minimum shell thickness (in mm-reference steel for shells made of metallic materials) (see 6.7.2.4): See 6.7.2.4.2
Pressure-relief requirements (see 6.7.2.8): Normal *)
Bottom opening requirements (see 6.7.2.6): See 6.7.2.6.3
*) When the word "Normal" is indicated, all the requirements of 6.7.2.8 apply except for 6.7.2.8.3.
Special provisions
,
Special provision TP1
The degree of filling prescribed in 4.2.1.9.2 shall not be exceeded:
Degree of filling = 97 / (1 + alpha x (tr - tf))
where
alpha = mean coefficient of cubical expansion of the liquid between tf and tr;
tr = maximum mean bulk temperature during carriage [°C];
tf = mean temperature of the liquid during filling [°C].
,
Special provision TP8
The test pressure may be reduced to 1.5 bar when the flash point of the substances carried is greater than 0 °C.
Special provision TP28
A portable tank having a minimum test pressure of 2.65 bar may be used if it is shown that a test pressure of 2.65 bar or less is acceptable according to the test pressure definition in 6.7.2.1.
ADR tanks
Tank code
Tank code LGBF
Code LGBF:
L = Type of tank:
Tank for substances in the liquid state (liquids or solids handed over for carriage in the molten state).
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G = Calculation pressure:
Minimum calculation pressure according to the general requirements of 6.8.2.1.14.
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B = Openings (see 6.8.2.2.2):
Tank with bottom-filling or bottom-discharge openings with 3 closures.
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F = Safety valves/devices:
Tank with a breather device, according to 6.8.2.2.6, fitted with a device protecting against the propagation of a flame; or explosion pressure shock resistant tank.
Special provisions
none
Vehicle for tank carriage
Tank vehicle
Tank vehicle: FL
(a) A vehicle intended for the carriage of liquids having a flash-point of not more than 60°C (with the exception of diesel fuel complying with standard EN 590:2013 + A1:2017, gas oil, and heating oil (light) - UN No. 1202 - with a flash-point as specified in standard EN 590:2013 + A1:2017) in fixed tanks or demountable tanks with a capacity exceeding 1 m³ or in tank-containers or portable tanks with an individual capacity exceeding 3 m³; or
(b) A vehicle intended for the carriage of flammable gases in fixed tanks or demountable tanks with a capacity exceeding 1 m³ or in tank-containers, portable tanks or MEGCs with an individual capacity exceeding 3 m³; or,
(c) A battery-vehicle with a total capacity exceeding 1 m³ intended for the carriage of flammable gases; or
d) A vehicle intended for the carriage of hydrogen peroxide, stabilized or hydrogen peroxide, aqueous solution stabilized with more than 60% hydrogen peroxide (Class 5.1, UN No. 2015) in fixed tanks or demountable tanks with a capacity exceeding 1 m3 or in tank-containers or portable tanks with an individual capacity exceeding 3 m³;
Transport in bulk is not permitted.
Transport in bulk containers (BK containers) is not permitted.