UN 2206 Dichlorophenyl isocyanates, isomers or isomeric mixture, solution ADN 2025 (Shortinfo)

The provisions of 3.1.2.8 apply. 3.1.2.8 Generic or "not otherwise specified" (N.O.S.) names 3.1.2.8.1 Generic and "not otherwise specified" proper shipping names that are assigned to special provision 274 or 318 in Column (6) of Table A in Chapter 3.2 or remark 27 in column (20) of Table C in Chapter 3.2 shall be supplemented with the technical name of the goods unless a national law or international convention prohibits its disclosure if it is a controlled substance. For explosive substances and articles of Class 1, the dangerous goods description may be supplemented by additional descriptive text to indicate commercial or military names. Technical names shall be entered in brackets immediately following the proper shipping name. An appropriate modifier, such as "contains" or "containing" or other qualifying words such as "mixture", "solution", etc. and the percentage of the technical constituent may aIso be used. For example: "UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS XYLENE AND BENZENE), 3, 11". 3.1.2.8.1.1 The technical name shall be a recognized chemical name or biological name, or other name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose. In the case of pesticides, only ISO common name(s), other name(s) in the World Health Organization (WHO) Recommended Classification of Pesticides by Hazard and Guidelines to Classification, or the name(s) of the active substance(s) may be used. 3.1.2.8.1.2 When a mixture of dangerous goods is described by one of the "N.O.S." or "generic" entries to which special provision 274 has been allocated in Column (6) of Table A in Chapter 3.2, or remark 27 has been allocated in column (20) of Table C in Chapter 3.2, not more than the two constituents which most predominantly contribute to the hazard or hazards of a mixture need to be shown, excluding controlled substances when their disclosure is prohibited by national law or international convention. If a package containing a mixture is labelled with any subsidiary risk label, one of the two technical names shown in parentheses shall be the name ofthe constituent which compels the use ofthe subsidiary risk label. NOTE: see 5.4.1.2.2. 3.1.2.8.1.3 Examples illustrating the selection of the proper shipping name supplemented with the technical name of goods for such N.O.S. entries are: UN 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. (drazoxolon); UN 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORlC, WATERREACTIVE (trimethylgallium). 3.1.2.8.1.4 For UN Nos. 3077 and 3082 only, the technical name may be a name shown in capital letters in column 2 of Table A of Chapter 3.2, provided that this name does not include "N.O.S." and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT) UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS). 3.1.2.8.1.5 (Deleted)

Solutions of these isocyanates having a flash-point below 23 °C are substances of Class 3.

See 7.1.4.10. ____ 7.1.4.10 Precautions with respect to foodstuffs, other articles of consumption and animal feeds 7.1.4.10.1 When special provision 802 is indicated for a dangerous good in column (6) of Table A of Chapter 3.2, precautions shall be taken as follows with respect to foodstuffs, other articles of consumption and animal feeds: Packages as well as uncleaned empty packagings, including large packagings and intermediate bulk containers (IBCs), bearing labels conforming to models Nos. 6.1 or 6.2, and those bearing labels of Class 9, containing substances of Class 9, UN Nos. 2212, 2315, 2590, 3151, 3152 or 3245, shall not be stacked on or loaded in immediate proximity to packages known to contain foodstuffs, other articles of consumption or animal feeds in the same hold and at places of loading and unloading or trans-shipment. When these packages, bearing the said labels, are loaded in immediate proximity of packages known to contain foodstuffs, other articles of consumption or animal feeds, they shall be kept apart from the latter: (a) by complete partitions which should be as high as the packages bearing the said labels, or (b) by packages not bearing labels conforming to models Nos. 6.1, 6.2 or 9 or packages bearing labels of Class 9 but not containing substances of that class, UN Nos. 2212, 2315, 2590, 3151, 3152 or 3245, or (c) by a space of at least 0.8 m, unless the packages bearing said labels are provided with an additional packaging or are completely covered (e.g. by a sheeting, a fibreboard cover or other measures).

For each member of the crew, a pair of protective goggles, a pair of protective gloves, a protective suit and a suitable pair of protective shoes (or protective boots, if necessary). On bord tank vessels, protective boots are required in all cases.

A suitable escape device for each person on bord.

A toximeter appropriate for the current and previous cargo, with the accessories and instructions *1) for its use. __________ *1) The instructions could be kept on board electronically in a human-readable format.

A breathing apparatus ambient air-dependent.

Holds containing these substances shall be ventilated whith the ventilators operating at full power, where after measurement it has been established that the holds are not free from toxic gases and vapours given off by the cargo. The measurement shall be carried out immediately after loading. A control measurement shall be repeated after one hour. The results of the measurement shall be recorded in writing. Alternatively, on vessels only containing these substances in containers in open holds, the holds containing such containers may be ventilated with the ventilation operating at full power only when it is suspected that the holds are not free of toxic gases and vapours given off by the cargo. Prior to unloading, the unloader shall be informed about this suspicion.