MATIÈRE DANGEREUSE DU POINT DE VUE DE L'ENVIRONNEMENT, LIQUIDE, N.S.A. (Dithioacétate de bis(2-éthylhexyle))
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UN no.
3082
Class
Class 9
Miscellaneous dangerous substances and articles
Classification code
Classification code M6
Environmentally hazardous substances: pollutant to the aquatic environment, liquid
Packing group
Packing group III
Substance presenting low danger
Special provisions
,
Special provision 274
The provisions of 3.1.2.8 apply.
3.1.2.8 Generic or "not otherwise specified" (N.O.S.) names
3.1.2.8.1 Generic and "not otherwise specified" proper shipping names that are assigned to special provision 274 or 318 in Column (6) of Table A in Chapter 3.2 or remark 27 in column (20) of Table C in Chapter 3.2 shall be supplemented with the technical name of the goods unless a national law or international convention prohibits its disclosure if it is a controlled substance. For explosive substances and articles of Class 1, the dangerous goods description may be supplemented by additional descriptive text to indicate commercial or military names. Technical names shall be entered in brackets immediately following the proper shipping name. An appropriate modifier, such as "contains" or "containing" or other qualifying words such as "mixture", "solution", etc. and the percentage of the technical constituent may aIso be used. For example: "UN 1993 FLAMMABLE LIQUID, N.O.S. (CONTAINS XYLENE AND BENZENE), 3, 11".
3.1.2.8.1.1 The technical name shall be a recognized chemical name or biological name, or other name currently used in scientific and technical handbooks, journals and texts. Trade names shall not be used for this purpose. In the case of pesticides, only ISO common name(s), other name(s) in the World Health Organization (WHO) Recommended Classification of Pesticides by Hazard and Guidelines to Classification, or the name(s) of the active substance(s) may be used.
3.1.2.8.1.2 When a mixture of dangerous goods is described by one of the "N.O.S." or "generic" entries to which special provision 274 has been allocated in Column (6) of Table A in Chapter 3.2, or remark 27 has been allocated in column (20) of Table C in Chapter 3.2, not more than the two constituents which most predominantly contribute to the hazard or hazards of a mixture need to be shown, excluding controlled substances when their disclosure is prohibited by national law or international convention. If a package containing a mixture is labelled with any subsidiary risk label, one of the two technical names shown in parentheses shall be the name ofthe constituent which compels the use ofthe subsidiary risk label.
NOTE: see 5.4.1.2.2.
3.1.2.8.1.3 Examples illustrating the selection of the proper shipping name supplemented with the technical name of goods for such N.O.S. entries are:
UN 2902 PESTICIDE, LIQUID, TOXIC, N.O.S. (drazoxolon);
UN 3394 ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORlC, WATERREACTIVE (trimethylgallium).
3.1.2.8.1.4 For UN Nos. 3077 and 3082 only, the technical name may be a name shown in capital letters in column 2 of Table A of Chapter 3.2, provided that this name does not include "N.O.S." and that special provision 274 is not assigned. The name which most appropriately describes the substance or mixture shall be used, e.g.:
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT)
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PERFUMERY PRODUCTS).
3.1.2.8.1.5 (Deleted)
,
Special provision 335
Mixtures of solids which are not subject to the requirements of ADN and environmentally hazardous liquids or solids shall be classified as UN 3077 and may be carried under this entry provided there is no free liquid visible at the time the substance is loaded or at the time the packaging or cargo transport unit is closed. Each cargo transport unit shall be leakproof when used for carriage in bulk. If free liquid is visible at the time the mixture is loaded or at the time the packaging or cargo transport unit is closed, the mixture shall be classified as UN 3082. Sealed packets and articles containing less than 10 ml of an environmentally hazardous liquid, absorbed into a solid material but with no free liquid in the packet or article, or containing less than 10 g of an environmentally hazardous solid, are not subject to the requirements of ADN.
,
Special provision 375
These substances when carried in single or combination packagings containing a net quantity per single or inner packaging of 5 l or less for liquids or having a net mass per single or inner packaging of 5 kg or less for solids, are not subject to any other provisions of ADN provided the packagings meet the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to 4.1.1.8 of ADR.
,
Special provision 601
Pharmaceutical products (medicines) ready for use, which are substances manufactured and packaged for retail sale or distribution for personal or household consumption are not subject to the requirements of ADN.
Special provision 650
Waste consisting of packaging residues, solidified residues and liquid residues of paint may be carried under the conditions of UN No. 1263, packing group II, or UN No. 3082, as appropriate. In addition to the provisions for UN No. 1263, packing group II, and UN No. 3082, the waste may also be packed and carried as follows:
(a) The waste may be packed in accordance with packing instruction P002 of 4.1.4.1 of ADR or to packing instruction IBC006 of 4.1.4.2 of ADR. Mixed packing of waste classified as UN No. 1263 and waste water-based paints classified as UN No. 3082 is permitted;
(b) The waste may be packed in flexible IBCs of types 13H3, 13H4 and 13H5 in overpacks with complete walls;
(c) Testing of packagings and IBCs indicated under (a) or (b) may be carried out in accordance with the requirements of Chapters 6.1 or 6.5 of ADR, as appropriate, in relation to solids, at the packing group II performance level.
The tests shall be carried out on packagings and IBCs, filled with a representative sample of the waste, as prepared for carriage;
(d) Carriage in bulk in sheeted wagons, movable roof wagons/sheeted vehicles, closed containers or sheeted large containers, all with complete walls is allowed. Waste classified as UN No. 1263 may be mixed and loaded with waste water-based paints classified as UN No. 3082 in the same vehicle, wagon or container. In the case of such mixed loading the entire contents shall be assigned to UN No. 1263. The wagons, containers or body of vehicles shall be leakproof or rendered leakproof, for example by means of a suitable and sufficiently stout inner lining;
(e) If the waste is carried under the conditions of this special provision, the goods shall be declared in accordance with 5.4.1.1.3.1 with the appropriate UN number(s) in the transport document, as follows:
"UN 1263 WASTE PAINT, 3, II";
"UN 1263 WASTE PAINT, 3, PG II;
"UN 3082 WASTE ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT), 9, III"; or
"UN 3082 WASTE ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PAINT), 9, PG III".
Class 9 hazard: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Label model No. 9
Symbol and symbol colour: 7 vertical stripes in upper half, black
Background: white
Figure in bottom corner (and figure colour): 9 underlined (black)
Marks
Mark EHS
Environmentally hazardous substance mark:
The mark shall be in the form of a square set at an angle of 45° (diamond-shaped). The symbol (fish and tree) shall be black on white or suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. If the size of the package so requires, the dimensions/line thickness may be reduced, provided the mark remains clearly visible. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
For each member of the crew, a pair of protective goggles, a pair of protective gloves, a protective suit and a suitable pair of protective shoes (or protective boots, if necessary). On bord tank vessels, protective boots are required in all cases.
Bulk
forbidden
Ventilation
No special ventilation required for this substance/article according to Chapter 3.2 Table A column (10).
Provisions concerning loading, unloading and carriage