Trinitrotoluene, scaled or prilled in dry condition

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Detailinfo IMDG-Code, Amdt. 42-24

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Substance information(collapsed)

The BAM name is based on the "name and description" from the regulations and the IUPAC rules, but may be supplemented with further information so that significant differences between two dangerous goods data sets are apparent.

Language BAM name
German Trinitrotoluen, geschuppt oder geprillt in trockenem Zustand
English Trinitrotoluene, scaled or prilled in dry condition
French Trinitrotoluène, à l'état sec sous forme de paillettes ou de granules ainsi

The aggregate state is given under normal conditions, i.e. at room temperature of 20 °C and normal pressure of 101.3 kPa.

Aggre­gate state
under normal con­di­tions solid
during trans­port solid

The formula describes the chemical composition of a substance.

Formula
C7H5N3O6

The BAM number is used to uniquely identify a substance or object in the BAM dangerous goods data pool.

BAM no. 4036
CAS no. 118-96-7
EC no. 204-289-6
Index no. 609-008-00-4
ZVG nos.
34200

Physico-chemical substance information(collapsed)
Properties and remarks
Appearance substance
Colour not specified
Odour not specified
Misci­bility/solu­bility not specified
Impact on human orga­nism not specified
Addi­tio­nal pro­per­ties/remarks Tritonal is a substance consisting of trinitrotoluene (TNT) mixed with aluminium.
Reaction with ...
Water not specified
Acids not specified
Alkalis not specified
Metals not specified
Oxidizing substances not specified

Classification(collapsed)
General
UN no. 0209
Class
Sub­si­diary risks
Packing group
Compati­bility group
Spe­cial pro­vi­sions none
Maritime transport
Marine pollutant
Environ­mentally ha­zar­dous
Emergency Schedules (EmS)
,
MFAG no.

Names(collapsed)
Transport document names 4
German 1 TRINITROTOLUEN
German 2 TNT
English 1 TRINITROTOLUENE
English 2 TNT
Instruction names 2
English TRINITROTOLUENE (TNT), dry or wetted with less than 30% water, by mass
German TRINITROTOLUEN (TNT), trocken oder angefeuchtet mit weniger als 30 Masse-% Wasser
Synonyms 0
Synonyms for transport documents 11
German 1-Methyl-2,4,6-trinitrobenzen
German 1-Methyl-2,4,6-trinitrobenzol
German 2,4,6-Trinitrotoluen
English 2,4,6-Trinitrotoluene
German 2,4,6-Trinitrotoluol
French 2,4,6-Trinitrotoluène
German TNT
English TNT
French TNT
French Tolite
German Trinitrotoluol
INCI synonyms 0
Synonyms (not recommended) 0

Transport exlusions(collapsed)
Transport status of this substance/article allowed

Labelling(collapsed)
Packagings
Label / Mark
IBC
Label / Mark
Notice not stated - the carriage in intermediate bulk containers (IBCs) is forbidden.
Large packagings (LP)
Label / Mark
Notice not stated - carriage in large packagings is forbidden
Tanks
Placard / Mark
Orange-coloured plate
Tanks Notice not stated - carriage in tanks is forbidden
Vehicles
Placard / Mark
Orange-coloured plate
Containers
Placard / Mark
Orange-coloured plate
Bulk
Placard / Mark
Orange-coloured plate
Notice not stated - carriage in bulk containers is forbidden

Limited and excepted quantities(collapsed)

Values in "ml" and "L" refer to substances that are liquid under normal conditions (temperature 20 °C, density 1013 mbar). Values in "g" and "kg" refer to substances that generally have a melting point greater than 20 °C. Solid substances that can liquefy during transport may only be transported in packagings that are suitable for liquids (paper bags, for example, are not permitted).

Limited quantities(collapsed)

No exemption according to the provisions of Chapter 3.4 possible

Excepted quantities(collapsed)

E0, No exemption according to the provisions of Chapter 3.5 possible


Containments(collapsed)
Single packagings(collapsed)
Permission Transport in packagings is generally permitted.
Instructions P112(b), P112(c)
Special provisions
PP46
Requirements Show requirements

Unless otherwise stated, the quantities indicated for the packagings in the table below refer to the maximum capacity (in litres, "l") or the maximum net mass (in kilograms, "kg"). For some quantities, an additional note with the requirements is displayed.

Number UN-Code Quantity (l/kg), opt. note
See requirements
Combination packagings(collapsed)
Combination packagings
Notice Packagings: see topic Packing methods
Packing methods(collapsed)
Packing method 1
Special provisions Packagings
Inner packaging Intermediate packaging Outer packaging
Bags paper, kraft
Bags paper, multiwall, water-resistant
Bags plastics
Bags textile
Bags textile, rubberized
Bags woven plastics
not necessary
Bags woven plastics, sift-proof (5H2)
Bags woven plastics, water-resistant (5H3)
Bags plastics, film (5H4)
Bags textile, sift-proof (5L2)
Bags textile, water resistant (5L3)
Bags paper, multiwall, water resistant (5M2)
Boxes steel (4A)
Boxes aluminium (4B)
Boxes metal, other than steel or aluminium (4N)
Boxes natural wood, ordinary (4C1)
Boxes natural wood, sift-proof (4C2)
Boxes plywood (4D)
Boxes reconstituted wood (4F)
Boxes fibreboard (4G)
Boxes plastics, expanded (4H1)
Boxes plastics, solid (4H2)
Drums steel (1A1, 1A2)
Drums aluminium (1B1, 1B2)
Drums other metal (1N1, 1N2)
Drums plywood (1D)
Drums fibreboard (1G)
Drums plastics (1H1, 1H2)
Special provisions

Special packing provision PP46: For UN 0209, bags, sift-proof (5H2) are recommended for flake or prilled TNT in the dry state and a maximum net mass of 30 kg.

Packing method 2
Inner packaging Intermediate packaging Outer packaging
Bags paper, multiwall, water-resistant
Bags plastics
Bags woven plastics
Receptacles fibreboard
Receptacles metal
Receptacles plastics
Receptacles wood
Bags paper, multiwall, water resistant with inner lining,
Bags plastics,
Receptacles metal,
Receptacles plastics,
Receptacles wood
Boxes steel (4A)
Boxes aluminium (4B)
Boxes metal, other than steel or aluminium (4N)
Boxes natural wood, ordinary (4C1)
Boxes natural wood, sift-proof (4C2)
Boxes plywood (4D)
Boxes reconstituted wood (4F)
Boxes fibreboard (4G)
Boxes plastics, solid (4H2)
Drums steel (1A1, 1A2)
Drums aluminium (1B1, 1B2)
Drums other metal (1N1, 1N2)
Drums plywood (1D)
Drums fibreboard (1G)
Drums plastics (1H1, 1H2)
Special provisions

Special packing provision PP46: For UN 0209, bags, sift-proof (5H2) are recommended for flake or prilled TNT in the dry state and a maximum net mass of 30 kg.

Intermediate bulk containers (IBC)(collapsed)
Intermediate bulk containers (IBC)
Permission Transport in intermediate bulk containers (IBCs) is not permitted.
Number UN-Code Permission Requirements
0
Large packagings(collapsed)
Permission Transport in large packagings is not permitted.
Notice not stated - carriage in large packagings is forbidden
Bulk(collapsed)
Bulk
The transport of that substance in bulk (IMSBC Code) on sea-vessels is: forbidden
Remark(s)
Bulk container(collapsed)
Bulk container
The transport in bulk conainers is according to subsection 4.3.1.1: forbidden
Special requirements according to 4.3
Tanks(collapsed)
Tanks
UN Tanks
Permissibility Transport in portable tanks (UN tanks) is not permitted.
Tank instruction Carriage in tanks is not authorized.
Additional information
Substance-related remark Carriage in tanks is not authorized.

Exceptions(collapsed)

The following is a list of exceptions from the regulations on the transport of dangerous goods (Gefahrgut-Ausnahmeverordnung - GGAV 2002, PDF (German)), which may be relevant for the current substance for transport within Germany.
The scope of the GGAV refers to the GGVSEB (Gefahrgutverordnung Straße, Eisenbahn und Binnenschifffahrt) and GGVSee (Gefahrgutverordnung See).

Exception Title Validity
8 B unlimited
18 S 30.06.2027
31 S 30.06.2027
32 S E unlimited
34 M unlimited

The Memorandum of Understanding for the transport of packaged dangerous goods by Ro/Ro ships in the Baltic Sea is a further exception in accordance with section 7 paragraph 2 of the GGVSee in conjunction with section 7.9.1 of the IMDG Code.


Further provisions(collapsed)
Security provisions
High consequence dangerous good according to table 1.4.3 !
Chapter 1.4 Security provisions

Mixed packing(collapsed)

The mixed packing of two or more dangerous goods is only permitted if the goods are compatible with each other. According to 7.2.2.1, two substances or articles are considered incompatible if, as a result of their being packed or stowed together, unacceptable hazards may arise in the event of leakage or escape of the contents or in the event of any other accident.

Note:
For guidance, refer to the general stowage and segregation instructions and to the segregation table in the section on mixed loading/stowage/segregation.

Note on mixed packing of limited quantities (3.4.4.1):
Different dangerous goods in limited quantities may be packed together in an outer packaging provided that the segregation provisions of Chapter 7.2 are taken into account and the goods do not react dangerously with each other in the event of leakage.


Mixed Loading, Stowage, Segregation(collapsed)
Segregation
 This substance or article is classified as dangerous good.
The table below provides information about which general segregation provisions shall be applied to the individual classes.
Since the properties of the substances or objects in the individual classes can be very different, you should always check the dangerous goods list to see whether special segregagtion provisions need to be applied. In the event of conflicting regulations, these take precedence over the general regulations.
A single secondary hazard must also be taken into account for the segregation.
Class 2.1
Class 2.2
Class 2.3
Class 3
Class 4.1
Class 4.2
Class 4.3
Class 5.1
Class 5.2
Class 6.1
Class 6.2
Class 7
Class 8
Class 9
The permitted mixed stowage for Class 1 goods can be found in the table below.
Compatibility group of current substance/article: D - Secondary detonating explosive substance or black powder or article containing a secondary detonating explosive substance, in each case without means of initiation and without a propelling charge, or article containing a primary explosive substance and having two or more effective protective features
Group A
Group B
Group C
Group D
Group E
Group F
Group G
Group H
Group J
Group L
Group N
Group S
General segregation provisions
No additional segregation provisions in column 16b of the dangerous goods list
Precautions with respect to foodstuffs and animal feeds: no
Stowage
Stowage category
Stowage category
General stowage provisions
Special stowage provisions
Special stowage provisions
Handling
Handling: No handlings provisions in column 16a of the dangerous goods list
Regulations for stowage and segregation for bulk cargoes (IMSBC-Code)
not stated - carriage in bulk is forbidden

Links to external databases(collapsed)