Methyl bromide, liquefied under pressure, chloropicrin <= 2 %

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Detailinfo IMDG-Code, Amdt. 42-24

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Substance information(collapsed)

The BAM name is based on the "name and description" from the regulations and the IUPAC rules, but may be supplemented with further information so that significant differences between two dangerous goods data sets are apparent.

Language BAM name
German Methylbromid, unter Druck verflüssigt, Chlorpikrin <= 2 %
English Methyl bromide, liquefied under pressure, chloropicrin <= 2 %
French Bromure de méthyle, liquéfié sous pression, chloropicrine <= 2 %

The aggregate state is given under normal conditions, i.e. at room temperature of 20 °C and normal pressure of 101.3 kPa.

Aggre­gate state
under normal con­di­tions gaseous
during trans­port liquified gas

The formula describes the chemical composition of a substance.

Formula
CH3Br

The BAM number is used to uniquely identify a substance or object in the BAM dangerous goods data pool.

BAM no. 590
CAS no. 74-83-9
EC no. 200-813-2
Index no. 602-002-00-2
ZVG nos.
31600

Physico-chemical substance information(collapsed)
Properties and remarks
Appearance toxic gas
Colour not specified
Odour chloroform-like
Misci­bility/solu­bility not specified
Impact on human orga­nism not specified
Addi­tio­nal pro­per­ties/remarks Even though this substance has a flammability hazard, it only exhibits such hazard under extreme fire conditions in confined areas. Much heavier than air (3.3).
Reaction with ...
Water not specified
Acids not specified
Alkalis not specified
Metals not specified
Oxidizing substances not specified

Classification(collapsed)
General
UN no. 1062
Class
Sub­si­diary risks
Packing group
Compati­bility group
Spe­cial pro­vi­sions
Maritime transport
Marine pollutant
Environ­mentally ha­zar­dous
Emergency Schedules (EmS)
,
MFAG no.
Transport status
allowed

Names(collapsed)
Transport document names 2
German METHYLBROMID
English METHYL BROMIDE
Instruction names 2
English METHYL BROMIDE with not more than 2.0% chloropicrin
German METHYLBROMID, mit höchstens 2,0 % Chlorpikrin
Synonyms 2
German Halon 1001
German R 40B1
Synonyms for transport documents 6
German Brommethan
English Bromomethane
French Bromoéthane
English Halon 1001
German Monobrommethan
English R 40B1
INCI synonyms 0
Synonyms (not recommended) 0

Transport exlusions(collapsed)
Transport status of this substance/article allowed

Labelling(collapsed)
Packagings
Label / Mark
IBC
Label / Mark
Notice not stated - the carriage in intermediate bulk containers (IBCs) is forbidden.
Large packagings (LP)
Label / Mark
Notice not stated - carriage in large packagings is forbidden
Tanks
Placard / Mark
Orange plate
Proper shipping name METHYL BROMIDE
Vehicles
Placard / Mark
Orange plate
Containers
Placard / Mark
Orange plate
Bulk
Placard / Mark
Orange plate
Notice not stated - carriage in bulk containers is forbidden

Limited and excepted quantities(collapsed)

Values in "ml" and "L" refer to substances that are liquid under normal conditions (temperature 20 °C, density 1013 mbar). Values in "g" and "kg" refer to substances that generally have a melting point greater than 20 °C. Solid substances that can liquefy during transport may only be transported in packagings that are suitable for liquids (paper bags, for example, are not permitted).

Limited quantities(collapsed)

No exemption according to the provisions of Chapter 3.4 possible

Excepted quantities(collapsed)

E0, No exemption according to the provisions of Chapter 3.5 possible


Containments(collapsed)
Single packagings(collapsed)
Permission Transport in packagings is generally permitted.
Instructions P200
Special provisions
Requirements Show requirements

Unless otherwise stated, the quantities indicated for the packagings in the table below refer to the maximum capacity (in litres, "l") or the maximum net mass (in kilograms, "kg"). For some quantities, an additional note with the requirements is displayed.

Number UN-Code Quantity (l/kg), opt. note
See requirements
Packing instruction P200 1
LC50 [ml/m³] min.
LC50 [ml/m³] max. 850
Cylinders X
Tubes X
Pressure drums X
Bundles of cylinders X
Multiple-Element Gas Container (MEGC) X
Test period [years] 5
Test pressure [bar] 10
Max. operating pressure [bar]
Filling ratio 1.51
Special provisions
Requirements
Combination packagings(collapsed)
Combination packagings
Code
Packing methods(collapsed)
Packing method
Notice For this substance or article no packing procedure applies.
Intermediate bulk containers (IBC)(collapsed)
Intermediate bulk containers (IBC)
Permission Transport in intermediate bulk containers (IBCs) is not permitted.
Number UN-Code Permission Requirements
0
Large packagings(collapsed)
Permission Transport in large packagings is not permitted.
Notice not stated - carriage in large packagings is forbidden
Bulk(collapsed)
Bulk
The transport of that substance in bulk (IMSBC Code) on sea-vessels is: forbidden
Remark(s)
Bulk container(collapsed)
Bulk container
The transport in bulk conainers is according to subsection 4.3.1.1: forbidden
Special requirements according to 4.3
Tanks(collapsed)
Tanks
UN Tanks
Permissibility Transport in portable tanks (UN tanks) is permitted.
Tank instruction
Additional information on UN gas tanks
Portable tanks for gases
Maximum allowable working pressure [bar]:
No.: 1
"Small": 7.0 bar
"Bare": 7.0 bar
"Sunshield": 7.0 bar
"Insulated": 7.0 bar
Openings below liquid level: nicht zugelassen
Pressure-relief requirements: siehe 6.7.3.7.3
Maximum filling ratio [%]: 1.51
Footnote 1):
  • "Small": tanks having a shell with a diameter of 1.5 m or less
  • "Without sunshield": tanks having a shell with a diameter of more than 1.5 m without insulation or sun shield (see 6.7.3.2.12)
  • "With sunshield": tanks having a shell with a diameter of more than 1.5 m with sun shield (see 6.7.3.2.12)
  • "Insulated": tank having a tank body with a diameter of more than 1.5 m with insulation (see 6.7.3.2.12); (See definition of "Design reference temperature" in 6.7.3.1)
Special provisions
Additional information
Substance-related remark

Exceptions(collapsed)

The following is a list of exceptions from the regulations on the transport of dangerous goods (Gefahrgut-Ausnahmeverordnung - GGAV 2002, PDF (German)), which may be relevant for the current substance for transport within Germany.
The scope of the GGAV refers to the GGVSEB (Gefahrgutverordnung Straße, Eisenbahn und Binnenschifffahrt) and GGVSee (Gefahrgutverordnung See).

Exception Title Validity
8 B unlimited
18 S 30.06.2027
31 S 30.06.2027
32 S E unlimited
33 M unlimited
34 M unlimited

The Memorandum of Understanding for the transport of packaged dangerous goods by Ro/Ro ships in the Baltic Sea is a further exception in accordance with section 7 paragraph 2 of the GGVSee in conjunction with section 7.9.1 of the IMDG Code.


Further provisions(collapsed)
Security provisions
High consequence dangerous good according to table 1.4.3 !
Chapter 1.4 Security provisions

Mixed packing(collapsed)

The mixed packing of two or more dangerous goods is only permitted if the goods are compatible with each other. According to 7.2.2.1, two substances or articles are considered incompatible if, as a result of their being packed or stowed together, unacceptable hazards may arise in the event of leakage or escape of the contents or in the event of any other accident.

Note:
For guidance, refer to the general stowage and segregation instructions and to the segregation table in the section on mixed loading/stowage/segregation.

Note on mixed packing of limited quantities (3.4.4.1):
Different dangerous goods in limited quantities may be packed together in an outer packaging provided that the segregation provisions of Chapter 7.2 are taken into account and the goods do not react dangerously with each other in the event of leakage.


Mixed Loading, Stowage, Segregation(collapsed)
Segregation
 This substance or article is classified as dangerous good.
The table below provides information about which general segregation provisions shall be applied to the individual classes.
Since the properties of the substances or objects in the individual classes can be very different, you should always check the dangerous goods list to see whether special segregagtion provisions need to be applied. In the event of conflicting regulations, these take precedence over the general regulations.
A single secondary hazard must also be taken into account for the segregation.
Class 1.1
Class 1.2
Class 1.3
Class 1.4
Class 1.5
Class 1.6
Class 2.1
Class 2.2
Class 2.3
Class 3
Class 4.1
Class 4.2
Class 4.3
Class 5.1
Class 5.2
Class 6.1
Class 6.2
Class 7
Class 8
Class 9
General segregation provisions
No additional segregation provisions in column 16b of the dangerous goods list
Precautions with respect to foodstuffs and animal feeds:
Stowage
Stowage category
Stowage category
General stowage provisions
Special stowage provisions
Special stowage provisions
Handling
Handling: No handlings provisions in column 16a of the dangerous goods list
Regulations for stowage and segregation for bulk cargoes (IMSBC-Code)
not stated - carriage in bulk is forbidden

Links to external databases(collapsed)