UN 3077 tert-Alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[(2-hydroxy-4-nitrophenyl)azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-bis[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) + tert-alkyl(C12-C14)ammonium-[[1-[[5-(1,1-dimethylpropyl)-2-hydroxy-3-nitrophenyl]azo]-2-naphthalenolato(2-)]-[1-[(2-hydroxy-5-nitrophenyl)azo]-2-naphthalenolato(2-)]]-chromat(1-) + C12-14-tert-alkylammonium((1-(4(or 5)-nitro-2-oxidophenylazo)-2-naphtholato)(1-(3-nitro-2-oxido-5-pentylphenylazo)-2-naphtholato))chromat(1-), mixture ADN 2025 (Detailinfo)

According to chapter 8.1 of the ADN, the following regulations apply to vessels and equipment:

• 8.1.1 (Reserved)
• 8.1.2 Documents

  8.1.2 Documents

  8.1.2 Documents 8.1.2.1 In addition to the documents required by other regulations, the following documents shall be kept on board: (a) The vessel's certificate of approval referred to in 1.16.1.1 or the vessel's provisional certificate of approval referred to in 1.16.1.3 and the annex referred to in 1.16.1.4; (b) Transport documents referred to in 5.4.1 for all dangerous goods carried as cargo on board and, where necessary the large container, vehicle or wagon packing certificate (see 5.4.2); (c) The instructions in writing prescribed in 5.4.3; (d) A copy of the ADN with the latest version of its annexed Regulations which may be a copy which can be consulted by electronic means at any time; (e) The inspection certificate of the insulation resistance of the electrical installations prescribed in 8.1.7.1 and the certificates prescribed in 8.1.7.2 concerning the inspection of all installations, equipment and self-contained protection systems and the conformity of the documents required in 8.1.2.2 (e) to (h) and 8.1.2.3 (r) to (v) with the circumstances on board; (f) A certificate concerning the inspection of the fire-extinguishing hoses prescribed in 8.1.6.1 and a certificate concerning the inspection of the special equipment prescribed in 8.1.6.3; (g) A book in which all required measurement results are recorded; (h) A copy of the relevant text of the special authorizations referred to in 1.5 if the transport operation is performed under this/these special authorization(s); (i) Means of identification, which include a photograph, for each crew member, in accordance with 1.10.1.4; and (j) (Deleted). (k) For vessels which carry hose assemblies used for loading, unloading or delivering liquefied natural gas for the operation of the vessel, the inspection certificate and the documentation of the calculated maximum load stress prescribed in 8.1.6.2. 8.1.2.2 In addition to the documents prescribed in 8.1.2.1, the following documents shall be carried on board dry cargo vessels: (a) The stowage plan prescribed in 7.1.4.11; (b) The ADN specialized knowledge certificate prescribed in 8.2.1.2; (c) For vessels complying with the additional requirements for double-hull vessels: - a damage-control plan; - the documents concerning intact stability as well as all conditions of intact stability taken into account for the damaged stability calculation in a form the master understands; - the certificate of the recognized classification society (see 9.1.0.88 or 9.2.0.88); (d) The inspection certificates concerning the fixed fire extinguishing systems prescribed in 9.1.0.40.2.9. (e) A list of or a general plan indicating the fixed installations and equipment suitable for use at least in zone 1 and the installations and equipment complying with 9.1.0.51; (f) A list of or a general plan indicating the fixed installations and equipment which are not authorized for use during loading and unloading, during a stay near to or within an onshore assigned zone (marked in red according to 9.1.0.52.2); (g) A plan indicating the boundaries of the zones and the location of the electrical and non-electrical equipment installed in the relevant zones intended for used in explosion hazardous areas; (h) A list of the installations and equipment referred to under (g) with the following information: - Installation/equipment, location, marking (explosion protection level according to IEC 60079-0, equipment category according to Directive 2014/34/EU*) or equivalent protection level, explosion group, temperature class, type of protection, test body) in case of electrical equipment for use in zone 1 (alternatively, a copy of the certificate of conformity according to Directive 2014/34/EU*)); - Installation/equipment, location, marking (explosion protection level according to IEC 60079-0, equipment category according to Directive 2014/34/EU*) or equivalent protection level, including explosion group and temperature class, type of protection, identification number) in case of electrical equipment for use in zone 2 and in the case of non-electrical equipment for use in zone 1 and zone 2 (alternatively, a copy of the certificate of conformity according to Directive 2014/34/EU*)); The documents listed in paragraphs (e) to (h) shall bear the stamp of the competent authority issuing the certificate of approval. 8.1.2.3 In addition to the documents prescribed in 8.1.2.1, the following documents shall be carried on board tank vessels: (a) The cargo stowage plan prescribed in 7.2.4.11.2; (b) The ADN specialized knowledge certificate prescribed in 8.2.1.2; (c) For vessels which have to conform to the conditions of damage-control (see 9.3.1.15, 9.3.2.15 or 9.3.3.15) - a damage-control plan; - the documents concerning intact stability as well as all conditions of intact stability taken into account for the damaged stability calculation in a form the master understands; the stability booklet and the proof of the loading instrument having been approved by the recognized classification society; (d) (Deleted); (e) The certificate of class issued by the recognized classification society prescribed in 9.3.1.8.1, 9.3.2.8.1 or 9.3.3.8.1; (f) The certificates concerning the inspection of the gas detection systems and the oxygen measuring system prescribed in 8.1.6.3; (g) The vessel substance list prescribed in 1.16.1.2.5; (h) The inspection certificate for the hose assemblies for loading and unloading prescribed in 8.1.6.2; (i) The instructions relating to the loading and unloading flows prescribed in 9.3.2.25.9 or 9.3.3.25.9; (j) The inspection certificate of the cargo pump-rooms prescribed in 8.1.8; (k) In the event of the carriage of goods having a melting point > 0° C, heating instructions; (l) (Deleted); (m) The registration document referred to in 8.1.11; (n) For the carriage of refrigerated substances, the instruction required in 7.2.3.28; (o) The certificate concerning the refrigeration system, prescribed in 9.3.1.27.10, 9.3.2.27.10 or 9.3.3.27.10; (p) The inspection certificates concerning the fixed fire extinguishing systems prescribed in 9.3.1.40.2.9, 9.3.2.40.2.9 or 9.3.3.40.2.9; and (q) When carrying refrigerated liquefied gases and the temperature is not controlled in accordance with 9.3.1.24.1 (a) and 9.3.1.24.1 (c), the determination of the holding time (7.2.4.16.16, 7.2.4.16.17 and documentation on the heat transmission coefficient); (r) A list of or a general plan indicating the fixed installations and equipment suitable to be used at least in zone 1 and the installations and equipment complying with 9.3.x.51; (s) A list of or a general plan indicating the fixed installations and equipment which are not authorized for use during loading and unloading, gas-freeing or during a stay near to or within an onshore assigned zone (marked in red according to 9.3.1.52.3, 9.3.2.52.3 or 9.3.3.52.3); (t) A plan approved by a recognized classification society indicating the boundaries of the zones and the location of the electrical and non-electrical equipment installed in the relevant zone intended to be used in explosion hazardous areas, as well as self-contained protection systems; (u) A list of the installations/equipment referred to under (t) and of the self-contained protection systems, with the following information: - Installations/equipment, location, marking (explosion protection level according to IEC 60079-0, equipment category according to Directive 2014/34/EU*) or at least equivalent), including explosion group and temperature class, type of protection and test body, in the case of electrical equipment for use in zone 0 or zone 1 and, in the case of non-electrical equipment for use in zone 0; (alternatively, a copy of the inspection certificate, for example the declaration of conformity under Directive 2014/34/EU*)); - Installation/equipment, location, marking (explosion protection level according to IEC 60079-0, equipment category according to Directive 2014/34/EU*) or equivalent protection level, including explosion group and temperature class, type of protection, identification number) in the case of electrical equipment for use in zone 2 and in the case of non-electrical equipment for use in zone 1 and zone 2 (alternatively, a copy of the inspection certificate, for example, the certificate of conformity according to Directive 2014/34/EU*)); - Self-protection system, place of installation, marking (explosion group/subgroup): (v) A list of or general plan indicating the fixed installations and equipment installed outside the explosion hazardous areas that may be used during loading, unloading, gas-freeing, berthing or during a stay in the immediate vicinity of or within an onshore assigned zone, if not referred to in (r) and (u). The documents listed in (r) to (v) shall bear the stamp of the competent authority issuing the certificate of approval. (w) The certificates required under 3.2.3.1, Explanations concerning Table C, explanatory note for column (20), remark 12 subparagraphs (p) and (q), if appropriate; (x) The certificates required under 3.2.3.1, Explanations concerning Table C, explanatory note for column (20), remark 33 subparagraphs (i), (n) and (o), if appropriate. 8.1.2.4 The instructions in writing referred to in 5.4.3 shall be handed to the master before loading. They shall be kept readily at hand in the wheelhouse. On board dry cargo vessels, the transport documents shall be handed to the master before loading and on board tank vessels they shall be handed to him after loading and before the journey commences. 8.1.2.5 (Reserved) 8.1.2.6 The presence on board of the certificate of approval is not required in the case of pusher barges which are not carrying dangerous goods, provided that the following additional particulars are indicated, in identical lettering, on the plate furnished by CEVNI: Number of the certificate of approval: ... issued by: ... valid until: ... The barge-owner shall thereafter keep the certificate of approval and the annex covered by 1.16.1.4 in his possession. The similarity of the particulars on the plate and those contained in the certificate of approval shall be certified by a competent authority which shall affix its stamp to the plate. 8.1.2.7 The presence on board of the certificate of approval is not required in the case of dry cargo barges or tank barges carrying dangerous goods provided that the plate furnished by CEVNI is supplemented by a second metal or plastic plate reproducing by photo-optical means a copy of the entire certificate of approval. A photo-optical copy of the annex referred to in 1.16.1.4 is not required. The barge-owner shall thereafter keep the certificate of approval and the annex referred to in 1.16.1.4 in his possession. The similarity of the particulars on the plate and the certificate of approval shall be certified by a competent authority which shall affix its stamp to the plate. 8.1.2.8 All documents shall be on board in a language the master is able to read and understand. If that language is not English, French or German, all documents, with the exception of the copy of ADN with its annexed Regulations and those for which the Regulations include special provisions concerning languages, shall be on board also in English, French or German, unless agreements concluded between the countries concerned in the transport operation provide otherwise. 8.1.2.9 8.1.2.1 (b), 8.1.2.1 (g), 8.1.2.4 and 8.1.2.5 do not apply to oil separator vessels or supply vessels. 8.1.2.1 (c) does not apply to oil separator vessels. __________ *) Official Journal of the European Union No. L 96 of 29 March 2014, p. 309.

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• 8.1.3 (Reserved)
• 8.1.4 Fire-extinguishing arrangements

  8.1.4 Fire-extinguishing arrangements

  8.1.4 Fire-extinguishing arrangements In addition to the fire-extinguishing appliances prescribed in the Regulations referred to in 1.1.4.6, each vessel shall be equipped with at least two additional hand fire-extinguishers having the same capacity. The fire-extinguishing agent contained in these additional hand fire-extinguishers shall be suitable for fighting fires involving the dangerous goods carried.

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• 8.1.5 Special equipment

  8.1.5 Special equipment

  8.1.5.3 For pushed convoys or side-by-side formations under way, it shall be sufficient, however, if the pusher tug or the vessel propelling the formation is equipped with the special equipment referred to in 8.1.5.1 above, when this is required in Chapter 3.2, Tables A or C.

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According to chapter 8.3 of the ADN, the following also apply:

• 8.3 Miscellaneous requirements to be complied with by the crew of the vessel

  8.3 Miscellaneous requirements to be complied with by the crew of the vessel

  8.3 MISCELLANEOUS REQUIREMENTS TO BE COMPLIED WITH BY THE CREW OF THE VESSEL 8.3.1 Persons authorized on board 8.3.1.1 Unless otherwise provided for in Part 7, only the following persons are authorized to be on board: (a) members of the crew; (b) persons who, although not being members of the crew, normally live on board; and (c) persons who are on board for duty reasons. 8.3.1.2 The persons referred to in 8.3.1.1 (b) are not authorized to remain in the protected area of dry cargo vessels or in the cargo area of tank vessels except for short periods. 8.3.1.3 When the vessel is required to carry two blue cones or two blue lights in accordance with column (19) of Table C of Chapter 3.2, persons under 14 years of age are not permitted on board. 8.3.2 Portable lighting apparatus On board, only portable lighting appliances with their own source of power are permitted in explosion hazardous areas and on deck. In explosion hazardous areas, they shall meet at least the requirements for use in the relevant area. 8.3.3 Admittance on board No unauthorized person shall be permitted on board. This prohibition shall be displayed on notice boards at appropriate places. 8.3.4 Prohibition on smoking, fire and naked light Smoking, including of electronic cigarettes and similar devices, fire and naked light are prohibited on board. However, the provisions of 7.1.3.41.1 and 7.2.3.41.1 are applicable. This prohibition shall be displayed on notice boards at appropriate places. The prohibition does not apply in the accommodation or the wheelhouse, provided that their windows, doors, skylights and hatches are closed or the ventilation system is adjusted to guarantee an overpressure of at least 0.1 kPa. 8.3.5 Work on board No work requiring the use of an open flame or electric current or liable to cause sparks may be carried out on board. This provision does not apply: - To berthing operations; - In the service spaces outside the protected area or the cargo area, provided the doors and openings of those areas are closed for the duration of the work and the vessel is not being loaded, unloaded or gas-freed; or - When the vessel is not in the vicinity of or within an onshore assigned zone and, in the case of a tank vessel, has a certificate attesting to the totally gas-free condition of the vessel in accordance with 7.2.3.7.6 or an authorization from the competent authority or in the case of a dry cargo vessel, has a certificate attesting to the totally gas-free condition of the protected area or an authorization from the competent authority. The use of low-sparking hand-tools (chromium vanadium steel screwdrivers and wrenches or screwdrivers and wrenches of equivalent material from the point of view of spark formation) and appropriate equipment at least for the zone concerned is permitted. NOTE: In addition, all other applicable regulations regarding workplace safety and safety of operations must be observed.

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According to chapter 3.2, table A, column 10 and subsection 7.1.6.12, the following special provisions apply to ventilation of dry cargo vessels:

According to chapter 9.1 of the ADN, the following regulations apply to dry cargo vessels:

• 9.1.0.12 Ventilation

  9.1.0.12 Ventilation

  Ventilation of dry cargo vessels 9.1.0.12 Ventilation 9.1.0.12.1 It must be possible to ventilate each hold by means of two mutually independent extraction ventilators having a capacity of not less than five changes of air per hour based on the volume of the empty hold. The extraction ducts shall be positioned at the extreme ends of the hold and extend down to not more than 50 mm above the bottom. The extraction of gases and vapours through the duct shall also be ensured for carriage in bulk. If the extraction ducts are movable they shall be suitable for the ventilator assembly and capable of being firmly fixed. Protection shall be ensured against bad weather and spray. The air intake shall be ensured during ventilation. 9.1.0.12.2 The ventilation system of a hold shall be arranged so that dangerous gases cannot penetrate into the accommodation, wheelhouse or engine rooms. 9.1.0.12.3 (a) Ventilation shall be provided for the accommodation, wheelhouse and for service spaces; (b) The ventilation system in such spaces shall meet the following requirements: (i) The air intakes of the ventilation system shall be located as far away as possible, and not less than 6.00 m from the protected area and not less than 2.00 m above the deck; (ii) Overpressure of at least 0.1 kPa (0.001 bar) may be maintained in the premises; (iii) A breakdown alarm is integrated; (iv) The ventilation system, including the breakdown alarm, shall be at least of the "limited explosion risk" type; (v) A gas detection system conforming to conditions 1. to 4. below is connected to the ventilation system: 1. It is appropriate at least for use in zone 1, explosion group IIC and temperature class T6; 2. It is equipped with sensors: - On the suction inlets of the ventilation systems; and - Directly below the top edge of the sill of the entrance doors; 3. Its t90-time is lower than or equal to 4 s; 4. Measurement shall be continuous; (vi) In the service spaces, the ventilation system is linked to the emergency lighting, which shall be at least of the "limited explosion risk" type; This emergency lighting is not necessary if the lighting installations in the service spaces are of at least the "limited explosion risk" type; (vii) The suction of the ventilation system and installations and equipment that do not meet the requirements of 9.1.0.51 and 9.1.0.52.1 shall be shut down when a concentration equal to 20 % of the LEL of n-Hexane is reached; The switching-off shall be indicated in the accommodation and wheelhouse by visual and audible signals; (viii) In the event of failure of the ventilation system or of the gas detection installations in the accommodation, installations and equipment in the accommodation that do not comply with the requirements of 9.1.0.51 and 9.1.0.52.1 shall be switched off; The switching-off shall be indicated in the accommodation, the wheelhouse and on the deck by visual and audible signals; (ix) In the event of failure of the ventilation system or of the gas detection installations in the wheelhouse or the service spaces, installations and equipment in those spaces that do not comply with the requirements of 9.1.0.51 and 9.1.0.52.1 shall be switched off; The switching-off shall be indicated in the wheelhouse and on the deck by visual and audible signals. The alarm must be relayed to the accommodation automatically if it has not been switched off; (x) Any switching-off shall take place immediately and automatically and, if necessary, shall switch on the emergency lighting; The automatic switch-off device is set so that no automatic switching-off may occur while the vessel is under way; (c) If there is no ventilation system or the ventilation system of a space does not comply with all the requirements set out in (b) above, any installations or equipment present in that space that may, if switched on, give rise to surface temperatures higher than those mentioned in 9.1.0.51 or that do not meet the requirements set out in 9.1.0.52.1 must be capable of being switched off. 9.1.0.12.4 Notice boards shall be fitted at the ventilation inlets indicating the conditions under which they shall be closed. All ventilation inlets of accommodation, wheelhouse and service spaces leading into the open air outside of the protected area shall be located not less than 2.00 m from the protected area. All ventilation inlets shall be fitted with fixed devices according to 9.1.0.40.2.2 (c) enabling them to be closed rapidly. It shall be clear whether they are open or closed. 9.1.0.12.5 Ventilators including their motors used within the protected area and motors for hold ventilators which are arranged in the air flow shall fulfil at least the requirements for use in zone 1. They shall meet at least the requirements for temperature class T4 and explosion group II B. 9.1.0.12.6 The requirements of 9.1.0.12.3 (b) or (c) must be met only if the vessel is located within or in the immediate vicinity of a shoreside assigned zone.

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