Aufhebung der bisher geltenden Beschränkung für die Durchfahrt ab 06.04.2016
Niedersachsen
A 38 - Heidkopftunnel
Aufhebung der bisher geltenden Beschränkung für die Durchfahrt
Niedersachsen
A 31 - Emstunnel
B (ganztägig)
Niedersachsen
B 437 - Wesertunnel
Aufhebung der bisher geltenden Beschränkung für die Durchfahrt
Nordrhein-Westfalen
A 1 - Einhausung/Tunnel Köln-Lövenich
Köln-Lövenich
Aufhebung der bisher geltenden Beschränkung für die Durchfahrt
Nordrhein-Westfalen
B 9 - Tunnel Bad Godesberg
Bonn-Bad Godesberg
E (ganztägig)
Nordrhein-Westfalen
B 55a -Tunnel Grenzstraße
Köln-Buchforst
E (ganztägig), ab 31. KW 2013 bis Ende 2022
Geschwindigkeitsreduzierung im Tunnel auf 50 km/h und Verbot der Durchfahrt des Tunnels für den Schwerlastverkehr (ab 7,5 t).
Nordrhein-Westfalen
B 55a -Tunnel Köln-Kalk
E (ganztägig)
Nordrhein-Westfalen
B 61n - Streckenabschnitt 99.1 Weserauentunnel
B 61, Abschnitt 99,1, von Station 177 bis Station 1910 / Porta Westfalica - Barkhausen
E (ganztägig)
Kategorisiert seit 21.04.2011
Nordrhein-Westfalen
Am Bahndamm, Verlängerung Trankgasse zum Konrad-Adenauer-Ufer
Innerorts Stadt Köln
E (ganztägig), ab dem 15.12.2017 angeordnet
Meldung der Stadt Köln, Amt für Brücken, Tunnel und Stadtbahnbau am 2.11.2017. Verkehrsbehördliche Anordnung durch Stadt Köln, Amt für Straßen und Verkehrstechnik erfolgte am 15.12.2017
Schleswig-Holstein
B 104 - Herrentunnel
Lübeck
E (ganztägig)
Umleitung über Travemünder Allee (B 75), Eric-Warburg-Brücke (K 25), BAB A 1 und A 226
Thüringen
A 71 - Tunnel Alte Burg
km 112,3 - 113,2
E (ganztägig)
Thüringen
A 71 - Tunnel Rennsteig
km 114,8 - 122,7
E (ganztägig)
Thüringen
A 71 - Tunnel Hochwald
km 123,6 - 124,3
E (ganztägig)
Thüringen
A 71 - Tunnel Berg Bock
km 126,4 - 129,0
E (ganztägig)
UN 90032-Ethylhexyl acrylate, stabilizedADN 2025 (Detailinfo)
All topics
Substance information(collapsed)
The BAM name is based on the "name and description" from the regulations and the IUPAC rules, but may be supplemented with further information so that significant differences between two dangerous goods data sets are apparent.
Language
BAM name
German
2-Ethylhexylacrylat, stabilisiert
English
2-Ethylhexyl acrylate, stabilized
French
Acrylate de 2-éthylhexyle, stabilisé
The aggregate state is given under normal conditions, i.e. at room temperature of 20 °C and normal pressure of 101.3 kPa.
Aggregate state
under normal conditions
liquid
during transport
liquid
The formula describes the chemical composition of a substance.
Formula
C11H20O2
The BAM number is used to uniquely identify a substance or object in the BAM dangerous goods data pool.
BAM no.
1387
CAS no.
103-11-7
EC no.
203-080-7
Index no.
607-107-00-7
ZVG nos.
15610
Classification(collapsed)
General
ID no.
9003
Class
Class 9
Miscellaneous dangerous substances and articles
Labels
none
Packing group
Compatibility group
Special provisions
none
Inland waterway transport
Classification code
Classification code M12
Other substances and articles presenting a danger during carriage in tank vessels, but not meeting the definitions of another class
Cones/Lights
0
Remark (german):Dieser Stoff ist in Tabelle C des ADN namentlich unter der Stoffnummer 9003 genannt. Der Stoff neigt jedoch zur Polymerisation. Der BAM liegen derzeit keine Informationen zur Temperatur der selbstbeschleunigenden Polymerisation (SAPT) in den verschiedenen Umschließungen und zur Reaktionswärme vor. Die angegeben Klassifizierung gilt für den Fall, dass der Stoff eine SAPT größer 75 °C oder eine Reaktionswärme von höchstens 300 J/g aufweist.
Sollte der Stoff bei Beförderung in Verpackungen, Großpackmitteln (IBC) oder Tanks eine Temperatur der selbstbeschleunigenden Polymerisation (SAPT) von höchstens 75 °C und eine Reaktionswärme von mehr als 300 J/g aufweisen, ist er der
UN-Nr. 3532 POLYMERISIERENDER STOFF, FLÜSSIG, STABILISIERT, N.A.G.
in der Klasse 4.1 zuzuordnen.
Bei einer Beförderung in Verpackungen oder Großpackmitteln (IBC) mit einer SAPT von höchstens 50 °C bzw. in Tanks von höchstens 45 °C muss eine Zuordnung zur
UN-Nr. 3534 POLYMERISIERENDER STOFF, FLÜSSIG, TEMPERATURKONTROLLIERT, N.A.G.
in der Klasse 4.1 erfolgen.
Names(collapsed)
Transport document names3
German
STOFFE MIT EINEM FLAMMPUNKT ÜBER 60 °C UND HÖCHSTENS 100 °C (2-ETHYLHEXYLACRYLAT, STABILISIERT)
English
SUBSTANCES WITH A FLASH-POINT ABOVE 60 °C AND NOT MORE THAN 100 °C (2-ETHYLHEXYLACRYLATE; STABILIZED)
French
MATIÈRES DONT LE POINT D'ÉCLAIR EST SUPÉRIEUR À 60 °C MAIS INFÉRIEUR OU ÉGAL À 100 °C (ACRYLATE D'ÉTHYL-2 HEXYLE, STABILISÉ)
Instruction names3
German
STOFFE MIT EINEM FLAMMPUNKT ÜBER 60 °C UND HÖCHSTENS 100 °C, die nicht anderen Klassen zuzuordnen sind
English
SUBSTANCES WITH A FLASH-POINT ABOVE 60 °C AND NOT MORE THAN 100 °C, which do not belong to another Class
French
MATIÈRES DONT LE POINT D'ÉCLAIR EST SUPÉRIEUR À 60 °C MAIS INFÉRIEUR OU ÉGAL À 100 °C, qui ne sont pas affectées à une autre classe
Synonyms0
Synonyms for transport documents9
English
2-Ethylhexyl 2-propenoate
English
2-Propenoic acid, 2-ethylhexyl ester
German
2-Propensäure-2-ethylhexylester
French
Acrylate d'éthyl-2 hexyle
English
Acrylic acid, 2-ethylhexyl ester
German
Acrylsäure-2-ethylhexylester
French
Ester 2-éthylhexylique de l'acide acrylique
French
Ester 2-éthylhexylique de l'acide propénique
French
Ester 2-éthylhexylique de l'acide propénoïque
INCI synonyms0
Synonyms (not recommended)0
Transport exlusions(collapsed)
Transport status of this substance/article
Subject to this regulation only in tank vessels
Labelling(collapsed)
Packagings
Label / Mark
Notice
not stated - subject to the requirements only in tank vessels
Remarks on labelling
For empty packagings sub-section 4.1.1.11 of the ADR, RID or the IMDG Code shall apply:
"Empty packagings, including IBCs and large packagings, that have contained a dangerous substance are subject to the same requirements as those for a filled packaging, unless adequate measures have been taken to nullify any hazard."
Furthermore the following provisions apply:
5.2.1.8 Special marking provisions for environmentally hazardous substances
5.2.1.8.1 Packages containing environmentally hazardous substances meeting the criteria of 2.2.9.1.10 shall be durably marked with the environmentally hazardous substance mark shown in 5.2.1.8.3 with the exception of single packagings and combination packagings where such single packagings or inner packagings of such combination packagings have:
- a quantity of 5 l or less for liquids; or
- a net mass of 5 kg or less for solids.
5.2.1.8.2 The environmentally hazardous substance mark shall be located adjacent to the marks required by 5.2.1.1. The requirements of 5.2.1.2 and 5.2.1.4 shall be met.
5.2.1.8.3 The environmentally hazardous substance mark shall be as shown in Figure 5.2.1.8.3.
The mark shall be in the form of a square set at an angle of 45° (diamond-shaped). The symbol (fish and tree) shall be black on white or suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. If the size of the package so requires, the dimensions/line thickness may be reduced, provided the mark remains clearly visible. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
NOTE: The labelling provisions of 5.2.2 apply in addition to any requirement for packages to bear the environmentally hazardous substance mark.
-- Remark from BAM --
Since the information on environmentally hazardous properties of the substances contained in the Dangerous Goods Database is not currently available for all substances, the user must check if such a mark is required for the substance to be transported.
5.2.1.9 Battery mark
5.2.1.9.1 Packages containing lithium cells or batteries or sodium ion cells or batteries prepared in accordance with special provisions 188 or 400 of Chapter 3.3 shall be marked as shown in Figure 5.2.1.9.2.
5.2.1.9.2 The mark shall indicate the UN number preceded by the letters "UN", i.e. "UN 3090" for lithium metal cells or batteries, "UN 3480" for lithium ion cells or batteries, or "UN 3551" for sodium ion cells or batteries. Where the cells or batteries are contained in, or packed with, equipment, the UN number preceded by the letters "UN", i.e. "UN 3091", "UN 3481" or "UN 3552" as appropriate shall be indicated. Where a package contains cells or batteries assigned to different UN numbers, all applicable UN numbers shall be indicated on one or more marks.
The mark shall be in the form of a rectangle or a square with hatched edging. The dimensions shall be a minimum of 100 mm wide x 100 mm high and the minimum width of the hatching shall be 5 mm. The symbol (group of batteries, one damaged and emitting flame, above the UN number(s)) shall be black on white or suitable contrasting background. The hatching shall be red. If the size of the package so requires, the dimensions may be reduced to not less than 100 mm wide x 70 mm high. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
5.2.1.10 Orientation arrows
5.2.1.10.1 Except as provided in 5.2.1.10.2:
(a) combination packagings having inner packagings containing liquids;
(b) single packagings fitted with vents;
(c) closed or open cryogenic receptacles intended for the carriage of refrigerated liquefied gases; and
(d) machinery or apparatus containing liquid dangerous goods when it is required to ensure the liquid dangerous goods remain in their intended orientation (see special provision 301 of Chapter 3.3), shall be legibly marked with package orientation arrows which are similar to the illustration shown below or with those meeting the specifications of ISO 780:1997. The orientation arrows shall appear on two opposite vertical sides of the package with the arrows pointing in the correct upright direction. They shall be rectangular and of a size that is clearly visible commensurate with the size of the package. Depicting a rectangular border around the arrows is optional.
5.2.1.10.2 Orientation arrows are not required on:
(a) Outer packagings containing pressure receptacles except closed or open cryogenic receptacles;
(b) Outer packagings containing dangerous goods in inner packagings each containing not more than 120 ml, with sufficient absorbent material between the inner and outer packagings to completely absorb the liquid contents;
(c) Outer packagings containing Class 6.2 infectious substances in primary receptacles each containing not more than 50 ml;
(d) Type IP-2, type IP-3, type A, type B(U), type B(M) or type C packages containing Class 7 radioactive material;
(e) Outer packagings containing articles which are leak-tight in all orientations (e.g. alcohol or mercury in thermometers, aerosols, etc.); or
(f) Outer packagings containing dangerous goods in hermetically sealed inner packagings each containing not more than 500 ml.
5.2.1.10.3 Arrows for purposes other than indicating proper package orientation shall not be displayed on a package marked in accordance with this sub-section.
----------
5.2.2.2 Provisions for labels
5.2.2.2.1 Labels shall satisfy the provisions below and conform, in terms of colour, symbols and general format, to the models shown in 5.2.2.2.2. Corresponding models required for other modes of transport, with minor variations which do not affect the obvious meaning of the label, are also acceptable.
NOTE: Where appropriate, labels in 5.2.2.2.2 are shown with a dotted outer boundary as provided for in 5.2.2.2.1.1. This is not required when the label is applied on a background of contrasting colour.
5.2.2.2.1.1 Labels shall be configured as shown in Figure 5.2.2.2.1.1.
5.2.2.2.1.1.1 Labels shall be displayed on a background of contrasting colour, or shall have either a dotted or solid outer boundary line.
5.2.2.2.1.1.2 The label shall be in the form of a square set at an angle of 45° (diamond-shaped). The minimum dimensions shall be 100 mm x 100 mm. There shall be a line inside the edge forming the diamond which shall be parallel and approximately 5 mm from the outside of that line to the edge of the label. The line inside the edge on the upper half of the label shall be the same colour as the symbol and the line inside the edge on the lower half of the label shall be the same colour as the class or division number in the bottom corner. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
5.2.2.2.1.1.3 If the size of the package so requires the dimensions may be reduced proportionally, provided the symbols and other elements of the label remain clearly visible. Dimensions for cylinders shall comply with 5.2.2.2.1.2.
5.2.2.2.1.2 Gas cylinders for Class 2 may, on account of their shape, orientation and securing mechanisms for carriage, bear labels representative of those specified in this section and the environmentally hazardous substance mark when appropriate, which have been reduced in size, according to the dimensions outlined in ISO 7225:2005, "Gas cylinders - Precautionary labels", for display on the non-cylindrical part (shoulder) of such cylinders.
NOTE: When the diameter of the cylinder is too small to permit the display of the reduced size labels on the non-cylindrical upper part of the cylinder, the reduced sized labels may be displayed on the cylindrical part.
Notwithstanding the provisions of 5.2.2.1.6, labels and the environmentally hazardous substance mark (see 5.2.1.8.3) may overlap to the extent provided for by ISO 7225:2005. However, in all cases, the primary hazard label and the figures appearing on any label shall remain fully visible and the symbols recognizable.
Empty uncleaned pressure receptacles for gases of Class 2 may be carried with obsolete or damaged labels for the purposes of refilling or inspection as appropriate and the application of a new label in conformity with current regulations or for the disposal of the pressure receptacle.
5.2.2.2.1.3 With the exception of labels for Divisions 1.4, 1.5 and 1.6 of Class 1, the upper half of the label shall contain the pictorial symbol and the lower half shall contain:
(a) For Classes 1, 2, 3, 5.1, 5.2, 7, 8 and 9, the class number;
(b) For Classes 4.1, 4.2 and 4.3, the figure "4";
(c) For Classes 6.1 and 6.2, the figure "6".
However for label model No. 9A, the upper half of the label shall only contain the seven vertical stripes of the symbol and the lower half shall contain the group of batteries of the symbol and the class number.
Except for label model No. 9A, the label may include text such as the UN number or words describing the hazard (e.g. "flammable") in accordance with 5.2.2.2.1.5 provided the text does not obscure or detract from the other required label elements.
5.2.2.2.1.4 In addition, except for Divisions 1.4, 1.5 and 1.6, labels for Class 1 shall show in the lower half, above the class number, the division number and the compatibility group letter for the substance or article. Labels for Divisions 1.4, 1.5 and 1.6 shall show in the upper half the division number, and in the lower half the class number and the compatibility group letter.
5.2.2.2.1.5 On labels other than those for material of Class 7, the optional insertion of any text (other than the class number) in the space below the symbol shall be confined to particulars indicating the nature of the hazard and precautions to be taken in handling.
5.2.2.2.1.6 The symbols, text and numbers shall be clearly legible and indelible and shall be shown in black on all labels except for:
(a) the Class 8 label, where the text (if any) and class number shall appear in white;
(b) labels with entirely green, red or blue backgrounds where they may be shown in white;
(c) the Class 5.2 label, where the symbol may be shown in white; and
(d) labels conforming to model No. 2.1 displayed on cylinders and gas cartridges for liquefied petroleum gases, where they may be shown in the background colour of the receptacle if adequate contrast is provided.
5.2.2.2.1.7 All labels shall be able to withstand open weather exposure without a substantial reduction in effectiveness.
----------
For gases which may be used for cooling or conditioning purposes see section 5.5.3:
5.5.3 Special provisions applicable to the carriage of dry ice (UN 1845) and to packages and vehicles and containers containing substances presenting a risk of asphyxiation when used for cooling or conditioning purposes (such as dry ice (UN 1845) or nitrogen, refrigerated liquid (UN 1977) or argon, refrigerated liquid (UN 1951) or nitrogen)
NOTE: In the context of this section the term "conditioning" may be used in a broader scope and includes protection.
5.5.3.1 Scope
5.5.3.1.1 This section is not applicable to substances which may be used for cooling or conditioning purposes when carried as a consignment of dangerous goods, except for the carriage of dry ice (UN No. 1845). When they are carried as a consignment, these substances shall be carried under the relevant entry of Table A of Chapter 3.2 in accordance with the associated conditions
of carriage.
For UN No. 1845, the conditions of carriage specified in this section, except 5.5.3.3.1, apply for all kinds of carriage, as a coolant, conditioner, or as a consignment. For the carriage of UN No. 1845, no other provisions of ADN apply.
5.5.3.1.2 This section is not applicable to gases in cooling cycles.
5.5.3.1.3 Dangerous goods used for cooling or conditioning tanks or MEGCs during carriage are not subject to this section.
5.5.3.1.4 Vehicles, wagons and containers containing substances used for cooling or conditioning purposes include vehicles, wagons and containers containing substances used for cooling or conditioning purposes inside packages as well as vehicles, wagons and containers with unpackaged substances used for cooling or conditioning purposes.
5.5.3.1.5 Sub-sections 5.5.3.6 and 5.5.3.7 only apply when there is an actual risk of asphyxiation in the vehicle, wagon or container. It is for the participants concerned to assess this risk, taking into consideration the hazards presented by the substances being used for cooling or conditioning, the amount of substance to be carried, the duration of the journey, the types of containment to be used and the gas concentration limits given in the note to 5.5.3.3.3.
5.5.3.2 General
5.5.3.2.1 Vehicles, wagons and containers in which dry ice (UN 1845) is carried or containing substances used for cooling or conditioning purposes (other than fumigation) during carriage are not subject to any provisions of ADN other than those of this section.
5.5.3.2.2 When dangerous goods are loaded in vehicles, wagons or containers containing substances used for cooling or conditioning purposes any provisions of ADN relevant to these dangerous goods apply in addition to the provisions of this section.
5.5.3.2.3 (Reserved)
5.5.3.2.4 Persons engaged in the handling or carriage of vehicles, wagons and containers in which dry ice (UN 1845) is carried or containing substances used for cooling or conditioning purposes shall be trained commensurate with their responsibilities.
5.5.3.3 Packages containing dry ice (UN 1845) or a coolant or conditioner
5.5.3.3.1 Packaged dangerous goods requiring cooling or conditioning assigned to packing instructions P203, P620, P650 or P800 of 4.1.4.1 of ADR shall meet the appropriate requirements of that packing instruction.
5.5.3.3.2 For packaged dangerous goods requiring cooling or conditioning assigned to other packing instructions, the packages shall be capable of withstanding very low temperatures and shall not be affected or significantly weakened by the coolant or conditioner. Packages shall be designed and constructed to permit the release of gas to prevent a build-up of pressure that could rupture the packaging. The dangerous goods shall be packed in such a way as to prevent movement after the dissipation of any coolant or conditioner.
5.5.3.3.3 Packages containing dry ice (UN 1845) or a coolant or conditioner shall be carried in well ventilated vehicles, wagons and containers. Marking according to 5.5.3.6 is not required in this case.
Ventilation is not required, and marking according to 5.5.3.6 is required, if:
- the load compartment is insulated, refrigerated or mechanically refrigerated equipment, for example as defined in the Agreement on the International Carriage of Perishable Foodstuffs and on the Special Equipment to be Used for such Carriage (ATP) and separated from the driver's cab;
- for vehicles, gas exchange between the load compartment and the driver's cab is prevented.
NOTE: In this context "well ventilated" means there is an atmosphere where the carbon dioxide concentration is below 0.5% by volume and the oxygen concentration is above 19.5% by volume.
5.5.3.4 Marking of packages containing dry ice (UN 1845) or a coolant or conditioner
5.5.3.4.1 Packages containing dry ice (UN 1845) as a consignment shall be marked "CARBON DIOXIDE, SOLID" or "DRY ICE"; packages containing dangerous goods used for cooling or conditioning shall be marked with the name indicated in Column (2) of Table A of Chapter 3.2 of these dangerous goods followed by the words "AS COOLANT" or "AS CONDITIONER" as appropriate in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements concluded between the countries concerned in the transport operation provide otherwise.
5.5.3.4.2 The marks shall be durable, legible and placed in such a location and of such a size relative to the package as to be readily visible.
...
Remarks on printing
See sections 5.1.2 and 5.1.3:
----------
5.1.2 Use of overpacks
5.1.2.1
a) (a) Unless marks and labels required in Chapter 5.2, except 5.2.1.3 to 5.2.1.6, 5.2.1.7.2 to 5.2.1.7.8 and 5.2.1.10, representative of all dangerous goods in the overpack are visible, the overpack shall be:
(i) marked with the word "OVERPACK". The lettering of the "OVERPACK" mark shall be at least 12 mm high. The mark shall be in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise; and
(ii) labelled and marked with the UN number and other marks, as required for packages in Chapter 5.2 except 5.2.1.3 to 5.2.1.6, 5.2.1.7.2 to 5.2.1.7.8 and 5.2.1.10, for each item of dangerous goods contained in the overpack. Each applicable mark or label only needs to be applied once.
Labelling of overpacks containing radioactive material shall be in accordance with 5.2.2.1.11.
(b) Orientation arrows illustrated in 5.2.1.10 shall be displayed on two opposite sides of overpacks containing packages which shall be marked in accordance with 5.2.1.10.1, unless the marks remains visible.
5.1.2.2 Each package of dangerous goods contained in an overpack shall comply with all applicable provisions of ADN. The intended function of each package shall not be impaired by the overpack.
5.1.2.3 Each package bearing package orientation marks as prescribed in 5.2.1.10 and which is overpacked or placed in a large packaging shall be oriented in accordance with such marks.
5.1.2.4 The prohibitions on mixed loading also apply to these overpacks.
5.1.3 Empty uncleaned packagings (including IBCs and large packagings), tanks, MEMUs, vehicles, wagons and containers for carriage in bulk
5.1.3.1 Empty uncleaned packagings (including IBCs and large packagings), tanks (including tankvehicles, tank-wagons, battery-vehicles, battery-wagons, demountable tanks, portable tanks, tank-containers, MEGCs, MEMUs), vehicles, wagons and containers for carriage in bulk having contained dangerous goods of the different classes other than Class 7, shall be marked and labelled as if they were full.
NOTE: For documentation, see Chapter 5.4.
----------
See section 5.2.1 Marking of packages
NOTE 1: For marks related to the construction, testing and approval of packagings, large packagings, pressure receptacles and IBCs, see Part 6 of ADR.
NOTE 2: In accordance with the GHS, a GHS pictogram not required by ADN should only appear in carriage as part of a complete GHS label and not independently (see GHS 1.4.10.4.4).
5.2.1.1 Unless provided otherwise in ADN, the UN number corresponding to the dangerous goods contained, preceded by the letters "UN" shall be clearly and durably marked on each package. The UN number and the letters "UN" shall be at least 12 mm high, except for packages of 30 l capacity or less or of 30 kg maximum net mass and for cylinders of 60 l water capacity or less when they shall be at least 6 mm in height and except for packages of 5 l capacity or less or of 5 kg maximum net mass when they shall be of an appropriate size. In the case of unpackaged articles the mark shall be displayed on the article, on its cradle or on its handling, storage or launching device.
5.2.1.2 All package marks required by this Chapter:
(a) shall be readily visible and legible;
(b) shall be able to withstand open weather exposure without a substantial reduction in effectiveness.
5.2.1.3 Salvage packagings, including large salvage packagings, and salvage pressure receptacles shall additionally be marked with the word "SALVAGE". The lettering of the "SALVAGE" mark shall be at least 12 mm high.
5.2.1.4 Intermediate bulk containers of more than 450 litres capacity and large packagings shall be marked on two opposite sides.
5.2.1.5 Additional provisions for goods of Class 1
For goods of Class 1, packages shall, in addition, bear the proper shipping name as determined in accordance with 3.1.2. The mark, which shall be clearly legible and indelible, shall be in one or more languages, one of which must be French, German or English, unless any agreements concluded between the countries concerned in the transport operation provide otherwise.
5.2.1.6 Additional provisions for goods of Class 2
Refillable receptacles shall bear the following particulars in clearly legible and durable characters:
(a) the UN number and the proper shipping name of the gas or mixture of gases, as determined in accordance with 3.1.2.
In the case of gases classified under an N.O.S. entry, only the technical name *1) of the gas has to be indicated in addition to the UN number.
In the case of mixtures, not more than the two constituents which most predominantly contribute to the hazards have to be indicated;
(b) for compressed gases filled by mass and for liquefied gases, either the maximum filling mass and the tare of the receptacle with fittings and accessories as fitted at the time of filling, or the gross mass;
(c) the date (year) of the next periodic inspection.
These particulars can either be engraved or indicated on a durable information disk or label attached on the receptacle or indicated by an adherent and clearly visible mark such as by printing or by any equivalent process.
NOTE 1: See also 6.2.2.7 of ADR.
NOTE 2: For non refillable receptacles, see 6.2.2.8 of ADR.
[...]
-----------------------------------------------
*1) Instead of the proper shipping name or, if applicable, of the proper shipping name of the n.o.s. entry followed by the technical name, the use of the following names is permitted:
- for UN No. 1078 refrigerant gas, n.o.s: mixture F1, mixture F2, mixture F3;
- for UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2;
- for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s: mixture A or butane, mixture A01 or butane, mixture A02 or butane, mixture A0 or butane, mixture A1, mixture B1, mixture B2, mixture B, mixture C or propane.
- for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized.
- for UN No. 1012 Butylene: 1-butylene, cis-2-butylene, trans-2-butylene, butylenes mixture.
IBC
Label / Mark
Notice
not stated - subject to the requirements only in tank vessels
Remarks on labelling
For empty packagings sub-section 4.1.1.11 of the ADR, RID or the IMDG Code shall apply:
"Empty packagings, including IBCs and large packagings, that have contained a dangerous substance are subject to the same requirements as those for a filled packaging, unless adequate measures have been taken to nullify any hazard."
Furthermore the following provisions apply:
5.2.1.8 Special marking provisions for environmentally hazardous substances
5.2.1.8.1 Packages containing environmentally hazardous substances meeting the criteria of 2.2.9.1.10 shall be durably marked with the environmentally hazardous substance mark shown in 5.2.1.8.3 with the exception of single packagings and combination packagings where such single packagings or inner packagings of such combination packagings have:
- a quantity of 5 l or less for liquids; or
- a net mass of 5 kg or less for solids.
5.2.1.8.2 The environmentally hazardous substance mark shall be located adjacent to the marks required by 5.2.1.1. The requirements of 5.2.1.2 and 5.2.1.4 shall be met.
5.2.1.8.3 The environmentally hazardous substance mark shall be as shown in Figure 5.2.1.8.3.
The mark shall be in the form of a square set at an angle of 45° (diamond-shaped). The symbol (fish and tree) shall be black on white or suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. If the size of the package so requires, the dimensions/line thickness may be reduced, provided the mark remains clearly visible. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
NOTE: The labelling provisions of 5.2.2 apply in addition to any requirement for packages to bear the environmentally hazardous substance mark.
-- Remark from BAM --
Since the information on environmentally hazardous properties of the substances contained in the Dangerous Goods Database is not currently available for all substances, the user must check if such a mark is required for the substance to be transported.
5.2.1.9 Battery mark
5.2.1.9.1 Packages containing lithium cells or batteries or sodium ion cells or batteries prepared in accordance with special provisions 188 or 400 of Chapter 3.3 shall be marked as shown in Figure 5.2.1.9.2.
5.2.1.9.2 The mark shall indicate the UN number preceded by the letters "UN", i.e. "UN 3090" for lithium metal cells or batteries, "UN 3480" for lithium ion cells or batteries, or "UN 3551" for sodium ion cells or batteries. Where the cells or batteries are contained in, or packed with, equipment, the UN number preceded by the letters "UN", i.e. "UN 3091", "UN 3481" or "UN 3552" as appropriate shall be indicated. Where a package contains cells or batteries assigned to different UN numbers, all applicable UN numbers shall be indicated on one or more marks.
The mark shall be in the form of a rectangle or a square with hatched edging. The dimensions shall be a minimum of 100 mm wide x 100 mm high and the minimum width of the hatching shall be 5 mm. The symbol (group of batteries, one damaged and emitting flame, above the UN number(s)) shall be black on white or suitable contrasting background. The hatching shall be red. If the size of the package so requires, the dimensions may be reduced to not less than 100 mm wide x 70 mm high. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
5.2.1.10 Orientation arrows
5.2.1.10.1 Except as provided in 5.2.1.10.2:
(a) combination packagings having inner packagings containing liquids;
(b) single packagings fitted with vents;
(c) closed or open cryogenic receptacles intended for the carriage of refrigerated liquefied gases; and
(d) machinery or apparatus containing liquid dangerous goods when it is required to ensure the liquid dangerous goods remain in their intended orientation (see special provision 301 of Chapter 3.3), shall be legibly marked with package orientation arrows which are similar to the illustration shown below or with those meeting the specifications of ISO 780:1997. The orientation arrows shall appear on two opposite vertical sides of the package with the arrows pointing in the correct upright direction. They shall be rectangular and of a size that is clearly visible commensurate with the size of the package. Depicting a rectangular border around the arrows is optional.
5.2.1.10.2 Orientation arrows are not required on:
(a) Outer packagings containing pressure receptacles except closed or open cryogenic receptacles;
(b) Outer packagings containing dangerous goods in inner packagings each containing not more than 120 ml, with sufficient absorbent material between the inner and outer packagings to completely absorb the liquid contents;
(c) Outer packagings containing Class 6.2 infectious substances in primary receptacles each containing not more than 50 ml;
(d) Type IP-2, type IP-3, type A, type B(U), type B(M) or type C packages containing Class 7 radioactive material;
(e) Outer packagings containing articles which are leak-tight in all orientations (e.g. alcohol or mercury in thermometers, aerosols, etc.); or
(f) Outer packagings containing dangerous goods in hermetically sealed inner packagings each containing not more than 500 ml.
5.2.1.10.3 Arrows for purposes other than indicating proper package orientation shall not be displayed on a package marked in accordance with this sub-section.
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5.2.2.2 Provisions for labels
5.2.2.2.1 Labels shall satisfy the provisions below and conform, in terms of colour, symbols and general format, to the models shown in 5.2.2.2.2. Corresponding models required for other modes of transport, with minor variations which do not affect the obvious meaning of the label, are also acceptable.
NOTE: Where appropriate, labels in 5.2.2.2.2 are shown with a dotted outer boundary as provided for in 5.2.2.2.1.1. This is not required when the label is applied on a background of contrasting colour.
5.2.2.2.1.1 Labels shall be configured as shown in Figure 5.2.2.2.1.1.
5.2.2.2.1.1.1 Labels shall be displayed on a background of contrasting colour, or shall have either a dotted or solid outer boundary line.
5.2.2.2.1.1.2 The label shall be in the form of a square set at an angle of 45° (diamond-shaped). The minimum dimensions shall be 100 mm x 100 mm. There shall be a line inside the edge forming the diamond which shall be parallel and approximately 5 mm from the outside of that line to the edge of the label. The line inside the edge on the upper half of the label shall be the same colour as the symbol and the line inside the edge on the lower half of the label shall be the same colour as the class or division number in the bottom corner. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
5.2.2.2.1.1.3 If the size of the package so requires the dimensions may be reduced proportionally, provided the symbols and other elements of the label remain clearly visible. Dimensions for cylinders shall comply with 5.2.2.2.1.2.
5.2.2.2.1.2 Gas cylinders for Class 2 may, on account of their shape, orientation and securing mechanisms for carriage, bear labels representative of those specified in this section and the environmentally hazardous substance mark when appropriate, which have been reduced in size, according to the dimensions outlined in ISO 7225:2005, "Gas cylinders - Precautionary labels", for display on the non-cylindrical part (shoulder) of such cylinders.
NOTE: When the diameter of the cylinder is too small to permit the display of the reduced size labels on the non-cylindrical upper part of the cylinder, the reduced sized labels may be displayed on the cylindrical part.
Notwithstanding the provisions of 5.2.2.1.6, labels and the environmentally hazardous substance mark (see 5.2.1.8.3) may overlap to the extent provided for by ISO 7225:2005. However, in all cases, the primary hazard label and the figures appearing on any label shall remain fully visible and the symbols recognizable.
Empty uncleaned pressure receptacles for gases of Class 2 may be carried with obsolete or damaged labels for the purposes of refilling or inspection as appropriate and the application of a new label in conformity with current regulations or for the disposal of the pressure receptacle.
5.2.2.2.1.3 With the exception of labels for Divisions 1.4, 1.5 and 1.6 of Class 1, the upper half of the label shall contain the pictorial symbol and the lower half shall contain:
(a) For Classes 1, 2, 3, 5.1, 5.2, 7, 8 and 9, the class number;
(b) For Classes 4.1, 4.2 and 4.3, the figure "4";
(c) For Classes 6.1 and 6.2, the figure "6".
However for label model No. 9A, the upper half of the label shall only contain the seven vertical stripes of the symbol and the lower half shall contain the group of batteries of the symbol and the class number.
Except for label model No. 9A, the label may include text such as the UN number or words describing the hazard (e.g. "flammable") in accordance with 5.2.2.2.1.5 provided the text does not obscure or detract from the other required label elements.
5.2.2.2.1.4 In addition, except for Divisions 1.4, 1.5 and 1.6, labels for Class 1 shall show in the lower half, above the class number, the division number and the compatibility group letter for the substance or article. Labels for Divisions 1.4, 1.5 and 1.6 shall show in the upper half the division number, and in the lower half the class number and the compatibility group letter.
5.2.2.2.1.5 On labels other than those for material of Class 7, the optional insertion of any text (other than the class number) in the space below the symbol shall be confined to particulars indicating the nature of the hazard and precautions to be taken in handling.
5.2.2.2.1.6 The symbols, text and numbers shall be clearly legible and indelible and shall be shown in black on all labels except for:
(a) the Class 8 label, where the text (if any) and class number shall appear in white;
(b) labels with entirely green, red or blue backgrounds where they may be shown in white;
(c) the Class 5.2 label, where the symbol may be shown in white; and
(d) labels conforming to model No. 2.1 displayed on cylinders and gas cartridges for liquefied petroleum gases, where they may be shown in the background colour of the receptacle if adequate contrast is provided.
5.2.2.2.1.7 All labels shall be able to withstand open weather exposure without a substantial reduction in effectiveness.
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For gases which may be used for cooling or conditioning purposes see section 5.5.3:
5.5.3 Special provisions applicable to the carriage of dry ice (UN 1845) and to packages and vehicles and containers containing substances presenting a risk of asphyxiation when used for cooling or conditioning purposes (such as dry ice (UN 1845) or nitrogen, refrigerated liquid (UN 1977) or argon, refrigerated liquid (UN 1951) or nitrogen)
NOTE: In the context of this section the term "conditioning" may be used in a broader scope and includes protection.
5.5.3.1 Scope
5.5.3.1.1 This section is not applicable to substances which may be used for cooling or conditioning purposes when carried as a consignment of dangerous goods, except for the carriage of dry ice (UN No. 1845). When they are carried as a consignment, these substances shall be carried under the relevant entry of Table A of Chapter 3.2 in accordance with the associated conditions
of carriage.
For UN No. 1845, the conditions of carriage specified in this section, except 5.5.3.3.1, apply for all kinds of carriage, as a coolant, conditioner, or as a consignment. For the carriage of UN No. 1845, no other provisions of ADN apply.
5.5.3.1.2 This section is not applicable to gases in cooling cycles.
5.5.3.1.3 Dangerous goods used for cooling or conditioning tanks or MEGCs during carriage are not subject to this section.
5.5.3.1.4 Vehicles, wagons and containers containing substances used for cooling or conditioning purposes include vehicles, wagons and containers containing substances used for cooling or conditioning purposes inside packages as well as vehicles, wagons and containers with unpackaged substances used for cooling or conditioning purposes.
5.5.3.1.5 Sub-sections 5.5.3.6 and 5.5.3.7 only apply when there is an actual risk of asphyxiation in the vehicle, wagon or container. It is for the participants concerned to assess this risk, taking into consideration the hazards presented by the substances being used for cooling or conditioning, the amount of substance to be carried, the duration of the journey, the types of containment to be used and the gas concentration limits given in the note to 5.5.3.3.3.
5.5.3.2 General
5.5.3.2.1 Vehicles, wagons and containers in which dry ice (UN 1845) is carried or containing substances used for cooling or conditioning purposes (other than fumigation) during carriage are not subject to any provisions of ADN other than those of this section.
5.5.3.2.2 When dangerous goods are loaded in vehicles, wagons or containers containing substances used for cooling or conditioning purposes any provisions of ADN relevant to these dangerous goods apply in addition to the provisions of this section.
5.5.3.2.3 (Reserved)
5.5.3.2.4 Persons engaged in the handling or carriage of vehicles, wagons and containers in which dry ice (UN 1845) is carried or containing substances used for cooling or conditioning purposes shall be trained commensurate with their responsibilities.
5.5.3.3 Packages containing dry ice (UN 1845) or a coolant or conditioner
5.5.3.3.1 Packaged dangerous goods requiring cooling or conditioning assigned to packing instructions P203, P620, P650 or P800 of 4.1.4.1 of ADR shall meet the appropriate requirements of that packing instruction.
5.5.3.3.2 For packaged dangerous goods requiring cooling or conditioning assigned to other packing instructions, the packages shall be capable of withstanding very low temperatures and shall not be affected or significantly weakened by the coolant or conditioner. Packages shall be designed and constructed to permit the release of gas to prevent a build-up of pressure that could rupture the packaging. The dangerous goods shall be packed in such a way as to prevent movement after the dissipation of any coolant or conditioner.
5.5.3.3.3 Packages containing dry ice (UN 1845) or a coolant or conditioner shall be carried in well ventilated vehicles, wagons and containers. Marking according to 5.5.3.6 is not required in this case.
Ventilation is not required, and marking according to 5.5.3.6 is required, if:
- the load compartment is insulated, refrigerated or mechanically refrigerated equipment, for example as defined in the Agreement on the International Carriage of Perishable Foodstuffs and on the Special Equipment to be Used for such Carriage (ATP) and separated from the driver's cab;
- for vehicles, gas exchange between the load compartment and the driver's cab is prevented.
NOTE: In this context "well ventilated" means there is an atmosphere where the carbon dioxide concentration is below 0.5% by volume and the oxygen concentration is above 19.5% by volume.
5.5.3.4 Marking of packages containing dry ice (UN 1845) or a coolant or conditioner
5.5.3.4.1 Packages containing dry ice (UN 1845) as a consignment shall be marked "CARBON DIOXIDE, SOLID" or "DRY ICE"; packages containing dangerous goods used for cooling or conditioning shall be marked with the name indicated in Column (2) of Table A of Chapter 3.2 of these dangerous goods followed by the words "AS COOLANT" or "AS CONDITIONER" as appropriate in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements concluded between the countries concerned in the transport operation provide otherwise.
5.5.3.4.2 The marks shall be durable, legible and placed in such a location and of such a size relative to the package as to be readily visible.
...
Remarks on printing
See sections 5.1.2 and 5.1.3:
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5.1.2 Use of overpacks
5.1.2.1
a) (a) Unless marks and labels required in Chapter 5.2, except 5.2.1.3 to 5.2.1.6, 5.2.1.7.2 to 5.2.1.7.8 and 5.2.1.10, representative of all dangerous goods in the overpack are visible, the overpack shall be:
(i) marked with the word "OVERPACK". The lettering of the "OVERPACK" mark shall be at least 12 mm high. The mark shall be in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise; and
(ii) labelled and marked with the UN number and other marks, as required for packages in Chapter 5.2 except 5.2.1.3 to 5.2.1.6, 5.2.1.7.2 to 5.2.1.7.8 and 5.2.1.10, for each item of dangerous goods contained in the overpack. Each applicable mark or label only needs to be applied once.
Labelling of overpacks containing radioactive material shall be in accordance with 5.2.2.1.11.
(b) Orientation arrows illustrated in 5.2.1.10 shall be displayed on two opposite sides of overpacks containing packages which shall be marked in accordance with 5.2.1.10.1, unless the marks remains visible.
5.1.2.2 Each package of dangerous goods contained in an overpack shall comply with all applicable provisions of ADN. The intended function of each package shall not be impaired by the overpack.
5.1.2.3 Each package bearing package orientation marks as prescribed in 5.2.1.10 and which is overpacked or placed in a large packaging shall be oriented in accordance with such marks.
5.1.2.4 The prohibitions on mixed loading also apply to these overpacks.
5.1.3 Empty uncleaned packagings (including IBCs and large packagings), tanks, MEMUs, vehicles, wagons and containers for carriage in bulk
5.1.3.1 Empty uncleaned packagings (including IBCs and large packagings), tanks (including tankvehicles, tank-wagons, battery-vehicles, battery-wagons, demountable tanks, portable tanks, tank-containers, MEGCs, MEMUs), vehicles, wagons and containers for carriage in bulk having contained dangerous goods of the different classes other than Class 7, shall be marked and labelled as if they were full.
NOTE: For documentation, see Chapter 5.4.
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See section 5.2.1 Marking of packages
NOTE 1: For marks related to the construction, testing and approval of packagings, large packagings, pressure receptacles and IBCs, see Part 6 of ADR.
NOTE 2: In accordance with the GHS, a GHS pictogram not required by ADN should only appear in carriage as part of a complete GHS label and not independently (see GHS 1.4.10.4.4).
5.2.1.1 Unless provided otherwise in ADN, the UN number corresponding to the dangerous goods contained, preceded by the letters "UN" shall be clearly and durably marked on each package. The UN number and the letters "UN" shall be at least 12 mm high, except for packages of 30 l capacity or less or of 30 kg maximum net mass and for cylinders of 60 l water capacity or less when they shall be at least 6 mm in height and except for packages of 5 l capacity or less or of 5 kg maximum net mass when they shall be of an appropriate size. In the case of unpackaged articles the mark shall be displayed on the article, on its cradle or on its handling, storage or launching device.
5.2.1.2 All package marks required by this Chapter:
(a) shall be readily visible and legible;
(b) shall be able to withstand open weather exposure without a substantial reduction in effectiveness.
5.2.1.3 Salvage packagings, including large salvage packagings, and salvage pressure receptacles shall additionally be marked with the word "SALVAGE". The lettering of the "SALVAGE" mark shall be at least 12 mm high.
5.2.1.4 Intermediate bulk containers of more than 450 litres capacity and large packagings shall be marked on two opposite sides.
5.2.1.5 Additional provisions for goods of Class 1
For goods of Class 1, packages shall, in addition, bear the proper shipping name as determined in accordance with 3.1.2. The mark, which shall be clearly legible and indelible, shall be in one or more languages, one of which must be French, German or English, unless any agreements concluded between the countries concerned in the transport operation provide otherwise.
5.2.1.6 Additional provisions for goods of Class 2
Refillable receptacles shall bear the following particulars in clearly legible and durable characters:
(a) the UN number and the proper shipping name of the gas or mixture of gases, as determined in accordance with 3.1.2.
In the case of gases classified under an N.O.S. entry, only the technical name *1) of the gas has to be indicated in addition to the UN number.
In the case of mixtures, not more than the two constituents which most predominantly contribute to the hazards have to be indicated;
(b) for compressed gases filled by mass and for liquefied gases, either the maximum filling mass and the tare of the receptacle with fittings and accessories as fitted at the time of filling, or the gross mass;
(c) the date (year) of the next periodic inspection.
These particulars can either be engraved or indicated on a durable information disk or label attached on the receptacle or indicated by an adherent and clearly visible mark such as by printing or by any equivalent process.
NOTE 1: See also 6.2.2.7 of ADR.
NOTE 2: For non refillable receptacles, see 6.2.2.8 of ADR.
[...]
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*1) Instead of the proper shipping name or, if applicable, of the proper shipping name of the n.o.s. entry followed by the technical name, the use of the following names is permitted:
- for UN No. 1078 refrigerant gas, n.o.s: mixture F1, mixture F2, mixture F3;
- for UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2;
- for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s: mixture A or butane, mixture A01 or butane, mixture A02 or butane, mixture A0 or butane, mixture A1, mixture B1, mixture B2, mixture B, mixture C or propane.
- for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized.
- for UN No. 1012 Butylene: 1-butylene, cis-2-butylene, trans-2-butylene, butylenes mixture.
Large packagings (LP)
Label / Mark
Notice
not stated - subject to the requirements only in tank vessels
Remarks on labelling
For empty packagings sub-section 4.1.1.11 of the ADR, RID or the IMDG Code shall apply:
"Empty packagings, including IBCs and large packagings, that have contained a dangerous substance are subject to the same requirements as those for a filled packaging, unless adequate measures have been taken to nullify any hazard."
Furthermore the following provisions apply:
5.2.1.8 Special marking provisions for environmentally hazardous substances
5.2.1.8.1 Packages containing environmentally hazardous substances meeting the criteria of 2.2.9.1.10 shall be durably marked with the environmentally hazardous substance mark shown in 5.2.1.8.3 with the exception of single packagings and combination packagings where such single packagings or inner packagings of such combination packagings have:
- a quantity of 5 l or less for liquids; or
- a net mass of 5 kg or less for solids.
5.2.1.8.2 The environmentally hazardous substance mark shall be located adjacent to the marks required by 5.2.1.1. The requirements of 5.2.1.2 and 5.2.1.4 shall be met.
5.2.1.8.3 The environmentally hazardous substance mark shall be as shown in Figure 5.2.1.8.3.
The mark shall be in the form of a square set at an angle of 45° (diamond-shaped). The symbol (fish and tree) shall be black on white or suitable contrasting background. The minimum dimensions shall be 100 mm x 100 mm and the minimum width of the line forming the diamond shall be 2 mm. If the size of the package so requires, the dimensions/line thickness may be reduced, provided the mark remains clearly visible. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
NOTE: The labelling provisions of 5.2.2 apply in addition to any requirement for packages to bear the environmentally hazardous substance mark.
-- Remark from BAM --
Since the information on environmentally hazardous properties of the substances contained in the Dangerous Goods Database is not currently available for all substances, the user must check if such a mark is required for the substance to be transported.
5.2.1.9 Battery mark
5.2.1.9.1 Packages containing lithium cells or batteries or sodium ion cells or batteries prepared in accordance with special provisions 188 or 400 of Chapter 3.3 shall be marked as shown in Figure 5.2.1.9.2.
5.2.1.9.2 The mark shall indicate the UN number preceded by the letters "UN", i.e. "UN 3090" for lithium metal cells or batteries, "UN 3480" for lithium ion cells or batteries, or "UN 3551" for sodium ion cells or batteries. Where the cells or batteries are contained in, or packed with, equipment, the UN number preceded by the letters "UN", i.e. "UN 3091", "UN 3481" or "UN 3552" as appropriate shall be indicated. Where a package contains cells or batteries assigned to different UN numbers, all applicable UN numbers shall be indicated on one or more marks.
The mark shall be in the form of a rectangle or a square with hatched edging. The dimensions shall be a minimum of 100 mm wide x 100 mm high and the minimum width of the hatching shall be 5 mm. The symbol (group of batteries, one damaged and emitting flame, above the UN number(s)) shall be black on white or suitable contrasting background. The hatching shall be red. If the size of the package so requires, the dimensions may be reduced to not less than 100 mm wide x 70 mm high. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
5.2.1.10 Orientation arrows
5.2.1.10.1 Except as provided in 5.2.1.10.2:
(a) combination packagings having inner packagings containing liquids;
(b) single packagings fitted with vents;
(c) closed or open cryogenic receptacles intended for the carriage of refrigerated liquefied gases; and
(d) machinery or apparatus containing liquid dangerous goods when it is required to ensure the liquid dangerous goods remain in their intended orientation (see special provision 301 of Chapter 3.3), shall be legibly marked with package orientation arrows which are similar to the illustration shown below or with those meeting the specifications of ISO 780:1997. The orientation arrows shall appear on two opposite vertical sides of the package with the arrows pointing in the correct upright direction. They shall be rectangular and of a size that is clearly visible commensurate with the size of the package. Depicting a rectangular border around the arrows is optional.
5.2.1.10.2 Orientation arrows are not required on:
(a) Outer packagings containing pressure receptacles except closed or open cryogenic receptacles;
(b) Outer packagings containing dangerous goods in inner packagings each containing not more than 120 ml, with sufficient absorbent material between the inner and outer packagings to completely absorb the liquid contents;
(c) Outer packagings containing Class 6.2 infectious substances in primary receptacles each containing not more than 50 ml;
(d) Type IP-2, type IP-3, type A, type B(U), type B(M) or type C packages containing Class 7 radioactive material;
(e) Outer packagings containing articles which are leak-tight in all orientations (e.g. alcohol or mercury in thermometers, aerosols, etc.); or
(f) Outer packagings containing dangerous goods in hermetically sealed inner packagings each containing not more than 500 ml.
5.2.1.10.3 Arrows for purposes other than indicating proper package orientation shall not be displayed on a package marked in accordance with this sub-section.
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5.2.2.2 Provisions for labels
5.2.2.2.1 Labels shall satisfy the provisions below and conform, in terms of colour, symbols and general format, to the models shown in 5.2.2.2.2. Corresponding models required for other modes of transport, with minor variations which do not affect the obvious meaning of the label, are also acceptable.
NOTE: Where appropriate, labels in 5.2.2.2.2 are shown with a dotted outer boundary as provided for in 5.2.2.2.1.1. This is not required when the label is applied on a background of contrasting colour.
5.2.2.2.1.1 Labels shall be configured as shown in Figure 5.2.2.2.1.1.
5.2.2.2.1.1.1 Labels shall be displayed on a background of contrasting colour, or shall have either a dotted or solid outer boundary line.
5.2.2.2.1.1.2 The label shall be in the form of a square set at an angle of 45° (diamond-shaped). The minimum dimensions shall be 100 mm x 100 mm. There shall be a line inside the edge forming the diamond which shall be parallel and approximately 5 mm from the outside of that line to the edge of the label. The line inside the edge on the upper half of the label shall be the same colour as the symbol and the line inside the edge on the lower half of the label shall be the same colour as the class or division number in the bottom corner. Where dimensions are not specified, all features shall be in approximate proportion to those shown.
5.2.2.2.1.1.3 If the size of the package so requires the dimensions may be reduced proportionally, provided the symbols and other elements of the label remain clearly visible. Dimensions for cylinders shall comply with 5.2.2.2.1.2.
5.2.2.2.1.2 Gas cylinders for Class 2 may, on account of their shape, orientation and securing mechanisms for carriage, bear labels representative of those specified in this section and the environmentally hazardous substance mark when appropriate, which have been reduced in size, according to the dimensions outlined in ISO 7225:2005, "Gas cylinders - Precautionary labels", for display on the non-cylindrical part (shoulder) of such cylinders.
NOTE: When the diameter of the cylinder is too small to permit the display of the reduced size labels on the non-cylindrical upper part of the cylinder, the reduced sized labels may be displayed on the cylindrical part.
Notwithstanding the provisions of 5.2.2.1.6, labels and the environmentally hazardous substance mark (see 5.2.1.8.3) may overlap to the extent provided for by ISO 7225:2005. However, in all cases, the primary hazard label and the figures appearing on any label shall remain fully visible and the symbols recognizable.
Empty uncleaned pressure receptacles for gases of Class 2 may be carried with obsolete or damaged labels for the purposes of refilling or inspection as appropriate and the application of a new label in conformity with current regulations or for the disposal of the pressure receptacle.
5.2.2.2.1.3 With the exception of labels for Divisions 1.4, 1.5 and 1.6 of Class 1, the upper half of the label shall contain the pictorial symbol and the lower half shall contain:
(a) For Classes 1, 2, 3, 5.1, 5.2, 7, 8 and 9, the class number;
(b) For Classes 4.1, 4.2 and 4.3, the figure "4";
(c) For Classes 6.1 and 6.2, the figure "6".
However for label model No. 9A, the upper half of the label shall only contain the seven vertical stripes of the symbol and the lower half shall contain the group of batteries of the symbol and the class number.
Except for label model No. 9A, the label may include text such as the UN number or words describing the hazard (e.g. "flammable") in accordance with 5.2.2.2.1.5 provided the text does not obscure or detract from the other required label elements.
5.2.2.2.1.4 In addition, except for Divisions 1.4, 1.5 and 1.6, labels for Class 1 shall show in the lower half, above the class number, the division number and the compatibility group letter for the substance or article. Labels for Divisions 1.4, 1.5 and 1.6 shall show in the upper half the division number, and in the lower half the class number and the compatibility group letter.
5.2.2.2.1.5 On labels other than those for material of Class 7, the optional insertion of any text (other than the class number) in the space below the symbol shall be confined to particulars indicating the nature of the hazard and precautions to be taken in handling.
5.2.2.2.1.6 The symbols, text and numbers shall be clearly legible and indelible and shall be shown in black on all labels except for:
(a) the Class 8 label, where the text (if any) and class number shall appear in white;
(b) labels with entirely green, red or blue backgrounds where they may be shown in white;
(c) the Class 5.2 label, where the symbol may be shown in white; and
(d) labels conforming to model No. 2.1 displayed on cylinders and gas cartridges for liquefied petroleum gases, where they may be shown in the background colour of the receptacle if adequate contrast is provided.
5.2.2.2.1.7 All labels shall be able to withstand open weather exposure without a substantial reduction in effectiveness.
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For gases which may be used for cooling or conditioning purposes see section 5.5.3:
5.5.3 Special provisions applicable to the carriage of dry ice (UN 1845) and to packages and vehicles and containers containing substances presenting a risk of asphyxiation when used for cooling or conditioning purposes (such as dry ice (UN 1845) or nitrogen, refrigerated liquid (UN 1977) or argon, refrigerated liquid (UN 1951) or nitrogen)
NOTE: In the context of this section the term "conditioning" may be used in a broader scope and includes protection.
5.5.3.1 Scope
5.5.3.1.1 This section is not applicable to substances which may be used for cooling or conditioning purposes when carried as a consignment of dangerous goods, except for the carriage of dry ice (UN No. 1845). When they are carried as a consignment, these substances shall be carried under the relevant entry of Table A of Chapter 3.2 in accordance with the associated conditions
of carriage.
For UN No. 1845, the conditions of carriage specified in this section, except 5.5.3.3.1, apply for all kinds of carriage, as a coolant, conditioner, or as a consignment. For the carriage of UN No. 1845, no other provisions of ADN apply.
5.5.3.1.2 This section is not applicable to gases in cooling cycles.
5.5.3.1.3 Dangerous goods used for cooling or conditioning tanks or MEGCs during carriage are not subject to this section.
5.5.3.1.4 Vehicles, wagons and containers containing substances used for cooling or conditioning purposes include vehicles, wagons and containers containing substances used for cooling or conditioning purposes inside packages as well as vehicles, wagons and containers with unpackaged substances used for cooling or conditioning purposes.
5.5.3.1.5 Sub-sections 5.5.3.6 and 5.5.3.7 only apply when there is an actual risk of asphyxiation in the vehicle, wagon or container. It is for the participants concerned to assess this risk, taking into consideration the hazards presented by the substances being used for cooling or conditioning, the amount of substance to be carried, the duration of the journey, the types of containment to be used and the gas concentration limits given in the note to 5.5.3.3.3.
5.5.3.2 General
5.5.3.2.1 Vehicles, wagons and containers in which dry ice (UN 1845) is carried or containing substances used for cooling or conditioning purposes (other than fumigation) during carriage are not subject to any provisions of ADN other than those of this section.
5.5.3.2.2 When dangerous goods are loaded in vehicles, wagons or containers containing substances used for cooling or conditioning purposes any provisions of ADN relevant to these dangerous goods apply in addition to the provisions of this section.
5.5.3.2.3 (Reserved)
5.5.3.2.4 Persons engaged in the handling or carriage of vehicles, wagons and containers in which dry ice (UN 1845) is carried or containing substances used for cooling or conditioning purposes shall be trained commensurate with their responsibilities.
5.5.3.3 Packages containing dry ice (UN 1845) or a coolant or conditioner
5.5.3.3.1 Packaged dangerous goods requiring cooling or conditioning assigned to packing instructions P203, P620, P650 or P800 of 4.1.4.1 of ADR shall meet the appropriate requirements of that packing instruction.
5.5.3.3.2 For packaged dangerous goods requiring cooling or conditioning assigned to other packing instructions, the packages shall be capable of withstanding very low temperatures and shall not be affected or significantly weakened by the coolant or conditioner. Packages shall be designed and constructed to permit the release of gas to prevent a build-up of pressure that could rupture the packaging. The dangerous goods shall be packed in such a way as to prevent movement after the dissipation of any coolant or conditioner.
5.5.3.3.3 Packages containing dry ice (UN 1845) or a coolant or conditioner shall be carried in well ventilated vehicles, wagons and containers. Marking according to 5.5.3.6 is not required in this case.
Ventilation is not required, and marking according to 5.5.3.6 is required, if:
- the load compartment is insulated, refrigerated or mechanically refrigerated equipment, for example as defined in the Agreement on the International Carriage of Perishable Foodstuffs and on the Special Equipment to be Used for such Carriage (ATP) and separated from the driver's cab;
- for vehicles, gas exchange between the load compartment and the driver's cab is prevented.
NOTE: In this context "well ventilated" means there is an atmosphere where the carbon dioxide concentration is below 0.5% by volume and the oxygen concentration is above 19.5% by volume.
5.5.3.4 Marking of packages containing dry ice (UN 1845) or a coolant or conditioner
5.5.3.4.1 Packages containing dry ice (UN 1845) as a consignment shall be marked "CARBON DIOXIDE, SOLID" or "DRY ICE"; packages containing dangerous goods used for cooling or conditioning shall be marked with the name indicated in Column (2) of Table A of Chapter 3.2 of these dangerous goods followed by the words "AS COOLANT" or "AS CONDITIONER" as appropriate in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements concluded between the countries concerned in the transport operation provide otherwise.
5.5.3.4.2 The marks shall be durable, legible and placed in such a location and of such a size relative to the package as to be readily visible.
...
Remarks on printing
See sections 5.1.2 and 5.1.3:
----------
5.1.2 Use of overpacks
5.1.2.1
a) (a) Unless marks and labels required in Chapter 5.2, except 5.2.1.3 to 5.2.1.6, 5.2.1.7.2 to 5.2.1.7.8 and 5.2.1.10, representative of all dangerous goods in the overpack are visible, the overpack shall be:
(i) marked with the word "OVERPACK". The lettering of the "OVERPACK" mark shall be at least 12 mm high. The mark shall be in an official language of the country of origin and also, if that language is not English, French or German, in English, French or German, unless agreements, if any, concluded between the countries concerned in the transport operation provide otherwise; and
(ii) labelled and marked with the UN number and other marks, as required for packages in Chapter 5.2 except 5.2.1.3 to 5.2.1.6, 5.2.1.7.2 to 5.2.1.7.8 and 5.2.1.10, for each item of dangerous goods contained in the overpack. Each applicable mark or label only needs to be applied once.
Labelling of overpacks containing radioactive material shall be in accordance with 5.2.2.1.11.
(b) Orientation arrows illustrated in 5.2.1.10 shall be displayed on two opposite sides of overpacks containing packages which shall be marked in accordance with 5.2.1.10.1, unless the marks remains visible.
5.1.2.2 Each package of dangerous goods contained in an overpack shall comply with all applicable provisions of ADN. The intended function of each package shall not be impaired by the overpack.
5.1.2.3 Each package bearing package orientation marks as prescribed in 5.2.1.10 and which is overpacked or placed in a large packaging shall be oriented in accordance with such marks.
5.1.2.4 The prohibitions on mixed loading also apply to these overpacks.
5.1.3 Empty uncleaned packagings (including IBCs and large packagings), tanks, MEMUs, vehicles, wagons and containers for carriage in bulk
5.1.3.1 Empty uncleaned packagings (including IBCs and large packagings), tanks (including tankvehicles, tank-wagons, battery-vehicles, battery-wagons, demountable tanks, portable tanks, tank-containers, MEGCs, MEMUs), vehicles, wagons and containers for carriage in bulk having contained dangerous goods of the different classes other than Class 7, shall be marked and labelled as if they were full.
NOTE: For documentation, see Chapter 5.4.
----------
See section 5.2.1 Marking of packages
NOTE 1: For marks related to the construction, testing and approval of packagings, large packagings, pressure receptacles and IBCs, see Part 6 of ADR.
NOTE 2: In accordance with the GHS, a GHS pictogram not required by ADN should only appear in carriage as part of a complete GHS label and not independently (see GHS 1.4.10.4.4).
5.2.1.1 Unless provided otherwise in ADN, the UN number corresponding to the dangerous goods contained, preceded by the letters "UN" shall be clearly and durably marked on each package. The UN number and the letters "UN" shall be at least 12 mm high, except for packages of 30 l capacity or less or of 30 kg maximum net mass and for cylinders of 60 l water capacity or less when they shall be at least 6 mm in height and except for packages of 5 l capacity or less or of 5 kg maximum net mass when they shall be of an appropriate size. In the case of unpackaged articles the mark shall be displayed on the article, on its cradle or on its handling, storage or launching device.
5.2.1.2 All package marks required by this Chapter:
(a) shall be readily visible and legible;
(b) shall be able to withstand open weather exposure without a substantial reduction in effectiveness.
5.2.1.3 Salvage packagings, including large salvage packagings, and salvage pressure receptacles shall additionally be marked with the word "SALVAGE". The lettering of the "SALVAGE" mark shall be at least 12 mm high.
5.2.1.4 Intermediate bulk containers of more than 450 litres capacity and large packagings shall be marked on two opposite sides.
5.2.1.5 Additional provisions for goods of Class 1
For goods of Class 1, packages shall, in addition, bear the proper shipping name as determined in accordance with 3.1.2. The mark, which shall be clearly legible and indelible, shall be in one or more languages, one of which must be French, German or English, unless any agreements concluded between the countries concerned in the transport operation provide otherwise.
5.2.1.6 Additional provisions for goods of Class 2
Refillable receptacles shall bear the following particulars in clearly legible and durable characters:
(a) the UN number and the proper shipping name of the gas or mixture of gases, as determined in accordance with 3.1.2.
In the case of gases classified under an N.O.S. entry, only the technical name *1) of the gas has to be indicated in addition to the UN number.
In the case of mixtures, not more than the two constituents which most predominantly contribute to the hazards have to be indicated;
(b) for compressed gases filled by mass and for liquefied gases, either the maximum filling mass and the tare of the receptacle with fittings and accessories as fitted at the time of filling, or the gross mass;
(c) the date (year) of the next periodic inspection.
These particulars can either be engraved or indicated on a durable information disk or label attached on the receptacle or indicated by an adherent and clearly visible mark such as by printing or by any equivalent process.
NOTE 1: See also 6.2.2.7 of ADR.
NOTE 2: For non refillable receptacles, see 6.2.2.8 of ADR.
[...]
-----------------------------------------------
*1) Instead of the proper shipping name or, if applicable, of the proper shipping name of the n.o.s. entry followed by the technical name, the use of the following names is permitted:
- for UN No. 1078 refrigerant gas, n.o.s: mixture F1, mixture F2, mixture F3;
- for UN No. 1060 methylacetylene and propadiene mixtures, stabilized: mixture P1, mixture P2;
- for UN No. 1965 hydrocarbon gas mixture, liquefied, n.o.s: mixture A or butane, mixture A01 or butane, mixture A02 or butane, mixture A0 or butane, mixture A1, mixture B1, mixture B2, mixture B, mixture C or propane.
- for UN No. 1010 Butadienes, stabilized: 1,2-Butadiene, stabilized, 1,3-Butadiene, stabilized.
- for UN No. 1012 Butylene: 1-butylene, cis-2-butylene, trans-2-butylene, butylenes mixture.
Tanks
Placard / Mark
Orange-coloured plate
Tanks Notice
not stated - subject to the requirements only in tank vessels
Tank vessels Cones/Lights
Marking of tank vessels with blue cones/lights is not necessary.
Vehicles
Placard / Mark
Orange-coloured plate
Notice Trockengüterschiff
not stated - subject to the requirements only in tank vessels
Containers
Placard / Mark
Orange-coloured plate
Notice
not stated - subject to the requirements only in tank vessels
Bulk
Placard / Mark
Orange-coloured plate
Notice
not stated - subject to the requirements only in tank vessels
Limited and excepted quantities(collapsed)
Values in "ml" and "L" refer to substances that are liquid under normal conditions (temperature 20 °C, density 1013 mbar). Values in "g" and "kg" refer to substances that generally have a melting point greater than 20 °C. Solid substances that can liquefy during transport may only be transported in packagings that are suitable for liquids (paper bags, for example, are not permitted).
Limited quantities(collapsed)
not stated - subject to the requirements only in tank vessels
Excepted quantities(collapsed)
not stated - subject to the requirements only in tank vessels
Exemption according to subsection 1.1.3.6(collapsed)
Since this substance is only dangerous when carried in tank vessels, it is not subject to the provisions of ADN in packages and tanks.
1.1.3.6 Exemptions related to quantities carried on board vessels
1.1.3.6.1 In the event of the carriage of dangerous goods in packages, the provisions of ADN other than those of 1.1.3.6.2 are not applicable when the gross mass of all the dangerous goods carried does not exceed 3,000 kg and for the individual classes does not exceed the quantity that is indicated in the Table below:
[...]
1.1.3.6.2The carriage of exempted quantities according to 1.1.3.6.1 is, however, subject to the following conditions:
(a) The obligation to report in accordance with 1.8.5 remains applicable;
(b) The requirements of sections 1.10.1, 1.10.2 and 1.10.3 apply to packages bearing UN Nos. 2910 and 2911 of Class 7 if the activity level (per package) exceeds the A2 value;
(c) Packages, except vehicles and containers (including swap bodies), shall comply with the requirements for packagings referred to in Parts 4 and 6 of ADR or RID; the provisions of Chapter 5.2 concerning marking and labelling are applicable;
(d) The following documents shall be on board:
- the transport documents (see 5.4.1.1); they shall concern all the dangerous goods carried on board;
- the stowage plan (see 7.1.4.11.1);
(e) The goods shall be stowed in the holds.
This provision does not apply to goods loaded in:
- closed containers;
- sheeted vehicles or sheeted wagons;
(f) Goods of different class shall be separated by a minimum horizontal distance of 3 m. They shall not be stowed on top of each other.
This provision does not apply to:
- closed containers;
- sheeted vehicles or sheeted wagons;
(g) For seagoing and inland navigation vessels, where the latter carry only containers, the above requirements under (e) and (f) shall be considered to have been met if the provisions of the IMDG Code regarding stowage and separation are met and if this particular is recorded in the transport document.
1.1.3.6.3 and 1.1.3.6.4 (Reserved)
1.1.3.6.5 For the purposes of this sub-section, dangerous goods exempted in accordance with 1.1.3.1 (a), (b) and (d) to (f), 1.1.3.2 to 1.1.3.5, 1.1.3.7, 1.1.3.9 and 1.1.3.10 shall not be taken into account.
Containments(collapsed)
Bulk(collapsed)
Bulk
The transport in bulk is according to subsection 7.1.1.11:
Subject to this regulation only in tank vessels
Special requirements according to 7.1.6
Common Regulations 4.1
4.1.3 For carriage in bulk of solids in vehicles, wagons, containers or bulk containers, the following requirements of the international Regulations shall be complied with:
- Chapter 4.3 of the IMDG Code; or
- Chapter 7.3 of ADR, taking account of indications in columns (10) or (17) of Table A of Chapter 3.2 of ADR, except that sheeted vehicles and containers are not allowed;
- Chapter 7.3 of RID, taking account of indications in columns (10) or (17) of Table A of Chapter 3.2 of RID, except that sheeted wagons and containers are not allowed.
----------
Note
For the transport in bulk containers the requirements for design and contruction of chapter 6.11 ADR or RID or chapter 6.9 of IMDG code apply.
Tank vessels (data from Table C)(collapsed)
Tank vessels (data from Table C)
Name and description
SUBSTANCES WITH A FLASH-POINT ABOVE 60 °C BUT NOT MORE THAN 100 °C or SUBSTANCES WHERE 60 °C < flashpoint <= 100 °C, which are not affected to another class (2-ETHYLHEXYLACRYLATE)
Type of tank vessel
Cargo tank design
Cargo tank type
Cargo tank equipment
Opening pressure of the pressure relief valve/ high velocity vent valve
Maximum degree of filling of the cargo tank
97 %
Type of sampling device
Pump room below deck permitted
yes
Temperature class
Explosion group
Anti-explosion protection required
no
Equipment required
Number of cones/blue lights
0
Additional requirements
,
Additional requirement or remark: 3
Arrangements shall be made to ensure that the cargo is sufficiently stabilized in order to prevent a reaction at any time during carriage. The transport document shall contain the following additional particulars:
(a) Name and amount of inhibitor added;
(b) Date on which inhibitor was added and expected duration of effectiveness under normal conditions;
(c) Any temperature limits having an effect on the inhibitor.
When stabilization is ensured solely by blanketing with an inert gas it is sufficient to mention the name of the inert gas used in the transport document.
When stabilization is ensured by another measurement, e.g. the special purity of the substance, this measurement shall be mentioned in the transport document.
,
Additional requirement or remark: 5
This substance is liable to clog the venting piping and its fittings or the fittings of cargo tanks. Careful surveillance should be ensured.
If a closed-type tank vessel cargo tank is required for the carriage of this substance and explosion protection is necessary or the substance for which explosion protection is necessary is carried in a closed cargo tank, the cargo tank shall conform to 9.3.2.22.4 or 9.3.3.22.4 or the venting piping shall conform to 9.3.2.22.5 (a) or 9.3.2.22.5 (b) or to 9.3.3.22.5 (a) or 9.3.3.22.5 (b).
This requirement does not apply when the cargo tanks and the corresponding piping are inerted in accordance with 7.2.4.18.
Additional requirement or remark: 16
If there is a possibility of a dangerous reaction such as polymerisation, decomposition, thermal instability or evolution of gases resulting from local overheating of the cargo in either the cargo tank or associated piping system, this cargo shall be loaded and carried adequately segregated from other substances the temperature of which is sufficiently high to initiate such reaction. Heating coils inside cargo tanks carrying this substance shall be blanked off or secured by equivalent means.
Exceptions(collapsed)
The following is a list of exceptions from the regulations on the transport of dangerous goods (Gefahrgut-Ausnahmeverordnung - GGAV 2002, PDF (German)), which may be relevant for the current substance for transport within Germany. The scope of the GGAV refers to the GGVSEB (Gefahrgutverordnung Straße, Eisenbahn und Binnenschifffahrt) and GGVSee (Gefahrgutverordnung See).
Exception
Title
Validity
none valid in Germany
The Memorandum of Understanding for the transport of packaged dangerous goods by Ro/Ro ships in the Baltic Sea is a further exception in accordance with section 7 paragraph 2 of the GGVSee in conjunction with section 7.9.1 of the IMDG Code.
Memorandum of Understanding
Memorandum of Understanding for the Transport of Packaged Dangerous Goods on Ro-Ro Ships in the Baltic Sea
(1) The competent authorities of Denmark, Estonia, Finland, Germany, Latvia, Lithuania, Poland and Sweden authorize the provisions of this Memorandum of Understanding (MoU) by exemption in accordance with 7.9.1.1 of the International Maritime Dangerous Goods Code (IMDG Code).
(2) This MoU lays down the exemptions (Annex 1) from the provisions of the IMDG Code when transporting dangerous goods covered by Appendix C (Regulations Concerning the International Carriage of Dangerous Goods by Rail (RID)) to the Convention Concerning International Carriage by Rail (COTIF) or Annexes A and B of the Agreement Concerning the International Carriage of Dangerous Goods by Road (ADR) on board ro-ro ships in the Baltic Sea.
(3) Amendments to this MoU shall be made in accordance with the principles in Annex 2.
(4) This MoU is not intended to supersede national or international law.
(5) This MoU shall come into force on 1 January 2023. It shall replace the Memorandum of Understanding, Lübeck 04-06 April 2017 edition as revised under the chairmanship of Germany. This MoU is valid until revoked or replaced with a new edition by the competent authorities.
Annex 1
Memorandum of Understanding for the Transport of Packaged Dangerous Goods in the Baltic Sea
Section 1
Scope
By derogation from the provisions of the IMDG Code, the present provisions (hereinafter this MoU) may be applied on all ro-ro ships operating within the Baltic Sea proper, the Gulf of Bothnia, the Gulf of Finland and the entrance to the Baltic Sea bounded in the north by the line Skaw-Lysekil.
Section 2
Definitions
(1) The terms used in this MoU refer to the IMDG Code except those listed below in this section.
(2) Shipowner means company as defined in the ISM Code.
(3) Low Wave Height Area (LWHA) is a sea area where according to the Agreement concerning specific stability requirements for ro-ro passenger ships undertaking regular scheduled international voyages between or to or from designated ports in North West Europe and the Baltic Sea, 28 February 1996 (Stockholm Agreement), put into effect on 1 April 1997, the significant wave height does not exceed 2.3 metres by a probability of more than 10 % on a yearly basis (see Appendix 1 of Annex 1). Traffic in other areas can be considered as LWHA traffic by the competent authorities concerned if an equivalent level of safety can be assured.
Section 3
Exempted dangerous goods
(1) Sections 3.4.4, 3.4.6 and 3.5.6 and chapter 5.4 of the IMDG Code need not be applied to dangerous goods transported in accordance with Chapter 3.4 and/or 3.5 of ADR/RID provided that the master has been informed by the consignor or his representative of the UN number(s) as well as class(es) of the respective dangerous goods. However, that information is not required for transport in accordance with subsection 3.5.1.4 of ADR/RID. Subsection 3.4.5.5 of the IMDG Code needs not be applied if the cargo transport unit (CTU) is marked in accordance with section 10 (1) c) of this MoU.
(2) The provisions of the IMDG Code need not be applied to dangerous goods exempted in accordance with paragraphs 1.1.3.1 (c) - (f) or 1.1.3.2 (a), (c) or (e) or 1.1.3.4.1 of ADR/RID provided that the master has been informed by the consignor or his representative that these paragraphs of ADR/RID are applied. This information is not required for dangerous goods exempted by the IMDG Code. However, UN 1327 shall be transported in accordance with the provisions of the IMDG Code.
(3) By derogation from the provisions of the IMDG Code, dangerous goods may be exempted in accordance with chapter 1.1.3.1(a) of the ADR, provided that the maximum quantity of flammable liquids in receptacle(-s) carried by private individual(-s) is no more than 25 litres per vehicle in total. Maximum size of receptacle shall not exceed 25 litres.
4) Irrespective of special provision 961 of the IMDG Code, the consignor or his representative shall inform the master of the presence of a vehicle (UN 3166 or UN 3171) when the vehicle is loaded in a closed or sheeted CTU.
Section 4
Training
Consignors and shipowners shall ensure that the persons involved in the transport of CTUs under the provisions of this MoU are made familiar, through repeated training, with the application of this MoU including the relevant provisions of ADR/RID commensurate with their responsibilities. Records of the training shall be kept by consignors and shipowners and made available to the employee or competent authority upon request.
Section 5
Classification
Dangerous goods may be classified in accordance with part 2, chapters 3.2 and 3.3 of ADR/RID. However, substances assigned to special provision 900 of the IMDG Code are prohibited from transport.
Section 6
Use of packagings
Dangerous goods may be packaged in accordance with chapter 4.1 of ADR/RID, except that the packing instruction R001 in section 4.1.4 of ADR/RID may only be applied for traffic in LWHA.
Section 7
Use of tanks
Tanks may be used in accordance with chapter 4.2 of ADR/RID or chapter 4.3 of ADR/RID, except that tanks with open venting devices are not permitted on board ro-ro ships.
Section 8
Bulk transport
Dangerous goods may be transported in bulk in accordance with column 10 or 17 of Table A of chapter 3.2 and chapter 7.3 of ADR/RID with the following exceptions:
a) For substances of class 4.3, only closed waterproof CTUs shall be used.
b) For batteries assigned to UN 2794, UN 2795, UN 2800 or UN 3028, bulk transport is not permitted.
Section 9
Marking and labelling of packages
Packages may be marked and labelled in accordance with chapter 5.2 of ADR/RID.
Section 10
Placarding and marking of CTUs
(1) A CTU may be placarded and marked in accordance with chapter 5.3 of ADR/RID provided the following additional requirements are met:
a) A CTU containing marine pollutants shall be marked in accordance with subsection 5.3.2.3 of the IMDG Code except when marked in accordance with section 5.3.6 of ADR/RID.
b) A trailer without a motor vehicle shall display two orange-coloured plates from the time it has been checked at the port facility and during the voyage except when placarded in accordance with section 5.3.1 of the IMDG Code. One of the plates shall be affixed at the front and the other at the rear of the trailer.
c) A CTU as referred to in paragraph 1.1.3.4.2 of ADR/RID shall display two orange-coloured plates from the time it has been checked at the port facility and during the voyage unless marked in accordance with chapter 3.4 of ADR/RID. One of the plates shall be affixed at the front and the other at the rear of the CTU for road transport or on both sides of the CTU for rail transport.
d) A CTU as referred to in subsection 1.1.3.6 of ADR shall display two orange-coloured plates from the time it has been checked at the port facility and during the voyage. One of the plates shall be affixed at the front and the other at the rear of the CTU.
(2) Additional plates required in accordance with paragraph (1) (b) to (d) shall be clearly visible and conform to paragraph 5.3.2.2.1 of ADR/RID regarding size and colour. These plates need not bear UN numbers and hazard identification numbers. These plates may be replaced by self-adhesive sheets, by paint or by any other equivalent process. The responsibility for affixing such plates shall rest with the person actually placing the CTU ready for loading on board the ro-ro ship.
Section 11
Documentation
(1) The dangerous goods transport document may be issued in accordance with section 5.4.1 of ADR/RID provided the following additional requirements are met:
a) When liquid dangerous goods with a flashpoint of 60 °C or below (closed cup (c. c.)) are to be transported, it shall be indicated whether the flashpoint is < 23 °C or >= 23 °C to ensure appropriate stowage.
b) Marine pollutants shall be identified within the documentation as "MARINE POLLUTANT" or "MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS" if required by paragraph 5.4.1.4.3.5 of the IMDG Code.
(2) By derogation from section 5.4.2 of the IMDG Code, a container/vehicle packing certificate (CTU packing certificate) needs not be provided for CTUs transported in accordance with subsections 1.1.3.1, 1.1.3.2, paragraphs 1.1.3.4.2 or 1.1.3.4.3 of ADR/RID.
(3) The packing certificate for CTUs packed in accordance with section 14 of this MoU shall state additionally: "Packed together in accordance with the MoU".
(4) The following documentation (paper version or electronic version) is required aboard the ship:
a) in addition to section 5.4.3 of the IMDG Code:
- the International Maritime Dangerous Goods Code (IMDG Code) and
- the applicable Regulations Concerning the International Carriage of Dangerous Goods by Rail (RID) or Annexes A and B of the Agreement Concerning the International Carriage of Dangerous Goods by Road (ADR), as appropriate to the mode of transport;
b) in accordance with subsection 7.9.1.4 of the IMDG Code, the applicable edition of this MoU;
c) the emergency response information in accordance with 5.4.3.2 of the IMDG Code shall include the Emergency Procedures for Ships Carrying Dangerous Goods (EmS) and the Medical First Aid Guide for Use in Accidents Involving Dangerous
Goods (MFAG).
(5) By derogation from special provision 932 of the IMDG Code, the certificate is not required if aluminium ferrosilicon powder of UN number 1395, aluminium silicon powder, uncoated of UN number 1398, calcium silicide of UN number 1405 and ferrosilicon of UN number 1408 is transported in packagings.
Section 12
Stowage of CTUs
(1) By derogation from subsection 7.1.3.2 and the stowage category in column 16a of the Dangerous Goods List of the IMDG Code, dangerous goods of classes 2 to 9 may be stowed in accordance with the table below.
Stowage table for CTUs containing packaged dangerous goods of classes 2 to 9
Note: Stowage shall also be in accordance with the Document of Compliance (SOLAS 1974, II2/19) or the Letter of Compliance referred to in section 16 (1) of this MoU.
Description and class as|Cargo ships or |Other passenger |
specified in |passenger ships |ships |
IMDG Code/RID/ADR |carrying either not | |
|more than 25 | |
|passengers or | |
|1 passenger per 3 | |
|metres of overall | |
|length*) | |
-----------------|------|-----------|-----------|-----------|-----------|
Description |Class |On deck |Under deck |On deck |Under deck |
-----------------|------|-----------|-----------|-----------|-----------|
Gases | 2 | | | | |
- flammable | 2.1 | Permitted |Prohibited |Prohibited |Prohibited |
gases | | | | | |
- non-flammable, | 2.2 | Permitted |Permitted1)|Permitted1)|Permitted1)|
non-toxic gases| | | | | |
- toxic gases | 2.3 | Permitted |Prohibited |Prohibited |Prohibited |
-----------------|------|-----------|-----------|-----------|-----------|
Flammable liquids| 3 | | | | |
- packing group | | Permitted | Permitted | Permitted |Prohibited |
I or II | | | | | |
- packing group | | Permitted | Permitted | Permitted |Permitted |
III | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Flammable solids | 4.1 | | | | |
- UN 1944, 1945, | | Permitted | Permitted | Permitted |Permitted |
2254, 2623 | | | | | |
- other UN | | Permitted |Prohibited | Permitted |Prohibited |
numbers | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Substances liable| 4.2 | Permitted |Prohibited | Permitted |Prohibited |
to spontaneous | | | | | |
combustion | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Substances which | 4.3 | Permitted |Prohibited | Permitted |Prohibited |
give off | | | | | |
flammable gases | | | | | |
in contact with | | | | | |
Water | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Oxidizing | 5.1 | Permitted | Permitted | Permitted |Prohibited |
substances | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Organic | 5.2 | Permitted |Prohibited |Prohibited |Prohibited |
peroxides | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Toxic substances | 6.1 | | | | |
- packing group | | Permitted |Prohibited | Permitted |Prohibited |
I or II | | | | | |
- packing group | | Permitted | Permitted | Permitted | Permitted |
III | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Infectious | 6.2 | Permitted | Permitted |Prohibited |Prohibited |
substances | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Radioactive | 7 | Permitted | Permitted | Permitted |Permitted |
material | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Corrosive | 8 | | | | |
substances | | | | | |
- packing group | | Permitted |Prohibited |Prohibited |Prohibited |
I or II | | | | | |
- liquids | | Permitted | Permitted | Permitted |Prohibited |
packing group | | | | | |
III | | | | | |
- solids | | Permitted | Permitted | Permitted |Permitted |
packing group | | | | | |
III | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Miscellaneous | 9 | Permitted | Permitted | Permitted |Permitted |
dangerous | | | | | |
substances and | | | | | |
articles | | | | | |
-----------------|------|-----------|-----------|-----------|-----------|
Footnote:
1) Refrigerated gases of ADR or of stowage category "D" of the IMDG Code
are prohibited.
*) For the purpose of this MoU, the total number of passengers may be
extended to not more than 1 person per 1 metre of the overall length
of the ship.
(2) A Letter of Compliance issued in accordance with previous editions of this MoU for ships constructed before 31 December 2002 is considered to be equivalent to an authorization in accordance with paragraph 7.5.2.6 of the IMDG Code.
Section 13
Segregation of CTUs
By derogation from chapters 7.2 and 7.5 of the IMDG Code for classes 2 to 9 in LWHA traffic, no segregation is required between CTUs if segregation categories "away from" or "separated from" are applicable in accordance with the provisions of the IMDG Code.
Section 14
Packing of CTUs
By derogation from chapter 7.3 of the IMDG Code, for LWHA traffic, packages may be loaded together in the same CTU if segregation categories "away from" or "separated from" are applicable in accordance with the provisions of the IMDG Code. Substances and articles of class 1 or bearing a label of class 1 as a subsidiary hazard may be loaded together in the same CTU in accordance with section 7.5.2 of ADR/RID.
Section 15
Contact information for the main designated national competent authorities
The competent authorities in accordance with these provisions are:
Denmark
Danish Maritime Authority
Caspar Brands Plads 9
DK-4220 Korsør
E-mail: sfs@dma.dk
Estonia
Estonian Transport Administration
Maritime Safety and Supervision
Department
Valge 4
EE-11413 Tallinn
E-mail: ljo@transpordiamet.ee
Finland
Finnish Transport and
Communications Agency
Traficom
P. O. Box 320
FI-00059 TRAFICOM
E-mail: kirjaamo@traficom.fi
Germany
Federal Ministry for Digital and Transport
P. O. Box 20 01 00
D-53170 BONN
E-mail: Ref-G16@bmdv.bund.de
Latvia
Maritime Administration of Latvia
5 Trijadibas str.
LV-1048 RIGA
E-mail: lja@lja.lv
Lithuania
Maritime Department of Lithuanian
Transport
Safety Administration
J. Janonio str. 24LT-92251 KLAIPEDA
E-mail: mardep@ltsa.lrv.lt
Mr. Linas Kasparavicius
Director of Maritime Department
E-mail: linas.kasparavicius@ltsa.lrv.lt
Poland
Ministry of Infrastructure
Chałbinskiego 4/6 Str
PL-00-928 WARSAW
E-mail: sekretariatDGM@mi.gov.pl
Sweden
Swedish Transport Agency
SE-601 73 NORRKÖPING
E-mail: sjofart@transportstyrelsen.se
Section 16
Transitional provisions
(1) Ships constructed before 1 September 1984 already provided with a Letter of Compliance in accordance with the Würzburg edition of the MoU may continue to stow dangerous goods in accordance with this Letter of Compliance.
(2) On board cargo ships and passenger ships carrying not more than 1 passenger per 1 meter length of the ship, CTUs may be stowed under deck in accordance with an approval of the competent authority having granted such a stowage until 31 December 2002 in this deck. In this case, section 13 of this MoU shall not be applied on that deck.
(Appendix 1 of Annex 1 of the MoU, Significant wave heights)
Annex 2
Principles for amending the Memorandum
General
1) The MoU may be amended at a conference or through a written procedure.
2) Conferences or written procedures should be so scheduled that amendments to the international transport regulations (ADR, RID and the IMDG Code) can be taken into account.
3) A conference or a written procedure should be hosted by one of the participating countries usually in the following order: Germany, Poland, Finland, Estonia, Lithuania, Sweden, Denmark, Latvia.
4) Each participating country may propose amendments to the MoU. Amendments may also be proposed by observer states/organisations that have been accepted by the participating countries. The participating countries should agree on amendments by consensus.
5) The revised MoU should be reproduced and circulated by the host when new amendments have been adopted. The amended parts of the text should be indicated in the margin.
6) The revised MoU shall come into force six months after the new text is available or as otherwise decided.
7) Distribution and communication in general should be performed by electronic means.
Conference
8) Proposals should be sent to the host of the next conference at least 3 months before the conference takes place. The host should distribute the proposals to all participating countries and observer states/organisations at least 1 month before the conference. All participating countries and observer states/organisations shall have the opportunity to respond to the documents presented within a period of 2 weeks after the distribution.
9) Working groups for special issues may be arranged in the time between the conferences. The reports or proposals from such working groups should be presented at the conference in the same way as other proposals. Working groups may also take place during a conference, and this should, if possible, be notified in advance.
Written procedure
10) A written procedure can be used as an alternative to a conference providing this is proposed by the participating country designated to host the next conference. In such case the designated participating country will host the written procedure.
11) A written procedure can also be initiated if at least 3 participating countries request it. In such case, the participating country who hosted the latest conference should host the written procedure.
12) The host shall distribute proposals to the participating countries and announce the schedule for written comments. All participating countries should respond to the proposals within a period of 6 weeks. If the initial proposal is amended on the basis of comments of the participating countries, the revised proposal should be distributed again to the participating countries. From the time when the revised proposal is distributed, the participating countries shall declare within 4 weeks whether they agree to the amended text of the MoU.
13) The amendments are adopted if supported by all participating countries. The host shall notify the adoption of the amendments and reproduce and circulate the revised MoU in accordance with paragraph 5.
14) In such case all participating countries shall sign and return to the host a hard copy of the revised MoU. The signed hard copies shall be kept by the host.
Agreements(collapsed)
The following agreements may be important for transport in Germany.
Agreement
Instruction type
Title, Publication status, Signatory states
Validity
none valid in Germany
Further provisions(collapsed)
Special provisions for vessel equipment
According to chapter 8.1 ADN the following requirements concerting vessels and equipment apply
Documents
8.1.2 Documents
8.1.2.1 In addition to the documents required by other regulations, the following documents shall be kept on board:
(a) The vessel's certificate of approval referred to in 1.16.1.1 or the vessel's provisional certificate of approval referred to in 1.16.1.3 and the annex referred to in 1.16.1.4;
(b) Transport documents referred to in 5.4.1 for all dangerous goods carried as cargo on board and, where necessary the large container, vehicle or wagon packing certificate (see 5.4.2);
(c) The instructions in writing prescribed in 5.4.3;
(d) A copy of the ADN with the latest version of its annexed Regulations which may be a copy which can be consulted by electronic means at any time;
(e) The inspection certificate of the insulation resistance of the electrical installations prescribed in 8.1.7.1 and the certificates prescribed in 8.1.7.2 concerning the inspection of all installations, equipment and self-contained protection systems and the conformity of the documents required in 8.1.2.2 (e) to (h) and 8.1.2.3 (r) to (v) with the circumstances on board;
(f) A certificate concerning the inspection of the fire-extinguishing hoses prescribed in 8.1.6.1 and a certificate concerning the inspection of the special equipment prescribed in 8.1.6.3;
(g) A book in which all required measurement results are recorded;
(h) A copy of the relevant text of the special authorizations referred to in 1.5 if the transport operation is performed under this/these special authorization(s);
(i) Means of identification, which include a photograph, for each crew member, in accordance with 1.10.1.4; and
(j) (Deleted).
(k) For vessels which carry hose assemblies used for loading, unloading or delivering liquefied natural gas for the operation of the vessel, the inspection certificate and the documentation of the calculated maximum load stress prescribed in 8.1.6.2.
8.1.2.2 In addition to the documents prescribed in 8.1.2.1, the following documents shall be carried on board dry cargo vessels:
(a) The stowage plan prescribed in 7.1.4.11;
(b) The ADN specialized knowledge certificate prescribed in 8.2.1.2;
(c) For vessels complying with the additional requirements for double-hull vessels:
- a damage-control plan;
- the documents concerning intact stability as well as all conditions of intact stability taken into account for the damaged stability calculation in a form the master understands;
- the certificate of the recognized classification society (see 9.1.0.88 or 9.2.0.88);
(d) The inspection certificates concerning the fixed fire extinguishing systems prescribed in 9.1.0.40.2.9.
(e) A list of or a general plan indicating the fixed installations and equipment suitable for use at least in zone 1 and the installations and equipment complying with 9.1.0.51;
(f) A list of or a general plan indicating the fixed installations and equipment which are not authorized for use during loading and unloading, during a stay near to or within an onshore assigned zone (marked in red according to 9.1.0.52.2);
(g) A plan indicating the boundaries of the zones and the location of the electrical and non-electrical equipment installed in the relevant zones intended for used in explosion hazardous areas;
(h) A list of the installations and equipment referred to under (g) with the following information:
- Installation/equipment, location, marking (explosion protection level according to IEC 60079-0, equipment category according to Directive 2014/34/EU*) or equivalent protection level, explosion group, temperature class, type of protection, test body) in case of electrical equipment for use in zone 1 (alternatively, a copy of the certificate of conformity according to Directive 2014/34/EU*));
- Installation/equipment, location, marking (explosion protection level according to IEC 60079-0, equipment category according to Directive 2014/34/EU*) or equivalent protection level, including explosion group and temperature class, type of protection, identification number) in case of electrical equipment for use in zone 2 and in the case of non-electrical equipment for use in zone 1 and zone 2 (alternatively, a copy of the certificate of conformity according to Directive 2014/34/EU*));
The documents listed in paragraphs (e) to (h) shall bear the stamp of the competent authority issuing the certificate of approval.
8.1.2.3 In addition to the documents prescribed in 8.1.2.1, the following documents shall be carried on board tank vessels:
(a) The cargo stowage plan prescribed in 7.2.4.11.2;
(b) The ADN specialized knowledge certificate prescribed in 8.2.1.2;
(c) For vessels which have to conform to the conditions of damage-control (see 9.3.1.15, 9.3.2.15 or 9.3.3.15)
- a damage-control plan;
- the documents concerning intact stability as well as all conditions of intact stability taken into account for the damaged stability calculation in a form the master understands; the stability booklet and the proof of the loading instrument having been approved by the recognized classification society;
(d) (Deleted);
(e) The certificate of class issued by the recognized classification society prescribed in 9.3.1.8.1, 9.3.2.8.1 or 9.3.3.8.1;
(f) The certificates concerning the inspection of the gas detection systems and the oxygen measuring system prescribed in 8.1.6.3;
(g) The vessel substance list prescribed in 1.16.1.2.5;
(h) The inspection certificate for the hose assemblies for loading and unloading prescribed in 8.1.6.2;
(i) The instructions relating to the loading and unloading flows prescribed in 9.3.2.25.9 or 9.3.3.25.9;
(j) The inspection certificate of the cargo pump-rooms prescribed in 8.1.8;
(k) In the event of the carriage of goods having a melting point > 0° C, heating instructions;
(l) (Deleted);
(m) The registration document referred to in 8.1.11;
(n) For the carriage of refrigerated substances, the instruction required in 7.2.3.28;
(o) The certificate concerning the refrigeration system, prescribed in 9.3.1.27.10, 9.3.2.27.10 or 9.3.3.27.10;
(p) The inspection certificates concerning the fixed fire extinguishing systems prescribed in 9.3.1.40.2.9, 9.3.2.40.2.9 or 9.3.3.40.2.9; and
(q) When carrying refrigerated liquefied gases and the temperature is not controlled in accordance with 9.3.1.24.1 (a) and 9.3.1.24.1 (c), the determination of the holding time (7.2.4.16.16, 7.2.4.16.17 and documentation on the heat transmission coefficient);
(r) A list of or a general plan indicating the fixed installations and equipment suitable to be used at least in zone 1 and the installations and equipment complying with 9.3.x.51;
(s) A list of or a general plan indicating the fixed installations and equipment which are not authorized for use during loading and unloading, gas-freeing or during a stay near to or within an onshore assigned zone (marked in red according to 9.3.1.52.3, 9.3.2.52.3 or 9.3.3.52.3);
(t) A plan approved by a recognized classification society indicating the boundaries of the zones and the location of the electrical and non-electrical equipment installed in the relevant zone intended to be used in explosion hazardous areas, as well as self-contained protection systems;
(u) A list of the installations/equipment referred to under (t) and of the self-contained protection systems, with the following information:
- Installations/equipment, location, marking (explosion protection level according to IEC 60079-0, equipment category according to Directive 2014/34/EU*) or at least equivalent), including explosion group and temperature class, type of protection and test body, in the case of electrical equipment for use in zone 0 or zone 1 and, in the case of non-electrical equipment for use in zone 0; (alternatively, a copy of the inspection certificate, for example the declaration of conformity under Directive 2014/34/EU*));
- Installation/equipment, location, marking (explosion protection level according to IEC 60079-0, equipment category according to Directive 2014/34/EU*) or equivalent protection level, including explosion group and temperature class, type of protection, identification number) in the case of electrical equipment for use in zone 2 and in the case of non-electrical equipment for use in zone 1 and zone 2 (alternatively, a copy of the inspection certificate, for example, the certificate of conformity according to Directive 2014/34/EU*));
- Self-protection system, place of installation, marking (explosion group/subgroup):
(v) A list of or general plan indicating the fixed installations and equipment installed outside the explosion hazardous areas that may be used during loading, unloading, gas-freeing, berthing or during a stay in the immediate vicinity of or within an onshore assigned zone, if not referred to in (r) and (u).
The documents listed in (r) to (v) shall bear the stamp of the competent authority issuing the certificate of approval.
(w) The certificates required under 3.2.3.1, Explanations concerning Table C, explanatory note for column (20), remark 12 subparagraphs (p) and (q), if appropriate;
(x) The certificates required under 3.2.3.1, Explanations concerning Table C, explanatory note for column (20), remark 33 subparagraphs (i), (n) and (o), if appropriate.
8.1.2.4 The instructions in writing referred to in 5.4.3 shall be handed to the master before loading. They shall be kept readily at hand in the wheelhouse.
On board dry cargo vessels, the transport documents shall be handed to the master before loading and on board tank vessels they shall be handed to him after loading and before the journey commences.
8.1.2.5 (Reserved)
8.1.2.6 The presence on board of the certificate of approval is not required in the case of pusher barges which are not carrying dangerous goods, provided that the following additional particulars are indicated, in identical lettering, on the plate furnished by CEVNI:
Number of the certificate of approval: ...
issued by: ...
valid until: ...
The barge-owner shall thereafter keep the certificate of approval and the annex covered by 1.16.1.4 in his possession.
The similarity of the particulars on the plate and those contained in the certificate of approval shall be certified by a competent authority which shall affix its stamp to the plate.
8.1.2.7 The presence on board of the certificate of approval is not required in the case of dry cargo barges or tank barges carrying dangerous goods provided that the plate furnished by CEVNI is supplemented by a second metal or plastic plate reproducing by photo-optical means a copy of the entire certificate of approval. A photo-optical copy of the annex referred to in 1.16.1.4 is not required.
The barge-owner shall thereafter keep the certificate of approval and the annex referred to in 1.16.1.4 in his possession.
The similarity of the particulars on the plate and the certificate of approval shall be certified by a competent authority which shall affix its stamp to the plate.
8.1.2.8 All documents shall be on board in a language the master is able to read and understand. If that language is not English, French or German, all documents, with the exception of the copy of ADN with its annexed Regulations and those for which the Regulations include special provisions concerning languages, shall be on board also in English, French or German, unless agreements concluded between the countries concerned in the transport
operation provide otherwise.
8.1.2.9 8.1.2.1 (b), 8.1.2.1 (g), 8.1.2.4 and 8.1.2.5 do not apply to oil separator vessels or supply vessels. 8.1.2.1 (c) does not apply to oil separator vessels.
__________
*) Official Journal of the European Union No. L 96 of 29 March 2014, p. 309.
Fire-extinguishing arrangements
8.1.4 Fire-extinguishing arrangements
In addition to the fire-extinguishing appliances prescribed in the Regulations referred to in 1.1.4.6, each vessel shall be equipped with at least two additional hand fire-extinguishers having the same capacity. The fire-extinguishing agent contained in these additional hand fire-extinguishers shall be suitable for fighting fires involving the dangerous goods carried.
Special equipment according to section 8.1.5
Special equipment PP
For each member of the crew, a pair of protective goggles, a pair of protective gloves, a protective suit and a suitable pair of protective shoes (or protective boots, if necessary). On bord tank vessels, protective boots are required in all cases.
Hints
8.1.5.3 For pushed convoys or side-by-side formations under way, it shall be sufficient, however, if the pusher tug or the vessel propelling the formation is equipped with the special equipment referred to in 8.1.5.1 above, when this is required in Chapter 3.2, Tables A or C.
Miscellaneous requirements to be complied with by the crew of the vessel
8.3 MISCELLANEOUS REQUIREMENTS TO BE COMPLIED WITH BY THE CREW OF THE VESSEL
8.3.1 Persons authorized on board
8.3.1.1 Unless otherwise provided for in Part 7, only the following persons are authorized to be on board:
(a) members of the crew;
(b) persons who, although not being members of the crew, normally live on board; and
(c) persons who are on board for duty reasons.
8.3.1.2 The persons referred to in 8.3.1.1 (b) are not authorized to remain in the protected area of dry cargo vessels or in the cargo area of tank vessels except for short periods.
8.3.1.3 When the vessel is required to carry two blue cones or two blue lights in accordance with column (19) of Table C of Chapter 3.2, persons under 14 years of age are not permitted on board.
8.3.2 Portable lighting apparatus
On board, only portable lighting appliances with their own source of power are permitted in explosion hazardous areas and on deck.
In explosion hazardous areas, they shall meet at least the requirements for use in the relevant area.
8.3.3 Admittance on board
No unauthorized person shall be permitted on board. This prohibition shall be displayed on notice boards at appropriate places.
8.3.4 Prohibition on smoking, fire and naked light
Smoking, including of electronic cigarettes and similar devices, fire and naked light are prohibited on board. However, the provisions of 7.1.3.41.1 and 7.2.3.41.1 are applicable.
This prohibition shall be displayed on notice boards at appropriate places.
The prohibition does not apply in the accommodation or the wheelhouse, provided that their windows, doors, skylights and hatches are closed or the ventilation system is adjusted to guarantee an overpressure of at least 0.1 kPa.
8.3.5 Work on board
No work requiring the use of an open flame or electric current or liable to cause sparks may be carried out on board.
This provision does not apply:
- To berthing operations;
- In the service spaces outside the protected area or the cargo area, provided the doors and openings of those areas are closed for the duration of the work and the vessel is not being loaded, unloaded or gas-freed; or
- When the vessel is not in the vicinity of or within an onshore assigned zone and, in the case of a tank vessel, has a certificate attesting to the totally gas-free condition of the vessel in accordance with 7.2.3.7.6 or an authorization from the competent authority or in the case of a dry cargo vessel, has a certificate attesting to the totally gas-free condition of the protected area or an authorization from the competent authority.
The use of low-sparking hand-tools (chromium vanadium steel screwdrivers and wrenches or screwdrivers and wrenches of equivalent material from the point of view of spark formation) and appropriate equipment at least for the zone concerned is permitted.
NOTE: In addition, all other applicable regulations regarding workplace safety and safety of operations must be observed.
Ventilation for dry-goods vessels according to chapter 3.2, Table A, column 10 resp. 7.1.6.12:
Since this substance is only dangerous when carried in tank vessels, there are no special ventilation requirements for carriage in dry cargo vessels.
Security provisions
This substance/article is NOT a high consequence dangerous good.
Chapter 1.10 Security Provisions
Definition
High consequence dangerous goods are those which have the potential for misuse in a terrorist event and which may, as a result, produce serious consequences such as mass casualties, mass destruction or, particularly for Class 7, mass socio-economic disruption.
Introductory remarks
Chapter 1.10 SECURITY PROVISIONS
NOTE: For the purposes of this Chapter, "security" means measures or precautions to be taken to minimise theft or misuse of dangerous goods that may endanger persons, property or the environment.
General provisions
1.10.1 General provisions
1.10.1.1 All persons engaged in the carriage of dangerous goods shall consider the security requirements set out in this Chapter commensurate with their responsibilities.
1.10.1.2 Dangerous goods shall only be offered for carriage to carriers that have been appropriately identified.
1.10.1.3 Holding areas in trans-shipment zones for dangerous goods shall be secured, well lit and, where possible and appropriate, not accessible to the general public.
1.10.1.4 For each crew member of a vessel carrying dangerous goods, means of identification, which includes a photograph, shall be on board during carriage.
1.10.1.5 Safety checks in accordance with 1.8.1 shall also concern the implementation of security measures.
1.10.1.6 The competent authority shall maintain up-to-date registers of all valid certificates for experts stipulated in 8.2.1 issued by it or by any recognized organization.
Security training
1.10.2 Security training
1.10.2.1 The training and the refresher training specified in Chapter 1.3 shall also include elements of security awareness. The security refresher training need not be linked to regulatory changes only.
1.10.2.2 Security awareness training shall address the nature of security risks, recognising security risks, methods to address and reduce such risks and actions to be taken in the event of a security breach. It shall include awareness of security plans (if appropriate) commensurate with the responsibilities and duties of individuals and their part in implementing security plans.
1.10.2.3 Such training shall be provided or verified upon employment in a position involving dangerous goods transport and shall be periodically supplemented with refresher training.
1.10.2.4 Records of all security training received shall be kept by the employer and made available to the employee or competent authority, upon request. Records shall be kept by the employer for a period of time established by the competent authority.
Provisions for high consequence dangerous goods
1.10.3 Provisions for high consequence dangerous goods
NOTE: In addition to the security provisions of ADN, competent authorities may implement further security provisions for reasons other than safety during carriage (see also Article 4, paragraph 1 of the Agreement). In order not to impede international and multimodal carriage by different explosives security marks, it is recommended that such marks be formatted consistent with an internationally harmonized standard (e.g. European Union Commission Directive 2008/43/EC).
1.10.3.1 Definition of high consequence dangerous goods
1.10.3.1.1 High consequence dangerous goods are those which have the potential for misuse in a terrorist event and which may, as a result, produce serious consequences such as mass casualties, mass destruction or, particularly for Class 7, mass socio-economic disruption.
1.10.3.1.2 High consequence dangerous goods in classes other than Class 7 are those listed in Table 1.10.3.1.2 and carried in quantities greater than those indicated therein.
1.10.3.1.3 to 1.10.3.1.5 apply to radioactive material
1.10.3.2 Security plans
1.10.3.2.1 Carriers, consignors and other participants specified in 1.4.2 and 1.4.3 engaged in the carriage of high consequence dangerous goods (see Table 1.10.3.1.2) or high consequence radioactive material (see 1.10.3.1.3) shall adopt, implement and comply with a security plan that addresses at least the elements specified in 1.10.3.2.2.
1.10.3.2.2 The security plan shall comprise at least the following elements:
(a) specific allocation of responsibilities for security to competent and qualified persons with appropriate authority to carry out their responsibilities;
(b) records of dangerous goods or types of dangerous goods concerned;
(c) review of current operations and assessment of security risks, including any stops necessary to the transport operation, the keeping of dangerous goods in the vessel, tank or container before, during and after the journey and the intermediate temporary storage of dangerous goods during the course of intermodal transfer or transshipment between units;
(d) clear statement of measures that are to be taken to reduce security risks, commensurate with the responsibilities and duties of the participant, including:
- training;
- security policies (e.g. response to higher threat conditions, new employee/employment verification, etc.);
- operating practices (e.g. choice/use of routes where known, access to dangerous goods in intermediate temporary storage (as defined in (c)), proximity to vulnerable infrastructure etc.);
- equipment and resources that are to be used to reduce risks;
(e) effective and up to date procedures for reporting and dealing with security threats, breaches of security or security incidents;
(f) procedures for the evaluation and testing of security plans and procedures for periodic review and update of the plans;
(g) measures to ensure the physical security of transport information contained in the security plan; and
(h) measures to ensure that the distribution of information relating to the transport operation contained in the security plan is limited to those who need to have it. Such measures shall not preclude the provision of information required elsewhere in ADN.
NOTE: Carriers, consignors and consignees should co-operate with each other and with competent authorities to exchange threat information, apply appropriate security measures and respond to security incidents.
1.10.3.3 Operational or technical measures shall be taken on vessels carrying high consequence dangerous goods (see Table 1.10.3.1.2) or high consequence radioactive material (see 1.10.3.1.3) in order to prevent the improper use of the vessel and of the dangerous goods.
The application of these protective measures shall not jeopardize emergency response.
NOTE: When appropriate and already fitted, the use of transport telemetry or other tracking methods or devices should be used to monitor the movement of high consequence dangerous goods (see Table 1.10.3.1.2 or 1.10.3.1.3).
Limitations
The provisions of this Chapter do not apply to the carriage of UN No. 2912 RADIOACTIVE MATERIAL, LOW SPECIFIC ACTIVITY (LSA-I) and UN No. 2913 RADIOACTIVE MATERIAL, SURFACE CONTAMINATED OBJECTS (SCO-I).
Mixed packing(collapsed)
If carriage in packages is permitted, they shall conform to the mixed packing provisions of one of the international regulations (ADR, RID or IMDG Code) (see Part 4 ADN).
4.1.1 Packagings and tanks shall be used in accordance with the requirements of one of the international Regulations, bearing in mind the indications given in the list of substances of these international Regulations, namely:
For packagings (including IBCs and large packagings): columns (9a) and (9b) of Chapter 3.2, Table A of RID or ADR, or the list of substances in Chapter 3.2 of the IMDG Code or the ICAO Technical Instructions; [...]
4.1.2 The requirements to be implemented are as follows:
For packagings (including IBCs and large packagings): Chapter 4.1 of RID, ADR, the IMDG Code or the ICAO Technical Instructions; [...]
Mixed Loading, Stowage, Segregation(collapsed)
Mixed loading (with other dangerous goods)
not stated - subject to the requirements only in tank vessels
Provisions concerning loading, unloading and carriage
General hints
Provisions concerning loading, unloading and carriage:
Notes:
1. Alphanumeric codes starting with the letters "CO", "ST" and "RA" mean that special additional conditions are applicable to carriage in bulk. These can be found in 7.1.6.11 and establish special requirements.
2. Alphanumeric codes starting with the letters "LO" mean that special additional conditions are applicable prior to loading. These can be found in 7.1.6.13 and establish special requirements.
3. Alphanumeric codes starting with the letters "HA" mean that special additional conditions are applicable to the handling and stowage of the cargo. These can be found in 7.1.6.14 and establish special requirements.
4. Alphanumeric codes starting with the letters "IN" mean that special additional conditions are applicable to the inspection of holds during carriage. These can be found in 7.1.6.16 and establish special requirements.
Excerpts from ADN 7.1.4.14 "Handling and stowage of the cargo"
7.1.4.14 Handling and stowage of the cargo
7.1.4.14.1 The various components of the cargo shall be stowed such as to prevent them from shifting in relation to one another or to the vessel and such that no damage can be caused by other cargo.
7.1.4.14.1.1 Packages containing dangerous substances and unpackaged dangerous articles shall be secured by suitable means capable of restraining the goods (such as fastening straps, sliding slatboards, adjustable brackets) in a manner that will prevent any movement during carriage which would change the orientation of the packages or cause them to be damaged. When dangerous goods are carried with other goods (e.g. heavy machinery or crates), all goods shall be securely fixed or packed so as to prevent the release of dangerous goods. Movement of packages may also be prevented by filling any voids by the use of dunnage or by blocking and bracing. Where restraints such as banding or straps are used, these shall not be overtightened to cause damage or deformation of the package. Flexible bulk containers shall be stowed in such way that there are no void spaces between them in the hold. If the flexible bulk containers do not completely fill the hold, adequate measures shall be taken to avoid shifting of cargo.
7.1.4.14.1.2 Packages shall not be stacked unless designed for that purpose. Where different design types of packages that have been designed for stacking are to be loaded together, consideration shall be given to their compatibility for stacking with each other. Where necessary, stacked packages shall be prevented from damaging the package below by the use of load-bearing devices. Flexible bulk containers may be stacked on each other in holds provided that the stacking height does not exceed three high. When flexible bulk containers are fitted with venting devices, the stowage of the flexible bulk containers shall not impede their function.
7.1.4.14.1.3 During loading and unloading, packages containing dangerous goods shall be protected from being damaged.
NOTE: Particular attention shall be paid to the handling of packages during their preparation for carriage, the type of vessel on which they are to be carried and to the method of loading or unloading, so that accidental damage is not caused through dragging or mishandling the packages.
7.1.4.14.1.4 When orientation arrows are required, packages and overpacks shall be oriented in accordance with such markings.
NOTE: Liquid dangerous goods shall be loaded below dry dangerous goods whenever practicable.
7.1.4.14.2 Dangerous goods shall be stowed at a distance of not less than 1 m from the accommodation, the engine rooms, the wheelhouse and any sources of heat.
When the accommodation or wheelhouse is situated above a hold, dangerous goods shall in no case be stowed beneath such accommodation or wheelhouse.
7.1.4.14.3 Packages shall be protected against heat, sunlight and the effects of the weather. This provision does not apply to vehicles, wagons, tank-containers, portable tanks, MEGCs and containers.
Where packages are not enclosed in vehicles, wagons or containers but loaded on deck, they shall be covered with tarpaulins that are not readily flammable.
The ventilation shall not be obstructed.
7.1.4.14.4 The dangerous goods shall be stowed in the holds. However, dangerous goods packed or loaded in:
- closed containers;
- MEGCs;
- sheeted vehicles or sheeted wagons;
- tank-containers or portable tanks;
- tank vehicles or tank wagons;
may be carried on deck in the protected area.
7.1.4.14.5 Packages containing dangerous goods of Classes 3, 4.1, 4.2, 5.1 or 8 may be stowed on deck in the protected area provided that drums are used or that they are contained in containers with complete walls or vehicles or wagons with complete walls. Substances of Class 2 may be stowed on deck in the protected area, provided they are contained in cylinders.
7.1.4.14.6 For seagoing vessels, the stowage requirements set out in 7.1.4.14.1 to 7.1.4.14.5 above and 7.1.4.14.7 below shall be deemed to have been met, if the relevant stowage provisions of the IMDG Code and, in the case of carriage of dangerous goods in bulk, those set out in subsection 9.3 of the IMSBC Code have been complied with.
Note: Section 7.1.4.14.7 applies to radioactive material.
7.1.4.15 Measures to be taken after unloading
7.1.4.15.1 After unloading the holds shall be inspected and cleaned if necessary. In the case of carriage in bulk, this requirement does not apply if the new cargo comprises the same goods as the previous cargo.
7.1.4.15.2 For material of Class 7 see also 7.1.4.14.7.5.
7.1.4.15.3 A cargo transport unit or hold space which has been used to carry infectious substances shall be inspected for release of the substance before re-use. If the infectious substances were released during carriage, the cargo transport unit or hold space shall be decontaminated before it is re-used. Decontamination may be achieved by any means which effectively inactivates the released infectious substance.
7.1.4.16 Measures to be taken during loading, carriage, unloading and handling of the cargo The filling or emptying of receptacles, tank vehicles, tank wagons, intermediate bulk containers (IBCs), large packagings, MEGCs, portable tanks or tank-containers on board the vessel is prohibited without special permission from the competent authority.
Additional regulations for special classes or goods:
not stated - subject to the requirements only in tank vessels
Links to external databases(collapsed)
Here are some links to external databases or websites where you may find further information on the current substance.
Chemsafe
Database for safety characteristics in explosion protection